Element concentrations and stable isotope record of planktonic foraminifera of sediment cores from the northeastern Brazilian Continental Margin

Detailed 14C AMS data and isotope based stratigraphies from high-resolution paleoceanographic records for the last 22 ka of cores from the upper continental slope off NE Brazil reveal sedimentation rates of up to 100 cm per 1000 yr. Variations in the sediment composition relate to changes in the input of terrigenous material. The sedimentation is controlled by sea level and by the climatic regime of the hinterland. Short-term changes in the tropical wind field may act as a climatic trigger. The zonality of the SE trades was probably increased and the monsoonal activity over Africa reduced during the Younger Dryas period.

Age determination and stable isotope ratios of three sediment cores from the Great Belt

The marine transgression Into the Baltic Sea through the Great Belt took place around 9,370 calibrated C-14-years B.P. The sedimentary sequence from the early brackish phase and the change to marine conditions has been investigated in detail through C-14-datings, and oxygen and carbon isotope measurements, and is interpreted by comparison with modern analogs. The oldest brackish sediments are the strongly laminated clays and silts rich in organic carbon followed by non-laminated heavily bioturbated silts. The bedding and textural characteristics and stable isotope analyses on Ammonia beccarii (dextral) and A. beccarii (sinistral) show that the deposltlonal conditions respond to a change at about 9,100 cal. a B.P. from an unstratified brackish water environment in the initial stage of the Littorina Transgression to a thermohaline layered milieu in the upper unit. The oxygen isotope results indicate that the bottom waters of this latter period had salinities and temperatures comparable to the present day Kiel Bay waters. The isotopic composition of the total organic carbon and the d13C-values of A. beccarii reveal a gradual change from an initially lacustrine/terrestrial provenance toward a brackish/marine dominated depositional environment. A stagnation of the sea level at around 9,100 to 9,400 B.P. is indicated.

Stable isotope stacks from GRIP and GISP ice cores

Recent efforts to link the isotopic composition of snow in Greenland with meteorological and climatic parameters have indicated that relatively local information such as observed annual temperatures from coastal Greenland sites, as well as more synoptic scale features such as the North Atlantic Oscillation (NAO) and the temperature seesaw between Jakobshaven, Greenland, and Oslo, Norway, are significantly correlated with d18O and dD values from the past few hundred years measured in ice cores. In this study we review those efforts and then use a new record of isotope values from the Greenland Ice Sheet Project 2 and Greenland Ice Core Project sites at Summit, Greenland, to compare with meteorological and climatic parameters. This new record consists of six individual annually resolved isotopic records which have been average to produce a Summit stacked isotope record. The stacked record is significantly correlated with local Greenland temperatures over the past century (r=0.471), as well as a number of other records including temperatures and pressures from specific locations as well as temperature and pressure patterns such as the temperature seesaw and the North Atlantic Oscillation. A multiple linear regression of the stacked isotope record with a number of meteorological and climatic parameters in the North Atlantic region reveals that five variables contribute significantly to the variance in the isotope record: winter NAO, solar irradiance (as recorded by sunspot numbers), average Greenland coastal temperature, sea surface temperature in the moisture source region for Summit (30°-20°N), and the annual temperature seesaw between Jakobshaven and Oslo. Combined, these variables yield a correlation coefficient of r=0.71, explaining half of the variance in the stacked isotope record.

Mineralogy, lithology and stable isotope composition of diagenetic siliceous rocks from ODP Leg 129 sites

Ocean Drilling Program Leg 129 recovered chert, porcellanite, and radiolarite from Middle Jurassic to lower Miocene strata from the western Pacific that formed by different processes and within distinct host rocks. These cherts and porcellanites formed by (1) replacement of chalk or limestone, (2) silicification and in-situ silica phase-transformation of bedded clay-bearing biosiliceous deposits, (3) high-temperature silicification adjacent to volcanic flows or sills, and (4) silica phase-transformation of mixed biosiliceous-volcaniclastic sediments. Petrologic and O-isotopic studies highlight the key importance of permeability and time in controlling the formation of dense cherts and porcellanites. The formation of dense, vitreous cherts apparently requires the local addition and concentration of silica. The influence of permeability is shown by two examples, in which: (1) fragments of originally identical radiolarite that were differentially isolated from pore-water circulation by cement-filled fractures were silicified to different degrees, and (2) by the development of secondary porosity during the opal-CT to quartz inversion within conditions of negligible permeability. The importance of time is shown by the presence of quartz chert below, but not above, a Paleogene hiatus at Site 802, indicating that between 30 and 52 m.y. was required for the formation of quartz chert within calcareous-siliceous sediments. The oxygen-isotopic composition for all Leg 129 carbonate- and Fe/Mn-oxide-free whole-rock samples of chert and porcellanite range widely from d18O = 27.8 per mil to 39.8 per mil vs. V-SMOW. Opal-CT samples are consistently richer in 18O (34.1 per mil to 39.3 per mil) than quartz subsamples (27.8 per mil to 35.7 per mil). Using the O-isotopic fractionation expression for quartz-water of Knauth and Epstein (1976) and assuming d18Opore water = -1.0 per mil, model temperatures of formation are 7°-26°C for carbonate-replacement quartz cherts, 22°-25°C for bedded quartz cherts, and 32°-34°C for thermal quartz cherts. Large variations in O-isotopic composition exist at the same burial depth between co-existing silica phases in the same sample and within the same phase in adjacent lithologies. For example, quartz has a wide range of isotopic compositions within a single breccia sample; d18O = 33.4 per mil and 28.0 per mil for early and late stages of fracture-filling cementation, and 31.6 per mil and 30.2 per mil for microcrystalline quartz precipitation within enclosed chert and radiolarite fragments. Similarly, opal-CT d101 spacing varies across lithologic or diagenetic boundaries within single samples. Co-occurring opal-CT and chalcedonic quartz in shallowly buried chert and porcellanite from Sites 800 and 801 have an 8.7 per mil difference in d18O, suggesting that pore waters in the Pigafetta Basin underwent a Tertiary shift to strongly 18O-depleted values due to alteration of underlying Aptian to Albian-Cenomanian volcaniclastic deposits after opal-CT precipitation, but prior to precipitation of microfossil-filling chalcedony.

High resolution stable isotope and Mg/Ca record of sediment core MD02-2550C2

An early Holocene record from the Gulf of Mexico (GOM) reveals climatic and hydrologic changes during the interval from 10.5 to 7 thousand calendar years before present from paired analyses of Mg/Ca and d18O on foraminiferal calcite. The sea surface temperature record based on foraminiferal Mg/Ca contains six oscillations and an overall ~1.5°C warming that appears to be similar to the September-March insolation difference. The d18O of seawater in the GOM (d18OGOM) record contains six oscillations, including a -0.8 per mil excursion that may be associated with the "8.2 ka climate event" or a broader climate anomaly. Faunal census records from three GOM cores exhibit similar changes, suggesting subcentennial-scale variability in the incursions of Caribbean waters into the GOM. Overall, our results provide evidence that the subtropics were characterized by decadal- to centennial-scale climatic and hydrologic variability during the early Holocene.

Stable isotope ratios and organic carbon accumulation rates of late Pleistocene sediments of ODP Hole 117-724C

Stable isotope records of coexisting benthic foraminifers Uvigerina spp. and Cibicidoides spp. and planktonic G. ruber (white variety) from Site 724 are used to study the late Pleistocene evolution of surface and intermediate water hydrography (593 m water depth) at the Oman Margin. Glacial-interglacial d18O amplitudes recorded by the benthic foraminifers are reduced when compared to the estimated mean ocean changes of d18Oseawater . Epibenthic d13C remains at its modern level or is increased during glacial times. This implies that Red Sea outflow waters which are enriched in d18Oseawater and d13C (Sum CO2) have been replaced during glacial periods by intermediate waters still positive in d13C (Sum CO2) but more negative in d18Oseawater. Glacial-interglacial amplitudes of the planktonic d18O record exceed those of the mean ocean d18Oseawater variation and imply decreased surface water temperatures (SST) during glacial times. Throughout most of the records these cooling events correlate with enhanced rates of carbon accumulation. However, both negative (colder) SST and positive Corg accumulation rate anomalies do not correlate with potential physical upwelling maxima as inferred from the orbital monsoon index. This is in conflict with the established hypothesis that upwelling in the estern Arabia Sea should be strongest during maxima of the southwest monsoon.

Magnetobiostratigraphy and stable isotope record of Paleocene sediments from ODP Hole 122-761B in the subtropical Indian Ocean

Surface and deep water circulation patterns in the eastern Indian Ocean during the Paleocene Epoch are inferred based on an integrated magnetobiostratigraphic and stable isotope investigation of Ocean Drilling Program Hole 761B, drilled on the Wombat Plateau. A combination of magnetostratigraphy, biostratigraphy and isotope stratigraphy demonstrates that numerous deep sea sites that have been considered to show continuous, or nearly continuous sedimentation through the Paleocene are punctuated by a series of hiatuses, some of which exceeding a duration of 1 Myr. Therefore, our study is based on a detailed temporal interpretation of the stratigraphic successions we used for paleoceanographic reconstructions. We compare detailed planktonic and benthic foraminiferal carbon and oxygen isotope records from Hole 761B with several temporally correlative records published from different oceanic provinces in order to distinguish between local and global patterns within the eastern Indian Ocean. Although Site 761 was situated at low latitudes during the Paleocene, its surface waters were predominantly influenced by circulation originating from the Southern Ocean as indicated by inferred cool sea surface temperatures and reduced surface to deep water temperature gradients. We suggest that deep waters in the eastern Indian Ocean were not directly fed by the Southern or Tethys Oceans. Rather, the more negative delta13C composition of the bottom waters recorded by benthic foraminifera implies the presence and/or active contribution of aged deep waters from the Pacific during this time, at least prior to ~60.2 Ma and subsequent to ~59.0 Ma. The Indian continent, Ninetyeast Ridge, Kerguelen Plateau and Broken Ridge may have played a significant role as submarine barriers to deep water circulation during the Paleocene.