Age models, iron intensity, magnetic susceptibility records and dry bulk density of sediment cores from around the Canary Islands

A set of 43 sediment cores from around the Canary Islands is used to characterise this region, which intersects meridional climatic regimes and zonal productivity gradients in a high spatial resolution. Using rapid and nondestructive core logging techniques we carried out Fe intensity and magnetic susceptibility (MS) measurements and created a stack on the basis of five stratigraphic reference cores, for which a stratigraphic age model was available from d18O and 14C analyses on planktonic foraminifera. By correlation of the stack with the Fe and MS records of the other cores, we were able to develop age depth models at all investigated sites of the region. We present the bulk sediment accumulation rates (AR) of the Canary Islands region as an indicator of shifts in the upwelling-influenced areas for the Holocene (0-12 ky), the deglaciation (12-18 ky) and the last glacial (18-40 ky). General observations are an enhanced productivity during glacial times with highest values during the deglaciation. The main differences between the analysed time intervals we interpret as result of the sea-level effects, changes in the extent of high productivity areas, and current intensity.

(Table 2) Depth-age control points of ODP Site 177-1090

At Ocean Drilling Program (ODP) Site 1090 on the Agulhas Ridge (subantarctic South Atlantic) benthic foraminiferal stable isotope records span the late Oligocene through the early Miocene (25~16 Ma) at a temporal resolution of ?10 kyr. In the same time interval a magnetic polarity stratigraphy can be unequivocally correlated to the geomagnetic polarity timescale (GPTS), thereby providing secure correlation of the isotope record to the GPTS. On the basis of the isotope-magnetostratigraphic correlation we provide refined age calibration of established oxygen isotope events Mi1 through Mi2 as well as several other distinctive isotope events. Our data suggest that the d18O maximum commonly associated with the Oligocene/Miocene (O/M) boundary falls within C6Cn.2r (23.86 Ma). The d13C maximum coincides, within the temporal resolution of our record, with C6Cn.2n/r boundary and hence to the O/M boundary. Comparison of the stable isotope record from ODP Site 1090 to the orbitally tuned stable isotope record from ODP Site 929 across the O/M boundary shows that variability in the two records is very similar and can be correlated at and below the O/M boundary. Site 1090 stable isotope records also provide the first deep Southern Ocean end-member for reconstructions of circulation patterns and late Oligocene to early Miocene climate change. Comparison to previously published records suggests that basin to basin carbon isotope gradients were small or nonexistent and are inconclusive with respect to the direction of deep water flow. Oxygen isotope gradients between sites suggest that the deep Southern Ocean was cold in comparison to the North Atlantic, Indian, and the Pacific Oceans. Dominance of cold Southern Component Deep Water at Site 1090, at least until 17 Ma, suggests that relatively cold circumpolar climatic conditions prevailed during the late Oligocene and early Miocene. We believe that a relatively cold Southern Ocean reflects unrestricted circumpolar flow through the Drake Passage in agreement with bathymetric reconstructions.

Carbon isotope record of 3 profiles from Campanian-Maastrichtian

Carbon-isotope stratigraphy has proven to be a powerful tool in the global correlation of Cretaceous successions. Here we present new, high-resolution carbon-isotope records for the Global Boundary Stratotype Section and Point (GSSP) of the Maastrichtian stage at Tercis les Bains (France), the Bottaccione and Contessa sections at Gubbio (Italy), and the coastal sections at Norfolk (UK) to provide a global d13C correlation between shelf-sea and oceanic sites. The new d13C records are correlated with d13C-stratigraphies of the boreal chalk sea (Trunch borehole, Norfolk, UK, Lägerdorf-Kronsmoor-Hemmoor section, northern Germany, Stevns-1 core, Denmark), the tropical Pacific (ODP-Hole 1210B, Shatsky Rise) and the South Atlantic and Southern Ocean (DSDP Hole 525A, ODP Hole 690C) by using an assembled Gubbio d13C record as a reference curve. The global correlation allows the identification of significant high-frequency d13C variations that occur superimposed on prominent Campanian-Maastrichtian events, namely the Late Campanian Event (LCE), the Campanian-Maastrichtian Boundary Event (CMBE), the mid-Maastrichtian Event (MME), and the Cretaceous-Paleogene transition (KPgE). The carbon-isotope events are correlated with the geomagnetic polarity scale recalculated using the astronomical 40Ar/39Ar calibration of the Fish Canyon sanidine. This technique allows the evaluation of the relative timing of base occurrences of stratigraphic index fossils such as ammonites, planktonic foraminifera and calcareous nannofossils. Furthermore, the Campanian-Maastrichtian boundary, as defined in the stratotype at Tercis, can be precisely positioned relative to carbon-isotope stratigraphy and the geomagnetic polarity timescale. The average value for the age of the Campanian-Maastrichtian boundary is 72.1 ± 0.1 Ma, estimated by three independent approaches that utilize the Fish Canyon sanidine calibration and Option 2 of the Maastrichtian astronomical timescale. The CMBE covers a time span of 2.5 Myr and reflects changes in the global carbon cycle probably related to tectonic processes than to glacioeustasy. The duration of the high-frequency d13C variations instead coincides with the frequency band of long eccentricity, indicative of orbital forcing of changes in climate and the global carbon cycle.

Planktonic foraminiferal stratigraphy, datum levels and ages of ODP Sites 184-1146 and 184-1148, South China Sea

Over 30 first and last occurrence (FO and LO, respectively) planktonic foraminifer datums were recognized from the Oligocene-Miocene section of Ocean Drilling Program (ODP) Site 1148. Most datum levels occur in similar order as, and are by correlation as probably synchronous with, their open-ocean records. Several datum levels represent local bioevents resulting from dissolution and Site 1148's unique paleoceanographic setting in the northern South China Sea. An age of 9.5-9.8 Ma is estimated for the local LO of Globoquadrina dehiscens (257 meters composite depth [mcd]), whereas the local LO of Globorotalia fohsi s.l. (301 mcd) is projected to be at ~13.0 Ma and the local FO of Globigerinatella insueta (367 mcd) is projected to be at ~18.0 Ma. The combined planktonic foraminifer and nannofossil results indicate that the Oligocene-Miocene section at Site 1148 is not complete. Unconformities up to 2-3 m.y. in duration, occurring at and before the Oligocene/Miocene boundary (OHS1, OHS2, OHS3, and OHS4 = MHS1), are associated with slump deposits between 457 and 495 mcd that signal tectonic instability during the transition from rifting to spreading in the South China Sea. Shorter unconformities of <0.5 m.y. duration that truncate the Miocene section were more likely to have been caused by sea-bottom erosion as well as dissolution. A total of 12 Miocene unconformities, MHS1 through MHS12, are mainly affected by dissolution and an elevated carbonate compensation depth (CCD) during Miocene third-order glaciations recorded in deep-sea positive oxygen isotope Mi glaciation events. Respectively, they fall at ~457 mcd (MHS1 = Mi-1), 407 mcd (MHS2 = Mi-1a), 385 mcd (MHS3 = Mi-1aa), 366 mcd (MHS4 = Mi-1b), 358 mcd (MHS5 = MLi-1), 333 mcd (MHS6 = Mi-2), 318 mcd (MHS7 = MSi-1), 308 mcd (MHS8 = Mi-3), 295 mcd (MHS9 = Mi-4), 288 mcd (MHS10 = Mi-5), 256 mcd (MHS11 = Mi-6), and 250 mcd (MHS12 = Mi-7). The correlation of these unconformities with Mi events indicates that some related driving mechanisms have been operating, causing deepwater circulation changes concomitantly in world oceans and in the marginal South China Sea.

Pollen profile of sediment core Dethlingen, Germany

To better understand the environmental variability during the Holsteinian interglacial, we have palynologically analyzed a new core from Dethlingen, northern Germany, at a decadal resolution. Our data provide insights into the vegetation dynamics and thus also climate variability during the meso- to telocratic forest phases of the interglacial. Temperate mixed forests dominated the regional landscape throughout the Holsteinian. However, changes in the forest composition during the younger stages of the interglacial suggest a climatic transition towards milder conditions in winter. The strong presence of boreal floral elements during the older stages of the Holsteinian interglacial suggests a high seasonality. In contrast, during the younger stages the development of sub-Atlantic and Atlantic floral elements suggests increasingly warm and humid climatic conditions. Peak warming during the younger stage of the Holsteinian is marked by the maximum pollen abundances of Buxus, Abies, and Quercus. Although the vegetation dynamics suggest a general warming trend throughout the Holsteinian interglacial, abrupt as well as gradual changes in the relative abundances of temperate plants indicate considerable climatic variability. In particular, two marked declines in temperate taxa leading to the transient development of boreal and sub-temperate forests indicate short-term climatic oscillations that occurred within full interglacial conditions. The palynological signatures of these two regressive phases in vegetation development differ with regard to the expansion of pioneer trees, the abundances and rates of change of temperate taxa, and the presence of frost-sensitive taxa. These differences point to different mechanisms responsible for the individual regressive phases. Assuming a correlation of the interglacial at Dethlingen with Marine Isotope Stage (MIS) 11, our data suggest that temperate forests prevailed in northern Germany during the younger parts of MIS 11c.

Stable carbon and nitrogen isotope composition of organic matter in sediments of the Oman Margin

Stable isotopic compositions of carbon and nitrogen and organic carbon content of sediments ranging from the Pliocene to the Pleistocene-Holocene in age from the Oman Margin (ODP Sites 724 and 725) are reported. In general, the organic carbon content is greater than 2% at Site 724. Prior to the Pleistocene-Holocene at this site, sediments with higher content of organic matter were deposited owing to favorable preservation conditions and/or higher productivity. In the Pleistocene, lower amounts of organic matter have been preserved; this material generally has more enriched nitrogen isotopic compositions. This may indicate intensification of the Oxygen Minimum Zone and denitrification with the onset of the Pleistocene. A correlation of carbon isotope content of these sediments with oxygen isotope stages at Site 724 indicates an enrichment in 13C during glacial events. Based on the stable isotope evidence of both carbon and nitrogen, there does not appear to be major input of terrigenous-derived allochthonous material in this marine environment. The timing and extent of monsoon winds on the productivity of this region are not evident, but require further studies for collaborative interpretation of small-scale features in the isotopic and carbon content of this environment.

(Fig. 1) Stable carbon and oxygen isotope ratios of foraminifera of ODP Hole 113-690B

A remarkable oxygen and carbon isotope excursion occurred in Antarctic waters near the end of the Palaeocene (~57.33 Myr ago), indicating rapid global warming and oceanographic changes that caused one of the largest deep-sea benthic extinctions of the past 90 million years. In contrast, the oceanic plankton were largely unaffected, implying a decoupling of the deep and shallow ecosystems. The data suggest that for a few thousand years, ocean circulation underwent fundamental changes producing a transient state that, although brief, had long-term effects on environmental and biotic evolution.

Beryllium-10, mineralogy and grain size distribution of DSDP Hole 68-502B (Table 1)

We present a high-resolution 10Be profile from deep sea sediments (sampled from Hole 502B in the Caribbean sea) that strongly resembles the 10Be record in ice core profiles, particularly the Vostok core from Antarctica. This high-resolution profile revealed occurrences of enhanced 10Be concentrations at about 23-24, 37-39 and 60-65 ka. The excellent match between these peaks appearing in a georeservoir profile other than in polar ice, strengthens the implications that can be inferred from 10Be and provide global markers for chronological correlation of climatic events. The position at low latitude of the studied sediment section is, unlike the case with the high latitude polar regions, excellent for exposing causes of modulation in 10Be production. We interpret the source of the pattern and enhancements, particularly the 37-39 ka peak, of 10Be to be global and do not strictly relate to climatic conditions and/or production rates specific to the polar regions.

(Table 2) Age model of ODP Site 184-1146

Orbital tuning of benthic d18O is a common approach for assigning ages to ocean sediment records. Similar environmental forcing of the northern South China Sea and the southeast Asian cave regions allows for transfer of the speleothem d18O radiometric chronology to the planktonic and benthic d18O records from Ocean Drilling Program Site 1146, yielding a new chronology with 41 radiometrically calibrated datums, spanning the past 350 kyr. This approach also provides for an independent assessment of the accuracy of the orbitally tuned benthic d18O chronology for the last 350 kyr. The largest differences relative to the latest chronology occur in marine isotope stages (MIS) 5.4, 5.5, 6, 7, and 9.3. Prominent suborbital-scale structure believed to be global in nature is identified within MIS 5.4 and MIS 7.2. On the basis of the radiometrically calibrated chronology, the time constant of the ice sheet is found to be 5.4 kyr at the precession band (light d18O lags precession minima by -55.4°) and 10.4 kyr at the obliquity band (light d18O lags obliquity maxima by 57.4°). These values are significantly shorter than the single 17 kyr time constant originally estimated by Imbrie et al. (1984), based primarily on the timing of terminations I and II and the 15 kyr time constant used by Lisiecki and Raymo (2005, doi:10.1029/2004PA001071).

Major and trace element concentration of melt inclusions from Zhupanovsky volcano, Kamchatka

The paper presents data on naturally quenched melt inclusions in olivine (Fo 69-84) from Late Pleistocene pyroclastic rocks of Zhupanovsky volcano in the frontal zone of the Eastern Volcanic Belt of Kamchatka. The composition of the melt inclusions provides insight into the latest crystallization stages (~70% crystallization) of the parental melt (~46.4 wt % SiO2, ~2.5 wt % H2O, ~0.3 wt % S), which proceeded at decompression and started at a depth of approximately 10 km from the surface. The crystallization temperature was estimated at 1100 ± 20°C at an oxygen fugacity of deltaFMQ = 0.9-1.7. The melts evolved due to the simultaneous crystallization of olivine, plagioclase, pyroxene, chromite, and magnetite (Ol: Pl: Cpx : (Crt-Mt) ~ 13 : 54 : 24 : 4) along the tholeiite evolutionary trend and became progressively enriched in FeO, SiO2, Na2O, and K2O and depleted in MgO, CaO, and Al2O3. Melt crystallization was associated with the segregation of fluid rich in S-bearing compounds and, to a lesser extent, in H2O and Cl. The primary melt of Zhupanovsky volcano (whose composition was estimated from data on the most primitive melt inclusions) had a composition of low-Si (~45 wt % SiO2) picrobasalt (~14 wt % MgO), as is typical of parental melts in Kamchatka and other island arcs, and was different from MORB. This primary melt could be derived by ~8% melting of mantle peridotite of composition close to the MORB source, under pressures of 1.5 ± 0.2 GPa and temperatures 20-30°C lower than the solidus temperature of 'dry' peridotite (1230-1240°C). Melting was induced by the interaction of the hot peridotite with a hydrous component that was brought to the mantle from the subducted slab and was also responsible for the enrichment of the Zhupanovsky magmas in LREE, LILE, B, Cl, Th, U, and Pb. The hydrous component in the magma source of Zhupanovsky volcano was produced by the partial slab melting under water-saturated conditions at temperatures of 760-810°C and pressures of ~3.5 GPa. As the depth of the subducted slab beneath Kamchatkan volcanoes varies from 100 to 125 km, the composition of the hydrous component drastically changes from relatively low-temperature H2O-rich fluid to higher temperature H2O-bearing melt. The geothermal gradient at the surface of the slab within the depth range of 100-125 km beneath Kamchatka was estimated at 4°C/km.

Cretaceous nannofossils of southeast France

The Aptian-lower Albian succession of the Vocontian Basin (SE France) consists of marine hemipelagic sediments including several black shale horizons. The latter are partly of regional and partly of global distribution. This sedimentary succession records the nannoplankton evolution of the Aptian-early Albian interval and thus provides an excellent opportunity to calibrate the calcareous nannofossil record with Tethyan ammonite and planktic foraminiferal biostratigraphy. The calcareous nannofossil biostratigraphy presented in this paper supports previous zonations, but it also provides a much higher resolution and thus improves the correlation of different black shale horizons on a supraregional scale. Up to 23 major (supraregionally significant) and minor (regionally significant) first and last occurrences of calcareous nannofossil taxa are recognized. Nannoconid abundances decrease rapidly in the upper Lower Aptian (nannoconid crisis I, NCI) and in the middle Upper Aptian (nannoconid crisis II, NCII). Both decreases correlate with carbonate-platform drowning events. The upper Lower Aptian interval above the NCI is characterized by high abundances of large specimens of Assipetra infracretacea and Rucinolithus terebrodentarius probably of supraregional significance. The uppermost Aptian-Lower Albian is characterized by high abundances of the calcareous nannoplankton taxon Repagulum parvidentatum, reflecting boreal influence on the Tethyan Realm. This suggests a temporary decrease in surface-water temperatures in the Vocontian Basin.