Ferromagnetic fraction of Cretaceous and Cenozoic sediments at DSDP Holes 72-515B and 72-516F

Investigation of the ferromagnetic fraction of sediments from the Brazil Basin and Rio Grande Rise shows that its main constituents are magnetite and hematite. The magnetite is detrital, but the hematite is both detrital and chemical in origin. Magnetite is the main carrier of the natural remanent magnetization (NRM); therefore, the NRM is detrital remanent magnetization (DRM). In a number of cases, the change of magnetic parameters along the stratigraphic column permits some refinement of the previously defined boundaries of the lithologic units.

Physical properties and minerals of Leg 65 Holes basalts

Velocities and densities of submarine basalts obtained during Leg 65 are distinguished by their relatively high values (about 6.3 km/s and 2.9 g/cm/**3, respectively). This is consistent with their low degree of alteration. The range of velocities covered by these samples correlates well with porosity, and a comparison with in situ velocities from refraction data suggests maximum porosities ih the upper 100 meters of the crust of about 10%.

Geochemistry at DSDP Hole 76-534A

At Site 534 in the Blake-Bahama Basin, western North Atlantic, an interval of 68 m of Maestrichtian (Upper Cretaceous) and upper middle to upper Eocene sediments consists of terrigenous siltstones, mudstones, and varicolored zeolitic claystones; minor recovery of micritic limestones, porcellanites, and quartzitic chert was made at this site as well. Comparisons with other Deep Sea Drilling Project (DSDP) sites in the western North Atlantic suggest that the following formations are present in this interval: Hatteras (Maestrichtian), Plantagenet (Maestrichtian and upper Eocene), Bermuda Rise (upper middle to upper Eocene), and the basal Blake Ridge Formation (upper middle to upper Eocene). Recognition of a Tertiary interval of the Plantagenet allows that formation to be divided into lower and upper informal units. Condensation makes this formal lithostratigraphic subdivision difficult. Together the formations record marked net condensed sedimentation (average rate ca. 2.5 m/m.y.) in strongly oxidizing bottom waters. From sedimentary structures and petrography, it is inferred that the terrigenous siltstones and micritic limestones were redeposited from the continental margin by turbidity currents. Chemical data plus petrography confirm relatively high plankton productivity during the upper Eocene. Much of the nonrecovered Eocene interval may represent chert and porcellanite. Fragments recovered were formed by replacement of relatively porous calciturbidites by opal-CT and quartz. Radiolarians in interbedded claystones rich in clinoptilolite show extensive dissolution. Relative to typical hemipelagic sediments, the claystones are enriched in many metals (Cu, Ni, Zn, Pb), particularly within manganese micronodules. The metal accumulation is related to a 30-m.y. period of slow net sediment accumulation, rather than to hydrothermal enrichment or to upward mobilization of metals from the underlying reduced Hatteras black shale facies. Elsewhere in the Blake-Bahama Basin, at Site 391, 22 km to the northwest, upper Eocene facies are missing, reportedly due to deep seafloor erosion of up to 800 m of the sedimentary succession. By contrast, the discovery that this interval is preserved at nearby Site 534 points to much less extensive seafloor erosion, possibly mostly in the Oligocene, which is missing at both DSDP Sites.

Petrology and diagenesis of sandstones at DSDP Hole 58-445

The sandstone succession in the lower 240 meters of DSDP Site 445, on the Daito Ridge, provided an opportunity to evaluate the effect of burial diagenesis of sandstones in a deep hole in a tectonic environment (remnant arc) characterized by a history of high heat flow. This report provides preliminary data concerning the petrology and diagenesis of these sandstones and records diagenetic changes which have occurred with increasing depth of burial. Methods used for this study included grain-size analysis (measured from thin sections using the method of Friedman, 1958), polarizing microscopy, X-ray diffraction, and scanning electron microscopy. A JEOL scanning electron microscope fitted with an energydispersive- X-ray detector was used for obtaining qualitative chemical data on certain minerals to aid in identification.

Isotopic composition of oxygen, carbon, and sulfur in interstitial water and cores at DSDP Leg 59 Holes

Comprehensive isotopic studies based on data from the Deep Sea Drilling Project have elucidated numerous details of the low- and high-temperature mechanisms of interaction between water and rocks of ocean crustal seismic Layers 1 and 2. These isotopic studies have also identified climatic changes during the Meso-Cenozoic history of oceans. Data on the abundance and isotopic composition of sulfur in the sedimentary layer as well as in rocks of the volcanic basement are more fragmentary than are oxygen and carbon data. In this chapter we specifically concentrate upon isotopic data related to specific features of the mechanisms of low-temperature interaction of water with sedimentary and volcanogenic rocks. The Leg 59 data provide a good opportunity for such lithologic and isotopic studies, because almost 600 meters of basalt flows and sills interbedded with tuffs and volcaniclastic breccias were cored during the drilling of Hole 448A. Moreover, rocks supposedly exposed to hydrothermal alteration play an important role at the deepest horizons of that mass. Sulfur isotopic studies of the character of possible biogenic processes of sulfate reduction in sediments are another focus, as well as the nature and origin of sulfide mineralization in Layer-2 rocks of remnant island arcs. Finally, oxygen and carbon istopic analyses of biogenic carbonates in the cores also enabled us to investigate the effects of changing climatic conditions during the Cenozoic. These results are compared with previous data from adjacent regions of the Pacific Ocean. Thus this chapter describes results of isotopic analyses of: oxygen and sulfur of interstitial water; oxygen and carbon of sedimentary carbonates and of calcite intercalations and inclusions in tuffs and volcaniclastic breccias interbedded with basalt flows; and sulfur of sulfides in these rocks.

Radiochemistry at DSDP Leg 54 and 70 Holes

Use of the hydraulic piston corer during DSDP Leg 70 in the Galapagos mounds area allowed recovery of an undisturbed sedimentary sequence down to the basement. It thus became possible to establish the chronology of different events. Several holes on and off the mounds were studied, using uranium series disequilibrium methods of age determination and oxygen isotope stratigraphy. The following sequence was thereby established: 1) From 600,000 to 300,000 years ago there was normal pelagic sedimentation, with an injection of uranium-rich solution, probably of hydrothermal origin, between 400,000 and 300,000 years ago. 2) From 300,000 to 90,000 years ago, nontronitic clay formed, replacing a pre-existing sediment. 3) From 60,000 to 20,000 years ago, manganese oxide deposits formed, probably also replacing pre-existing sediments. 4) About 19,000 years ago there occurred a uranium injection from seawater, attributed to the end of the hydrothermal circulation. In some holes, especially Hole 424, Leg 54, younger manganese oxides have been found, indicating that some mounds may be presently active.

Planktonic foraminifera at DSDP Holes 72-516 and 72-518

Quantitative analysis was performed on the Quaternary planktonic foraminiferal fauna from Site 516, near the crest of the Rio Grande Rise, and Site 518, on the lower western flank of the Rise. From Hole 516, 46 samples were taken, and from Hole 518, 80 samples were taken. The mean interval between samples is 20 to 25 cm. About 50 species of Quaternary and Pliocene planktonic foraminifers were identified. Quaternary sediments, dated by the initial evolutionary appearance of Globorotalia truncatulinoides and other criteria, have thickness, of 9.8 m in Hole 516 and 16 m in Hole 518. The Globorotalia truncatulinoides Zone is subdivided into four subzones or biostratigraphic horizons (from lower to upper): (1) Globorotalia crassaformis viola, (2) Globorotalia crassaformis hessi, (3) Globigerina calida calida, and (4) Globigerinoides ruber (pink). Thickness of these horizons in Hole 516 establishes the age of the boundaries between them as 1.47, 0.81, and 0.28 Ma, respectively. All the Quaternary planktonic foraminiferal complexes sampled are subtropical. The region of the Rio Grande Rise, therefore, has been within the southern subtropical gyre continuously for the last 2 Ma. The average annual surface water temperatures were reconstructed for the Quaternary at both sites. A micropaleontologic method for the paleotemperature analysis of the thanatocoenosis registers an average Quaternary temperature of 21.2°C at Site 516 and 21.7°C at Site 518. The temperature fluctuations increase up to 3.5°C during the accumulation of the two last horizons (since 0.81 Ma). Temperature peaks are tentatively compared with oxygen isotopic stages and with continental glaciations. Levels at which planktonic foraminiferal species disappear correspond to coldwater intervals. In the Quaternary of Site 518, some layers show signs of dissolution. Corrosive to CaCO3, the northward flow of Antarctic Bottom Water through the Vema Channel increases during the cold periods. Site 518 has two layers of redeposited foraminiferal sand with Pliocene foraminifers. The average rate of the Quaternary sedimentation in Hole 516 is 0.52 cm per thousand years, and in Hole 518 it is 0.84 cm per thousand years.

Reflectance and composition of dispersed organic matter at DSDP Leg 67 Hole

Dispersed organic matter of plant origin from three sites of the Middle America Trench transect was investigated by coal petrographic methods. Samples from the slope region are rich in lipoid and inert substances. Humic matter is predominant in the trench sediments. Reflectance measurements show that the rank of the organic matter is peat, independent of the tectonic position and age of the samples in question. A slow increase of coalification with depth is observed.

Chemistry of pore water and solids, formation factors and salt-corrected porosities of DSDP Site 68-503

Recent discoveries relating to the circulation of fluids within the oceanic crust include the finding of both important fluxes of elements and isotopes into the oceans by ridge-crest hydrothermal convection and important fluxes of heat out of the oceanic crust by convection at ridge crests and at some distance from ridge crests. In the present chapter, I present isotopic, chemical, and physical data from sediments and pore waters of Deep Sea Drilling Project (DSDP) Holes 503A and 503B. These results are modeled in terms of pore-water diffusion, advection, and production to ascertain the relative contribution of these processes at this location, 7.5 m.y. removed from ridge-crest hydrothermal activity. The observations made here contribute to the understanding of chemical and heat transport in oceanic crust of moderate age.

Physical properties of sediments at DSDP Holes 78-541 and 78-543

Sediment cored within the Barbados subduction complex at Sites 541 and 542 are underconsolidated. Underconsolidation and changes in physical properties of the cored section can be related to excess pore water pressure that equals the lithostatic load at Site 542 and to major thrust faulting observed at Site 541. Apparently, the pore fluids within the subduction complex are absorbing the tectonic shock of underthrusting. Sediment sampled from the reference Site 543 on the adjacent Atlantic Plate are also underconsolidated. However, underconsolidation in Hole 543 is apparently due to the movement of excess nitrogen gas observed deeper in the hole. Excess gas was not observed at Sites 541 and 542.

Concentration and isotope composition of sulphur in sediments and pore water at DSDP Leg 70 Holes

Data obtained while investigating the mounds area near the Galapagos Spreading Center demonstrate the direct influence of solutions derived from the interaction of seawater and young oceanic crust on the sedimentary cover. Investigation of metalliferous sediments from the mid-oceanic ridges, the Galapagos mounds, and the FAMOUS-area zone formations have shown that this influence and the resulting products are dependent on composition, temperature, and conditions of solution input. The study of sulfur in upwardly migrating solutions and the interaction of these solutions with sediments is of great interest. Investigations of different types of hydrothermally derived formations (Edmond, et al., 1979; Spiess et al., 1980; Styrt et al., 1981; Rosanova 1976; Grinenko et al., 1978) have shown the significant role of sulfur-bearing minerals in deposits formed from hightemperature solutions. In contrast, the addition of hydrothermal sulfur is negligible in those metalliferous sediments that precipitated as a result of the interaction between the solutions and open seawater (Bonatti et al., 1972, 1976; Gordeev et al., 1979; Migdisov, Bogdanov, et al., 1979). For example, sulfides are absent in clearly oxidized metalliferous sediments from the East Pacific Rise (EPR). Barite sulfur from these sediments is identical with seawater sulfate sulfur in isotope composition (Grinenko et al., 1978). Gurvich and Bogdanov (1977) have suggested that barium from EPR metalliferous sediments results completely from biological activity and from the components of ocean waters. Edmond et al. (1979) report that low-temperature springs from the Galapagos Rift axis contain two types of solutions: those with and those without H2S.

Geochemisty at DSDP Hole 62-465A

Very significant enhancements of the element iridium have been observed in association with the Cretaceous/ Tertiary boundary in marine sediments laid down 65 m.y. ago and subsequently uplifted above the ocean's surface. If our hypothesis for the origin of the iridium and the cause of the Cretaceous/Tertiary life extinctions (the asteroid-impact theory) (Alvarez et al., 1980) is correct, the Ir anomaly should be associated with the Cretaceous/ Tertiary boundary region wherever it is intact. The present work was undertaken to search for the Ir anomaly in a deep-sea-drilling core, in order to check this aspect of the asteroid-impact theory.

(Table 1) Non-arboreal and arboreal pollen spectra at DSDP Holes 75-532 and 75-530A

Some samples from DSDP Holes 530A and 532 were analyzed for their fossil pollen content. The sites are located in the southeastern corner of the Angola Basin, about 200 km west of the present coastline. Fossil pollen assemblages of Holocene to Miocene age were compared with present-day pollen deposition in the arid Namib sand sea. The strong resemblance of all the pollen spectra indicates that very arid conditions existed in the coastal region of Namibia in Quaternary and Pliocene times. These data are in agreement with the late Miocene origin of the coastal aridity and with the conception that upwelling of cold water was responsible for these desert conditions.