Geochemical processes and rare earth element analysis in cold-seep pore waters of Hydrate Ridge, northeast Pacific Ocean

The concentrations of rare earth elements (REEs), sulphate, hydrogen sulphide, total alkalinity, calcium, magnesium and phosphate were measured in shallow (<12 cm below seafloor) pore waters from cold-seep sediments on the northern and southern summits of Hydrate Ridge, offshore Oregon. Downward-decreasing sulphate and coevally increasing sulphide concentrations reveal sulphate reductionas dominant early diagenetic process from ~2 cm depth downwards. A strong increase of total dissolved REE concentrations is evident immediately below the sediment-water interface, which can be related to early diagenetic release of REEs into pore water resulting from the remineralization of particulate organic matter. The highest pore water REE concentrations were measured close to the sediment-water interface at ~2 cm depth. Distinct shale normalized REE patterns point to particulate organic matter and iron oxides as main REE sources in the upper ~2-cm depth interval. In general, the pore waters have shalenormalized patterns reflecting heavy REE (HREE) enrichment, which suggests preferential complexation of HREEs with carbonate ions. Below ~2 cm depth, a downward decrease in REE correlates with a decrease in pore water calcium concentrations. At this depth, the anaerobic oxidation of methane (AOM) coupled to sulphate reduction increases carbonate alkalinity through the production of bicarbonate, which results in the precipitation of carbonate minerals. It seems therefore likely that the REEs and calcium are consumed during vast AOM-induced precipitation of carbonate in shallow Hydrate Ridge sediments. The analysis of pore waters from Hydrate Ridge shed new light on early diagenetic processes at cold seeps, corroborating the great potential of REEs to identify geochemical processes and to constrain environmental conditions.

Fossil datums of Late Neogene sediments from the Southwest Pacific Ocean

The assumption of synchrony of first and last occurrences of fossil taxa can be tested using graphic correlation procedures which, by allowing measured stratigraphic sections to be compared on a common depth scale, make it possible to develop a correlation model which integrates information from a number of cores. The strategy of the test presented here is to use a graphic correlation model that is based on data from the Atlantic (Deep Sea Drilling Project (DSDP) sites 502, 516A) and north Pacific (DSDP site 577A) as a basis for determining to what extent fossil datums in the southwest Pacific are synchronous. First and last occurrences of Pliocene calcareous nannofossils and planktonic foraminifers have been compared in five DSDP cores from the southwest Pacific ocean (sites 586, 587, 588, 590A, and 592). All cores were recovered using hydraulic piston coring technology, which assures the best recovery and minimal disturbance. Most of these cores contain abundant, well-preserved foraminifers and nannofossils, as well as a partial record of many of the expected magnetic polarity reversals in this part of the section. To assure taxonomic consistency, all taxonomic identifications were made by the author. Graphic correlation of this data set suggests that several important biostratigraphic markers are highly diachronous. For example, this study confirms that Globorotalia truncatulinoides first occurs at approximately 2.4 Ma between 20° and 35° south latitude in the southwest Pacific, approximately 0.5 m.y. earlier than it is found elsewhere in the Atlantic and Pacific. Other datums, such as the last occurrence of Discoaster brouweri, are essentially synchronous. These findings suggest that biostratigraphic models based on the assumption of synchrony of first and last occurrences of fossil taxa may be incorrect. Biostratigraphic models created with the Graphic Correlation method offer an opportunity to examine the biogeographic dimensions of origination, migration, and extinction of planktonic taxa.

Chemistry on manganese nodules from the Pacific Ocean

Three manganese nodules from the Pacific Ocean have been analysed for 35 elements by using mainly spectrophotometric and spectrographic methods. Cu, Co, Ni, Zn, and Pb were found in amounts approaching 1 %, which far exceeds their average concentrations in igneous rocks. On the other hand, elements having readily hydrolysable ions, such as Ga, Sc, Zr, Y, La and Ti, are present only in amounts comparable with their concentrations in igneous rocks. Sb, Bit Be, and Cr were not detected. The hydrochloric acid-insoluble fraction of nodules is practically free of the heavy metals that are characteristic of the acid-soluble fraction; it consists principally of clay minerals, together with lesser amounts of quartz, apatite, biotite and sodium and potassium felspars.

Stable isotopic record of planktonic foraminifera of the Pacific Ocean

We determined the d18O and d13C of individual Globigerinoides ruber and Pulleniatina obliquiloculata from sediment traps located from 5°N to 12°S along 140°W in the Pacific Ocean to evaluate the effects of varying [CO3=] on shell d18O and d13C. Variations in the offset between shell d13C and d13CDIC (Dd13Cs-DIC) are attributed to differences in [CO3]2-, temperature, and shell size between sample sites. When Dd13Cs-DIC of G. ruber was corrected for variations in [CO3]2- using the experimental slope of Bijma et al. (1998), the residual Dd13Cs-DIC was correlated with mixed layer temperature (+0.10±0.04 per mil °C**-1). The slope of this temperature effect is consistent with experimental results. In P. obliquiloculata, Dd13Cs-DIC and temperature were strongly anticorrelated (?0.14±0.03 per mil C**-1). We are unable to separate the influences of [CO3]2- and temperature in this species without independent experimental data. Correcting for [CO3]2- variability on d18Os of G. ruber improves the accuracy of estimated sea surface temperatures.

Calcareous nannofossil biostratigraphy of the central East Pacific Rise

During Leg 92 of the Deep Sea Drilling Project, sediments containing calcareous nannofossils of latest Oligocene to Holocene age were recovered from 14 holes at six sites (597 to 602) along the East Pacific Rise. The combined sections yield a virtually complete record for the region, with a compressed upper Miocene to Pleistocene interval. The nannofossil content of 14 U.S.N.S. Eltanin piston cores from the study area were also examined in order to supplement data generated during Leg 92. Two taxonomically new combinations are presented: Sphenolithus umbellus and Pontosphaera segmenta. Assemblages of calcareous nannofossils juxtaposed in reversed stratigraphic order within the upper Miocene provide strong evidence for downslope transport of sediments along the East Pacific Rise during the Messinian. Narrow bands of dark metalliferous sediment of coccolith Zone CN8b alternate with normal light-colored, in situ, pelagic sequences of Zone CN9b. This may indicate more vigorous bottom current activity between 5.40 and 6.70 Ma.

(Table 1) Platinoids in Fe-Mn crusts and nodules from the Pacific Ocean

Platinoid element contents were determined in 16 samples of Fe-Mn crusts and nodules collected during dredging deep-sea mound slopes of the Pacific Ocean from the equator to 27°N. The method of neutron activation analysis with pre-concentration of the platinoids was used for these determinations. There is no relationship between platinoid contents in deep-sea (>3000 m) Fe-Mn nodules with depth of sampling, as well as with age of nodule layers. It is concludet that ultramafic rocks are the primary source of platinoids in Fe-Mn nodules.

Geochemistry of lavas and dikes from the upper oceanic crust of Hess Deep Rift, eastern Pacific Ocean

Strontium isotopes are useful tracers of fluid-rock interaction in marine hydrothermal systems and provide a potential way to quantify the amount of seawater that passes through these systems. We have determined the whole-rock Sr-isotopic compositions of a section of upper oceanic crust that formed at the fast-spreading East Pacific Rise, now exposed at Hess Deep. This dataset provides the first detailed comparison for the much-studied Ocean Drilling Program (ODP) drill core from Site 504B. Whole-rock and mineral Sr concentrations indicate that Sr-exchange between hydrothermal fluids and the oceanic crust is complex, being dependent on the mineralogical reactions occurring; in particular, epidote formation takes up Sr from the fluid increasing the 87Sr/86Sr of the bulk-rock. Calculating the fluid-flux required to shift the Sr-isotopic composition of the Hess Deep sheeted-dike complex, using the approach of Bickle and Teagle (1992, doi:10.1016/0012-821X(92)90221-G) gives a fluid-flux similar to that determined for ODP Hole 504B. This suggests that the level of isotopic exchange observed in these two regions is probably typical for modern oceanic crust. Unfortunately, uncertainties in the modeling approach do not allow us to determine a fluid-flux that is directly comparable to fluxes calculated by other methods.

Neogene and Quaternary radiolarians from the Izu-Bonin Forearc in the western Pacific Ocean

Radiolarians were recovered from three of the five holes investigated during Leg 125. Relative abundances are estimated at Holes 782A and 784A, where preservation is poor to good. Rare, poorly preserved radiolarians are present in Hole 786A. Seven radiolarian zones are recognized in the latest early- middle Miocene to early Pleistocene of Holes 782A and 784A. These zones are approximately correlated to the zones of Sanfilippo and others published in 1985.