339 resultados para AIRBORNE ISOCYANATES


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Ice shelves strongly impact coastal Antarctic sea-ice and the associated ecosystem through the formation of a sub-sea-ice platelet layer. Although progress has been made in determining and understanding its spatio-temporal variability based on point measurements, an investigation of this phenomenon on a larger scale remains a challenge due to logistical constraints and a lack of suitable methodology. In this study, we applied a laterally-constrained Marquardt-Levenberg inversion to a unique multi-frequency electromagnetic (EM) induction sounding dataset obtained on the landfast sea ice of Atka Bay, eastern Weddell Sea, in 2012. In addition to consistent fast-ice thickness and -conductivities along > 100 km transects; we present the first comprehensive, high resolution platelet-layer thickness and -conductivity dataset recorded on Antarctic sea ice. The reliability of the algorithm was confirmed by using synthetic data, and the inverted platelet-layer thicknesses agreed within the data uncertainty to drill-hole measurements. Ice-volume fractions were calculated from platelet-layer conductivities, revealing that an older and thicker platelet layer is denser and more compacted than a loosely attached, young platelet layer. The overall platelet-layer volume below Atka Bay fast ice suggests that the contribution of ocean/ice-shelf interaction to sea-ice volume in this region is even higher than previously thought. This study also implies that multi-frequency EM induction sounding is an effective approach in determining platelet layer volume on a larger scale than previously feasible. When applied to airborne multi-frequency EM, this method could provide a step towards an Antarctic-wide quantification of ocean/ice-shelf interaction.

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Results of helicopter-borne electromagnetic measurements of total (ice plus snow) sea-ice thickness performed in May 2004 and 2005 in the Lincoln Sea and adjacent Arctic Ocean up to 86° N are presented. Thickness distributions south of 84° N are dominated by multi-year ice with modal thicknesses of 3.9 m in 2004 and 4.2 m in 2005 (mean thicknesses 4.67 and 5.18 m, respectively). Modal and mean snow thickness on multi-year ice amounted to 0.18 and 0.30 m in 2004, and 0.28 and 0.35 m in 2005. There are also considerable amounts of 0.9-2.2 m thick first-year ice (modal thickness), mostly representing ice formed in the recurring, refrozen Lincoln Polynya. Results are in good agreement with ground-based electromagnetic thickness measurements and with ice types demarcated in satellite synthetic aperture radar imagery. Four drifting buoys deployed in 2004 between 86° N and 84.5° N show a similar pattern of a mean southward drift of the ice pack of 83 ± 18 km between May 2004 and April 2005, towards the coast of Ellesmere Island and Nares Strait. The resulting area decrease of 26% between the buoys and the coast is larger than the observed thickness increase south of 84° N. This points to the importance of shear in a narrow band along the coast, and of ice export through Nares Strait in removing ice from the study region.

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The knowledge of ice sheet surface topography and the location of the ice divides are essential for ice dynamic modeling. An improved digital elevation model (DEM) of Dronning Maud Land (DML), Antarctica, is presented in this paper. It is based on ground-based kinematic GPS profiles, airborne radar altimetry, and data of the airborne radio-echo sounding system, as well as spaceborne laser altimetry from NASA's Ice, Cloud and land Elevation Satellite (ICESat). The accuracy of ICESat ice sheet altimetry data in the area of investigation is discussed. The location of the ice divides is derived from aspect calculation of the topography and is verified with several velocity data derived from repeated static GPS measurements.

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A 6-m.y.-long composite marine record of explosive silicic volcanism from five Ocean Drilling Program sites in the subpolar North Atlantic was compared with several marine records of global and local paleoclimate proxies (benthic d18O and ice-rafted debris records). Coarsening and high frequency of occurrence of Icelandic tephras were recorded in 3.6-3 Ma sediments, suggesting that these tephras were dispersed farther from the source by enhanced westerly winds over the subpolar North Atlantic. The 40Ar/39Ar ages were determined by laser probe on K-feldspar and biotite phenocrysts of tephras that were erupted from the Jan Mayen volcanic system. Compared to the tuned paleomagnetic age model, the 40Ar/39Ar dating (0.618+/-0.007 Ma to 4.90+/-0.05 Ma) yields a new age model that postdates by 155 k.y. the inception of ice rafting on the Iceland Plateau during the cold marine isotope stage M2 (i.e., 3.3-3.14 Ma).

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New maps of free-air and the Bouguer gravity anomalies on the Weddell Sea sector (70-81° S, 6-75° W) of Antarctica are presented. These maps are based on the first computer compilation of available gravity data collected by ''Sevmorgeologia'' in 1976-89 in the southern Weddell Sea and adjacent coasts of western Dronning Maud Land (WDML) and Coats Land. The accomplished gravity studies comprise airborne observations with a line spacing of about 20 km and conventional measurements at over-the-ice points, which were spaced at 10-30 km and supplemented by seismic soundings. Hence, anomalies on the maps represent mainly large-scale and deep crustal features. The dominant feature in free-air gravity map is a large dipolar gravity anomaly stretching along the continental margin. Following the major grain of seabed morphology this shelf-edge/slope anomaly (SESA) is clearly divided into three segments characterized by diverse anomaly amplitudes, wavelengths and trends. They are associated with continental margins of different geotectonic provinces of Antarctica surrounding the Weddell Sea. Apparent distinctions in the SESA signatures are interpreted as the gravity expression of tectonic, deep crustal structure segmentation of the continental margin. The prominent gravity highs (100-140 mGal) of the shelf edge anomaly mapped along WDML are assumed to represent high-density mantle injections intruded into the middle/lower crust during initial rifting of continental breakup. Enlarged wavelengths and diminished amplitudes of the gravity anomaly westwards, along the Weddell Sea embayment (WSE) margin, reflect a widening of the continental slope and a significant increase in thickness of underlying sediment strata. Low amplitude, negative free-air anomalies in the Filchner-Ronne Ice Shelves (FRIS) contrast sharply with the dominating positive anomalies offshore. This indicates a greater sedimentary thickness of the basin in this area. Crustal response to the enlarged sediment load is impressed in mostly positive features of the Bouguer gravity field observed here. Two pronounced positive Bouguer anomalies of 50-70 mGal and an average widths of 200 km dominate the Weddell Sea embayment margins towards the Antarctic Peninsula and the East Antarctic craton. They correlate well with very deep seabed troughs (> 1000 m below sea level). The gravity highs are most likely caused by a shallow upper mantle underneath graben-rift structures evolved at the margins of the WSE basin. A regional zone (> 100 km in width) of the prominent Bouguer and free-air negative anomalies (-40 to -60 mGal) adjacent Coats Land to the north of the ice shelf edge may indicate the presence of the thick old cratonic crust far offshore beneath the Weddell Sea Embayment.

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Hallstätter Glacier is the northernmost glacier of Austria. Appendant to the northern Limestone Alps, the glacier is located at 47°28'50'' N, 13°36'50'' E in the Dachstein-region. At the same time with its advance linked to the Little Ice Age (LIA), research on changes in size and mass of Hallstätter glacier was started in 1842 by Friedrich Simony. He observed and documented the glacier retreat related to its last maximum extension in 1856. In addition, Hallstätter Glacier is a subject to scientific research to date. In this thesis methods and results of ongoing mass balance measurements are presented and compared to long term volume changes and meteorological observations. The current mass balance monitoring programm using the direct glaciological method was started 2006. In this context, 2009 the ice thickness was measured with ground penetrating radar. The result are used with digital elevation models reconstucted from historical maps and recent digital elevation models to calculate changes in shape and volume of Hallstätter Glacier. Based on current meteorological measurements near the glacier and longtime homogenized climate data provided by HISTALP, time series of precipitation and temperature beginning at the LIA are produced. These monthly precipitation and monthly mean temperature data are used to compare results of a simple degree day model with the volume change calculated from the difference of the digital elevation models. The two years of direct mass balance measurements are used to calibrate the degree day model. A number of possible future scenarios are produced to indicate prospective changes. Within the 150-year-period between 1856 and 2007 the Hallstätter Glacier lost 1940 meters of its length and 2.23 km**2 in area. 37% of the initial volume of 1856 remained. This retreat came along with a change in climate. The application of a running avarage of 30 years shows an increase in precipitation of 18.5% and a warming of 1.3°C near the glacier between 1866 and 1993. The mass loss was continued in the hydrological years 2006/2007 and 2007/2008 showing mean specific mass balance of -376 mm and -700 mm, respectively. Applying a temperature correction for the different minimum elevations of the glacier, the degree day approach based on the two measured mass balances can reproduce sign and order of magnitude of the volume change of Hallstätter Glacier since 1856. Nevertheless, the relative deviation is significant. Future scenarios show, that 30% of the entire glacier volume remains after subtracting the elevation changes between the digital elevation models of 2002 and 2007 ten times from the surface of 2007. The past and present mass changes of Hallstätter Glacier are showing a retreating glacier as a consequence of rising temperatures. Due to high precepitation, increased with previous warming, the Hallstätter Glacier can and will exist in lower elevation compared to inner alpine glaciers.

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During two Antarctic field seasons, western Dronning Maud Land and eastern Coats Land were covered by airborne radio-echo sounding surveys, conducted in combination with magnetic and gravity measurements along the 50 NW-SE-directed tracks, totaling about 11200 km and spaced 20 km apart. The data were collected in analogue form and then processed to compile ice surface, ice thickness and bedrock topography maps in I : 2 500 000 scale which gave a new and/or more detailed information on the region than previous compilations. The maps show that western Dronning Maud Land is dominated by a large mountainous area with altitudes up to 2800 m including rock outcrops of Annandagstoppane, Borgmassivet, Kirwanveggen and Heimefrontfjella. Upland terrains of Vestfjella and Mannefallknausane have an isolated position and are surrounded by a plain with bedrock depressions of 600 m deep below sea level. A narrow strip of north-eastern Coats Land studied by radio-echo soundings exhibits a smooth subice relief with altitudes close to sea level. The structural style of bedrock topography was mostly determined by extensional tectonics.

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The algorithms designed to estimate snow water equivalent (SWE) using passive microwave measurements falter in lake-rich high-latitude environments due to the emission properties of ice covered lakes on low frequency measurements. Microwave emission models have been used to simulate brightness temperatures (Tbs) for snowpack characteristics in terrestrial environments but cannot be applied to snow on lakes because of the differing subsurface emissivities and scattering matrices present in ice. This paper examines the performance of a modified version of the Helsinki University of Technology (HUT) snow emission model that incorporates microwave emission from lake ice and sub-ice water. Inputs to the HUT model include measurements collected over brackish and freshwater lakes north of Inuvik, Northwest Territories, Canada in April 2008, consisting of snowpack (depth, density, and snow water equivalent) and lake ice (thickness and ice type). Coincident airborne radiometer measurements at a resolution of 80x100 m were used as ground-truth to evaluate the simulations. The results indicate that subsurface media are simulated best when utilizing a modeled effective grain size and a 1 mm RMS surface roughness at the ice/water interface compared to using measured grain size and a flat Fresnel reflective surface as input. Simulations at 37 GHz (vertical polarization) produce the best results compared to airborne Tbs, with a Root Mean Square Error (RMSE) of 6.2 K and 7.9 K, as well as Mean Bias Errors (MBEs) of -8.4 K and -8.8 K for brackish and freshwater sites respectively. Freshwater simulations at 6.9 and 19 GHz H exhibited low RMSE (10.53 and 6.15 K respectively) and MBE (-5.37 and 8.36 K respectively) but did not accurately simulate Tb variability (R= -0.15 and 0.01 respectively). Over brackish water, 6.9 GHz simulations had poor agreement with airborne Tbs, while 19 GHz V exhibited a low RMSE (6.15 K), MBE (-4.52 K) and improved relative agreement to airborne measurements (R = 0.47). Salinity considerations reduced 6.9 GHz errors substantially, with a drop in RMSE from 51.48 K and 57.18 K for H and V polarizations respectively, to 26.2 K and 31.6 K, although Tb variability was not well simulated. With best results at 37 GHz, HUT simulations exhibit the potential to track Tb evolution, and therefore SWE through the winter season.

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A new, third, glacier inventory (GI3) is presented for North Tyrol, which is based on Airborne Laser Scanning for the year 2006. 447 glaciers covering 235 km**2 are included. 4 small, formerly neglected glaciers have been added. Basic quantities such as size, maximum, minimum and median elevation show large variances. Very recent glacier changes between the former inventory (GI2: 1998) and GI3 show a strong reduction in area (-8%) and mean thickness (-7 m). An asymmetry of mean maximum, minimum and median elevation is quantified with approximately 200 m higher values for south-exposed glaciers. Rates of changes are around 1% per year and 1 m per year between GI2 and GI3. The strongest volume losses occurred for glaciers between 5 and 10 km**2.