Physical oceanography, pore water chemistry and water column methane turover rates during POLARSTERN cruise ANT-XXIX/4

Recent studies have suggested that the marine contribution of methane from shallow regions and melting marine terminating glaciers may have been underestimated. Here we report on methane sources and potential sinks associated with methane seeps in Cumberland Bay, South Georgia's largest fjord system. The average organic carbon content in the upper 8 meters of the sediment is around 0.65 wt.%; this observation combined with Parasound data suggest that the methane gas accumulations probably originate from peat-bearing sediments currently located several tens of meters below the seafloor. Only one of our cores indicates upward advection; instead most of the methane is transported via diffusion. Sulfate and methane flux estimates indicate that a large fraction of methane is consumed by anaerobic oxidation of methane (AOM). Carbon cycling at the sulfate-methane transition (SMT) results in a marked fractionation of the d13C-CH4 from an estimated source value of -65 per mil to a value as low as -96 per mil just below the SMT. Methane concentrations in sediments are high, especially close to the seepage sites (~40 mM); however, concentrations in the water column are relatively low (max. 58 nM) and can be observed only close to the seafloor. Methane is trapped in the lowermost water mass, however, measured microbial oxidation rates reveal very low activity with an average turnover of 3.1 years. We therefore infer that methane must be transported out of the bay in the bottom water layer. A mean sea-air flux of only 0.005 nM/m²/s confirms that almost no methane reaches the atmosphere.

Stable isotope record of foraminifera from the Barents Sea

We measured the oxygen isotopic composition of planktonic and benthic foraminifera in three cores collected at key positions to reconstruct the paleoceanography of the Barents Sea: core ASV 880 on the path of the northern branch of Atlantic water inflowing from the Arctic Ocean, core ASV 1200 in the central basin near the polar front, and core ASV 1157 in the main area of brine formation. Modern seawater d18O measurements show that far from the coast, d18O variations are linearly linked to the salinity changes associated with sea ice melting. The foraminifer d18O records are dated by 14C measurements performed on mollusk shells, and they provide a detailed reconstruction of the paleoceanographic evolution of the Barents Sea during the Holocene. Four main steps were recognized: the terminal phase of the deglaciation with melting of the main glaciers, which were located on the surrounding continent and islands, the short thermal optimum from 7.8 ka B.P. to 6.8 ka B.P., a cold mid-Holocene phase with a large reduction of the inflow of Atlantic water, and the inception of the modern hydrological pattern by 4.7 ka B.P. Brine water formation was active during the whole Holocene. The paleoclimatic evolution of the Barents Sea was driven by both high-latitude summer insolation and the intensity of the Atlantic water inflow.

Paleoceanographical studies of MIS 11 for sediment core MD99-2277

Paleoceanographical studies of Marine Isotope Stage (MIS) 11 have revealed higher-than-present sea surface temperatures (SSTs) in the North Atlantic and in parts of the Arctic, but lower-than-present SSTs in the Nordic Seas, the main throughflow-area of warm water into the Arctic Ocean. We resolve this contradiction by complementing SST data based on planktic foraminiferal abundances with surface salinity changes using hydrogen isotopic compositions of alkenones in a core from the central Nordic Seas. The data indicate the prevalence of a relatively cold, low-salinity, surface water layer in the Nordic Seas during most of MIS 11. In spite of the low-density surface layer, which was kept buoyant by continuous melting of surrounding glaciers, warmer Atlantic water was still propagating northward at the subsurface thus maintaining meridional overturning circulation. This study can help to better constrain the impact of continuous melting of Greenland and Arctic ice on high-latitude ocean circulation and climate.

Tab. 1: Proportion of glacial quartz grains contained in the deposits

The Yari-Hotaka Mountain Range is one of the most famous formerly-glaciated areas of Japan. Many glacial landforms remain in three neighbouring U-shaped valleys, named Yarisawa, Yokoo and Migimata. Moraines and outwash terraces can be classified into four groups according to their location and to the amount of glacial quartz grains contained in the deposits. A glaciation is proved for other parts of the Northern Japanese Alps before 100 000 years B.P., but not for the Yari-Hotaka Mountain Range, because the corresponding glacial landforms cannot be found here. The oldest known Ichinomata stage before and after 60 000 years B.P. corresponds to the Yokoo glacial which is proved wirhin the whole Japanese Alps. The three younger stages, Babadaira stage (before 30 000 years B.P.), Yarisawa stage I (about 30000 years B.P.) and Yarisawa stage II (about 15000 years B.P.), belong to the Karasawa glacial. About 10 000 years B.P. the glaciers melted away. At all times the relief-influence was especially important for Ihe mass-balances of Japanese glaciers. Wind-drifted snow from the west-exposed windward slopes to the slopes in eastern (lee) exposition, and a voluminous snow accumulation by avalanches from the high rocky walls onto the glacier surfaces beneath, caused very low situated glaciers as well as low equilibrium-lines. In most cases the snow-lines were situated 100 m or more above the equilibrium-lines. During the Ichinomata stage the snow-line reached an altitude of 2400-2450 m. It rose about 100 m to the Babadaira stage, 300 m to Yarisawa stage I and about 450 m to Yarisawa stage II. At present the snow-line is situated above the Northern Japanese Alps at over 4000 m. Therefore only perennial snow-patches exist. If the snow-line would go down by a few hundred meters, this region would be highly interesting Ifor studies on the beginning of mountain glaciation.

Opal chemistry of costal Antarctic sediments

During the last 50 years, the Antarctic Peninsula has experienced rapid warming with associated retreat of 87% of marine and tidewater glacier fronts. Accelerated glacial retreat and iceberg calving may have a significant impact on the freshwater and nutrient supply to the phytoplankton communities of the highly productive coastal regions. However, commonly used biogenic carbonate proxies for nutrient and salinity conditions are not preserved in sediments from coastal Antarctica. Here we describe a method for the measurement of zinc to silicon ratios in diatom opal, (Zn/Si)opal, which is a potential archive in Antarctic marine sediments. A core top calibration from the West Antarctic Peninsula shows (Zn/Si)opal is a proxy for mixed layer salinity. We present down-core (Zn/Si)opal paleosalinity records from two rapidly accumulating sites taken from nearshore environments off the West Antarctic Peninsula which show an increase in meltwater input in recent decades. Our records show that the recent melting in this region is unprecedented for over 120 years.

(Table 1) Luminescence datings from Varchushka and Pyoza rivers, Russia

The Pyoza River area in the Arkhangelsk district exposes sedimentary sequences suitable for study of the interaction between consecutive Valdaian ice sheets in Northern Russia. Lithostratigraphic investigations combined with luminescence dating have revealed new evidence on the Late Pleistocene history of the area. Overlying glacigenic deposits of the Moscowian (Saalian) glaciation marine deposits previously confined to three separate transgression phases have all been connected to the Mikulinian (Eemian) interglacial. Early Valdaian (E. Weichselian) proglacial, lacustrine and fluvial deposits indicate glaciation to the east or north and consequently glacier damming and meltwater run-off in the Pyoza area around 90-110 ka BP. Interstadial conditions with forest-steppe tundra vegetation and lacustrine and fluvial deposition prevailed at the end of the Early Valdaian around 75-95 ka BP. A terrestrial-based glaciation from easterly uplands reached the Pyoza area at the Early to Middle Valdaian transition around 65-75 ka BP and deposited glaciofluvial strata and subglacial till (Yolkino Till). During deglaciation, laterally extensive glaciolacustrine sediments were deposited in ice-dammed lakes in the early Middle Valdaian around 55-75 ka BP. The Barents-Kara Sea ice sheet deposited the Viryuga Till on the lower Pyoza from northerly directions. The ice sheet formed the Pyoza marginal moraines, which can be correlated with the Markhida moraines further east, and proglacial lacustrine deposition persisted in the area during the first part of the Middle Valdaian. Glacio-isostatic uplift caused erosion followed by pedogenesis and the formation of a deflation horizon in the Middle Valdaian. Widely dispersed periglacial river plains were formed during the Late Valdaian around 10-20 ka BP. Thus, the evidence of a terrestrial-based ice sheet from easterly uplands in the Pyoza area suggests that local piedmont glaciers situated in highlands such as the Timan Ridge or the Urals could have developed into larger, regionally confined ice sheets. Two phases of ice damming and development of proglacial lakes occurred during the Early and Middle Valdaian. The region did not experience glaciation during the Late Valdaian.

Firn line elevation of the Dickson Land peninsula

The Dickson Land peninsula is located in central West-Spitsbergen between the NNE branches of Isfjorden. The climatic firn line lying at 500 m causes plateau glaciers with outlet tongues which are characteristic of S-Dickson Land. The distribution of valley glaciers and the variations of the orographic firn line depend on wind direction. In comparing the firn lines established by the methods of LICHTENECKER (1938) and VISSER (1938), to the values calculated by the method of v. HÖFER (1879), differences of up to l07 m are found. These differences may depend on the inclination and distance relationships of the glaciers above and below the real firn lines. During the latest glacial advance, Dickson Land was located on the peripheries of two local glaciation centers. At that time an inland glaciation of West-Spitsbergen did not exist . The formation of a subglacial channel system dates back to the maximum extent of the late glacial phase before 17500 B.P, (+2000/-1375 years). A correlation of postglacial stadia and 14C dated marine terraces (FEYLING-HANSSEN & OLSSON, 1960; FEYLING-HANSSEN, 1965) is possible. Considering isostatic movement and the difference between calculated and real firn lines, a postglacial stadium at about 10400 B. P. can be reconstructed with a firn line lying 265 m above former sea level. On average, the absolute depression below the recent firn line amounted to 246 m. Stagnation at 9650 B.P. coincided with a firn line at 315 m above former sea level and a depression of 173 m. Around 1890 A.D., glacial fluctuations corresponded to a firn line at 415 m (depression: 64 m). To some extent the morphology of the main valleys appears to depend on structure and petrography. Therefore their value as indicators of former glaciations is questionable. The periglacial forms are shown on a large-scale map. At the time of the "Holocene warm interval", between 7000 and 2000 B.P. (FEYLING-HANSSEN, 1955a, 1965), an increase of periglacial activity seems likely. This can be explained by a simultaneous increase in the depth of the active layer in both soil and bedrock.

(Table 1) Mass loss of the Greenland Ice Sheet

Using satellite radar interferometry observations of Greenland, we detected widespread glacier acceleration below 66° north between 1996 and 2000, which rapidly expanded to 70° north in 2005. Accelerated ice discharge in the west and particularly in the east doubled the ice sheet mass deficit in the last decade from 90 to 220 cubic kilometers per year. As more glaciers accelerate farther north, the contribution of Greenland to sea-level rise will continue to increase.

Carbonate sedimentation beneath the Carlifornia Current system

A north-south transect of 17 cores was constructed along the eastern boundary of the California Current system from 33° to 42°N to investigate the changes in biogenic sedimentation over the past 30 kyr. Percentages and mass accumulation rates of CaCO3, Corg, and biogenic opal were assembled at 500 to 1000 years/sample to provide relatively high resolution. Time-space maps reveal a complex pattern of changes that do not follow a simple glacial-interglacial two-mode model. Biogenic sedimentation shows responses that are sometimes time-transgressive and sometimes coeval, and most of the responses show more consistency within a limited geographic area than any temporal consistency. Reconstructed conditions during late oxygen isotope stage 3 were more like early Holocene conditions than any other time during the last 30 kyr. Coastal upwelling and productivity during oxygen isotope stage 3 were relatively strong along the central California margin but were weak along the northern California margin. Precipitation increased during the last glacial interval in the central California region, and the waters of the southern California margin had relatively low productivity. Productivity on the southern Oregon margin was relatively low at the beginning of the last glacial interval, but by about 20 ka, productivity in this area significantly increased. This change suggests that the center of the divergence of the West Wind Drift shifted south at this time. The end of the last glacial interval was characterized by increased productivity in the southern California margin and increased upwelling along the central California margin but upwelling remained weak along the northern California margin. A sudden (<300 years) decrease in CaCO3, Corg, and biogenic opal occurred at 13 ka. The changes suggest a major reorientation of the atmospheric circulation in the North Pacific and western North America and the establishment of a strong seasonality in the central California region. A carbonate preservation event occurred at 10 ka that appears to reflect the uptake of CO2 by the terrestrial biosphere as the northern latitudes were reforested following retreat of the glaciers. The Holocene has been a period of relatively high productivity in the southern California margin, relatively strong coastal upwelling along the central California margin, relatively weak upwelling along the northern California margin, and the northward migration of the divergence zone of the West Wind Drift.

Occurrence of microtextures recorded from quartz sand grains of ODP Hole 178-1101A (Table 1)

Sediment drifts on the continental rise are located proximal to the western side of the Antarctic Peninsula and recorded changes in glacial volume and thermal regime over the last ca. 15 m.y. At Ocean Drilling Program (ODP) Site 1101 (Leg 178), which recovered sediments back to 3.1 Ma, glacial-interglacial cyclicity was identified based on the biogenic component and sedimentary structures observed in X-radiographs, magnetic susceptibility and lithofacies descriptions. Glacial intervals are dominated by fine-grained laminated mud and interglacial units consist of bioturbated muds enriched in biogenic components. From 2.2 to 0.76 Ma, planktonic foraminifera and calcareous nannofossils dominate in the interglacials suggesting a shift of the Antarctic Polar Front (APF) to the south near the drifts. Prior to 2.2 Ma, cyclicity cannot be identified and diatoms dominate the biogenic component and high percent opal suggests warmer conditions south of the APF and reduced sea ice over the drifts. Analyses of the coarse-grained terrigenous fraction (pebbles and coarse sand) from Sites 1096 and 1101 record glaciers at sea-level releasing iceberg-rafted debris (IRD) throughout the last 3.1 m.y. Analyses of quartz sand grains in IRD with the scanning electron microscope (SEM) show an abrupt change in the frequency of occurrence of microtextures at ~1.35 Ma. During the Late Pliocene to Early Pleistocene, the population of quartz grains included completely weathered grains and a low frequency of crushing and abrasion, suggesting that glaciers were small and did not inundate the topography. Debris shed from mountain peaks was transported supraglacially or englacially allowing weathered grains to pass through the glacier unmodified. During glacial periods from 1.35-0.76 Ma, glaciers expanded in size. The IRD flux was very high and dropstones have diverse lithologies. Conditions resembling those at the Last Glacial Maximum (LGM) have been episodically present on the Antarctic Peninsula since ~0.76 Ma. Quartz sand grains show high relief, fracture and abrasion common under thick ice and the IRD flux is low with a more restricted range of dropstone lithologies.