Radiocarbon dating on cold-water corals, grain size, Corg, and benthic foraminfera assemblage of two sediment cores from the Ionian Sea

Continuous sedimentary records from an eastern Mediterranean cold-water coral ecosystem thriving in intermediate water depths (~600 m) reveal a temporary extinction of cold-water corals during the Early to Mid Holocene from 11.4-5.9 cal kyr BP. Benthic foraminiferal assemblage analysis shows low-oxygen conditions of 2 ml l**-1 during the same period, compared to bottom-water oxygen values of 4-5 ml l**-1 before and after the coral-free interval. The timing of the corals' demise coincides with the sapropel S1 event, during which the deep eastern Mediterranean basin turned anoxic. Our results show that during the sapropel S1 event low oxygen conditions extended to the rather shallow depths of our study site in the Ionian Sea and caused the cold-water corals temporary extinction. This first evidence for the sensitivity of cold-water corals to low oceanic oxygen contents suggests that the projected expansion of tropical oxygen minimum zones resulting from global change will threaten cold-water coral ecosystems in low latitudes in the same way that ocean acidification will do in the higher latitudes.

Sediments in arctic sea ice - entrainment, characterization and quantification

Sediments in Arctic sea ice are important for erosion and redistribution and consequently a factor for the sediment budget of the Arctic Ocean. The processes leading to the incorporation of sediments into the ice are not understood in detail yet. In the present study, experiments on the incorporation of sediments were therefore conducted in ice tanks of The Hamburg Ship Model Basin (HSVA) in winter 1996/1997, These experiments showed that on average 75 % of the artificial sea-ice sediments were located in the brine-channel system. The sediments were scavenged from the water column by frazil ice. Sediments functioning as a nucleus for the formation of frazil ice were less important for the incorporation. Filtration in grease ice during relatively calm hydrodynamic conditions was probably an effective process to enrich sediments in the ice. Wave fields did not play an important role for the incorporation of sediments into the artificial sea ice. During the expedition TRANSDRIFT III (TDIII, October 1995), different types of natural, newly-formed sea ice (grease ice, nilas and young ice) were sampled in the inner Laptev Sea at the time of freeze-up. The incorporation of sediments took place during calm meteorological conditions then. The characteristics of the clay mineral assemblages of these sedirnents served as references for sea-ice sediments which were sampled from first-year drift ice in the outer Laptev Sea and the adjacent Arctic Ocean during the POLARSTERN expedition ARK-XI/1 (July-September 1995). Based on the clay mineral assemblages, probable incorporation areas for the sedirnents in first-year drift ice could be statistically reconstructed in the inner Laptev Sea (eastern, central, and Western Laptev Sea) as well as in adjacent regions. Comparing the amounts of particulate organic carbon (POC) in sea-ice sediments and in surface sediments from the shelves of potential incorporation areas often reveals higher values in sea-ice sediments (TDIII: 3.6 %DM; ARK-XI/1: 2.3 %DM). This enrichment of POC is probably due to the incorporation process into the sea ice, as could be deducted from maceral analysis and Rock-Eval pyrolysis. Both methods were applied in the present study to particulate organic material (POM) from sea-ice sediments for the first time. It was shown that the POM of the sea-ice sediments from the Laptev Sea and the adjacent Arctic Ocean was dominated by reworked, strongly fragmented, allochthonous (terrigenous) material. This terrigenous component accounted for more than 75 % of all counted macerals. The autochthonous (marine) component was also strongly fragmented, and higher in the sediments from newly-formed sea ice (24 % of all counted macerals) as compared to first-year drift ice (17 % of all counted macerals). Average hydroge indices confirmed this pattern and were in the transition zone between kerogen types II and III (TDIII: 275 mg KW/g POC; ARK-XI/1: 200 mg KW/g POC). The sediment loads quantified in natural sea ice (TDIII: 33.6 mg/l, ARK-XI/1: 49.0 mg/l) indicated that sea-ice sediments are an important factor for the sediment budget in the Laptev Sea. In particular during the incorporation phase in autumn and early winter, about 12 % of the sediment load imported annually by rivers into the Laptev Sea can be incorporated into sea ice and redistributed during calm meteorological conditions. Single entrainment events can incorporate about 35 % of the river input into the sea ice (ca. 9 x 10**6 t) and export it via the Transpolar Drift from the Eurasian shelf to the Fram Strait.

Sea surface temperature reconstruction of sediment core GeoB6518-1

Past hydrological changes in Africa have been linked to various climatic processes, depending on region and timescale. Long-term precipitation changes in the regions of northern and southern Africa influenced by the monsoons are thought to have been governed by precessional variations in summer insolation (Kutzbach and Liu, 1997, doi:10.1126/science.278.5337.440; Partridge et al., 1997, doi:10.1016/S0277-3791(97)00005-X). Conversely, short-term precipitation changes in the northern African tropics have been linked to North Atlantic sea surface temperature anomalies, affecting the northward extension of the Intertropical Convergence Zone and its associated rainbelt (Hastenrath, 1990, doi:10.1002/joc.3370100504, Street-Perrott and Perrott, 1990, doi:10.1038/343607a0). Our knowledge of large-scale hydrological changes in equatorial Africa and their forcing factors is, however, limited (Gasse, 2000, doi:10.1016/S0277-3791(99)00061-X). Here we analyse the isotopic composition of terrigenous plant lipids, extracted from a marine sediment core close to the Congo River mouth, in order to reconstruct past central African rainfall variations and compare this record to sea surface temperature changes in the South Atlantic Ocean. We find that central African precipitation during the past 20,000 years was mainly controlled by the difference in sea surface temperatures between the tropics and subtropics of the South Atlantic Ocean, whereas we find no evidence that changes in the position of the Intertropical Convergence Zone had a significant influence on the overall moisture availability in central Africa. We conclude that changes in ocean circulation, and hence sea surface temperature patterns, were important in modulating atmospheric moisture transport onto the central African continent.

Stable oxygen isotope record and Calcium concentrations of sediment core GeoB3910-2

There is increasing evidence that the preceding Holocene climate was as unstable as the last glacial period, although variations occurred at much lower amplitudes. However, low-latitude climate records that confirm this variability are sparse. Here we present a radiocarbon-dated Holocene marine record from the tropical western Atlantic. Aragonite dissolution derived from the degree of preservation of the pteropod Limacina inflata records changes in the corrosiveness of the bottom water at the core site due to the changing influence of northern versus southern water masses. The delta18O difference between the shallow-living planktonic foraminifera Globigerinoides sacculifer and the deep-living Globorotalia tumida is used as proxy for changes in the vertical stratification of the surface water, hence the trade wind strength at this latitude. We compared our data to high-latitude records of the North Atlantic region. A good agreement is found between the aragonite dissolution and the strength in the Island-Scotland Overflow Water, which contributes significantly to the North Atlantic Deep Water. This suggests that large-scale variations in the Atlantic thermohaline circulation occurred throughout the Holocene. Concurrently, the comparison of our Delta delta18O with the GISP2 glaciochemical records points to global Holocene atmospheric reorganizations seen in both the tropics and high northern latitudes.

Age determination and clay content of sediment core GeoB5804-4

Paleosalinity and terrigenous sediment input changes reconstructed on two sediment cores from the northernmost Red Sea were used to infer hydrological changes at the southern margin of the Mediterranean climate zone during the Holocene. Between approximately 9.25 and 7.25 thousand years ago, about 3 per mil reduced surface water salinities and enhanced fluvial sediment input suggest substantially higher rainfall and freshwater runoff, which thereafter decreased to modern values. The northern Red Sea humid interval is best explained by enhancement and southward extension of rainfall from Mediterranean sources, possibly involving strengthened early-Holocene Arctic Oscillation patterns and a regional monsoon-type circulation induced by increased land-sea temperature contrasts. We conclude that Afro-Asian monsoonal rains did not cross the subtropical desert zone during the early to mid-Holocene.

Low-temperature magnetic remanence and hysteresis measurements on sediment core GeoB4901-8 from the Niger deep-sea fan

Low-temperature (LT) magnetic remanence and hysteresis measurements, in the range 300-5 K, were combined with energy dispersive spectroscopy (EDS) in order to characterize the magnetic inventory of strongly diagenetically altered sediments originating from the Niger deep-sea fan. We demonstrate the possibility of distinguishing between different compositions of members of the magnetite-ulvöspinel and ilmenite-hematite solid solution series on a set of five representative samples, two from the upper suboxic and three from the lower sulfidic anoxic zone of gravity core GeoB 4901. Highly sensitive LT magnetic measurements were performed on magnetic extracts resulting in large differences in the magnetic behavior between samples from the different layers. This emphasizes that both Fe-Ti oxide phases occur in different proportions in the two geochemical environments. Most prominent are variations in the coercivity sensitive parameter coercive field (BC). At room-temperature (RT) hysteresis loops for all extracts are narrow and yield low coercivities (6-13 mT). With decreasing temperature the loops become more pronounced and wider. At 5 K an approximately 5-fold increase in BC for the suboxic samples contrasts a 20-25-fold increase for the samples from the anoxic zone. We demonstrate that this distinct increase in BC at LT corresponds to the increasing proportion of the Ti-rich hemoilmenite phase, while Fe-rich (titano-)magnetite dominates the magnetic signal at RT. This trend is also seen in the room-temperature saturation isothermal remanent magnetization (RT-SIRM) cycles: suboxic samples show remanence curves dominated by Fe-rich mineral phases while anoxic samples display curves clearly dominated by Ti-rich particles. We show that the EDS intensity ratios of the characteristic Fe Kalpha and Ti Kalpha lines of the Fe-Ti oxides may be used to differentiate between members of the magnetite-ulvöspinel and ilmenite-hematite solid solution series. Furthermore it is possible to calculate an approximate composition for each grain if the intensity ratios of natural particles are linked to well-known standards. Thus, element spectra with high Fe/Ti intensity ratios were found to be rather typical of titanomagnetite while low Fe/Ti ratios are indicative of hemoilmenite. The EDS analyses confirm the LT magnetic results, Fe-rich magnetic phases dominate in the upper suboxic environment whereas Ti-rich magnetic phases comprise the majority of particles in the lower anoxic domain: The mineral assemblage of the upper suboxic environments is composed of magnetite (~19%), titanomagnetite (~62%), hemoilmenite (~17%) and ~2% other particles. In the lower anoxic sediments, reductive diagenetic alteration has resulted in more extensive depletion of the (titano-)magnetite phase, resulting in a relative enrichment of the hemoilmenite phase (~66%). In these strongly anoxic sediments stoichiometric magnetite is barely preserved and only ~5% titanomagnetite was detected. The remaining ~28% comprises Ti-rich particles such as pseudobrookite or rutile.

Organic geochemistry of Late Cretaceous to Paleogene sediments from MITI Sanriku-oki borehole

Perylene is present in high concentration in Paleogene sediments from the Sanriku-oki borehole of the Ministry of International Trade and Industry (MITI), northeastern Japan. The borehole penetrates a thick sequence of Late Cretaceous to Neogene sediments deposited under a range of conditions, including fluvial-deltaic and shallow marine. Organic petrological and geochemical data show the sediments to be rich in organic matter (OM) derived from higher plants. Biomarker analysis of aliphatic and aromatic hydrocarbons confirms a significant input from higher plants, with extracts dominated by numerous gymnosperm- and angiosperm-derived biomarkers such as diterpanes, oleanenes, des-A-triterpanes and their aromatized counterparts. The highest concentration of perylene occurs in Middle Eocene sediments deposited in a relatively reducing environment. Stable carbon isotope compositions show 13C enrichment in perylene compared to gymnosperm and angiosperm biomarkers, consistent with a fungal origin. This elevated abundance of sedimentary perylene could relate to a Paleogene continental climate where fungi probably flourished.

Age model, lipids, and iron/calcium-ratios of sediment core GeoB9307-3

Hide Intense debate persists about the climatic mechanisms governing hydrologic changes in tropical and subtropical southeast Africa since the Last Glacial Maximum, about 20,000 years ago. In particular, the relative importance of atmospheric and oceanic processes is not firmly established. Southward shifts of the intertropical convergence zone (ITCZ) driven by high-latitude climate changes have been suggested as a primary forcing, whereas other studies infer a predominant influence of Indian Ocean sea surface temperatures on regional rainfall changes. To address this question, a continuous record representing an integrated signal of regional climate variability is required, but has until now been missing. Here we show that remote atmospheric forcing by cold events in the northern high latitudes appears to have been the main driver of hydro-climatology in southeast Africa during rapid climate changes over the past 17,000 years. Our results are based on a reconstruction of precipitation and river discharge changes, as recorded in a marine sediment core off the mouth of the Zambezi River, near the southern boundary of the modern seasonal ITCZ migration. Indian Ocean sea surface temperatures did not exert a primary control over southeast African hydrologic variability. Instead, phases of high precipitation and terrestrial discharge occurred when the ITCZ was forced southwards during Northern Hemisphere cold events, such as Heinrich stadial 1 (around 16,000 years ago) and the Younger Dryas (around 12,000 years ago), or when local summer insolation was high in the late Holocene, i.e., during the last 4,000 years.

Late Pleistocene oxygen isotope record of biognic silica

We determined the isotopic composition of oxygen in marine diatoms in eight deep-sea cores recovered from the Atlantic sector of the Southern Ocean. The analytical reproducibility and core-to-core consistency of the isotopic signal suggests that diatom delta18O can be used as a new paleocenographic tool to reconstruct past variations in surface water characteristics and to generate 18O -isotope-based stratigraphy for the Southern Ocean. The data indicate that diatom delta18O reflects sea surface temperature and seawater isotopic composition and that diatoms retain their isotopic signal on timescales of a least 430 ka. The delta18O analyses of different diatom assemblages reveal that the isotopic signal is free of species effects and that the common Antarctic species have the same water-opal fractionation. The transition from the last glacial maximum (LGM) to the Holocene is fully recorded in high sedimentation rate cores. An 18O enrichment during the LGM, a post-LGM meltwater spike and an input of meltwater during the late Holocene are the main isotopic features observed in down core records. The origin of this meltwater was very likely melting icebergs and/or continental ice or by melting sea ice that had accumulated snow. The most pronounced meltwater effects are recorded in cores that are associated with the Weddel gyre. Our results provide the basis for extending isotope studies to oceanic regions devoid of carbonate; further, isotopic stratigraphies may be constructed for records and regions where they were previously not possible.

Alkenone composition, UK'37 index, and carbon, sulphur, nitrogen and element oxides of ODP Site 186-1151

Ocean Drilling Program (ODP) Site 1151 (Sacks, Suyehiro, Acton, et al., 2000, doi:10.2973/odp.proc.ir.186.2000) is located in an area where the surface water mass is influenced by both the Kuroshio and Oyashio Currents. The site also receives a relatively high flux of detrital materials from riverine input from Honsyu Island and eolian input from Central and East Asia. We analyzed alkenones and alkenoates in the sediments to reconstruct alkenone unsaturation index (Uk'37)-based sea-surface temperature (SST), total organic carbon, and total nitrogen to estimate the terrigenous contribution by the C/N ratio during the last glacial-interglacial cycle. The major elements were also analyzed to examine the variation in terrigenous composition.

Planktonic foraminifera of sediment core MD01-2390

Sea-surface temperature (SST) estimates in the sediment core MD01-2390 based on planktonic foraminiferal species abundances using five different transfer function techniques suggest nearly unchanged or unusually higher temperatures in the tropical southern South China Sea (SCS) during the Last Glacial Maximum (LGM) relative to modern temperatures. These results are in contrast to substantial cooling of 2-5 °C inferred by geochemical (Uk'37, Mg/Ca ratios) and terrestrial proxies from the western tropical Pacific region. Using multivariate statistics we show that the glacial southern SCS harboured unique planktonic foraminiferal assemblages that have no modern analogs. Analyses of faunal variation through the core reveal that planktonic foraminiferal assemblages responded to temperature changes inferred from Mg/Ca data but that this signal is subdued by superimposed variations in the relative abundance of Pulleniatina obliquiloculata and Neogloboquadrina pachyderma (dextral). These species occur in glacial samples at proportions that are not observed in the calibration data set. The glacial high abundance of N. pachyderma (dextral) are interpreted to reflect a seasonal (winter) inflow of cold surface water from the northeast via the Bashi Strait due to the combined effects of an intensified winter monsoon, a southward shift of the polar front and the eastward migration of the Kuroshio Current. In contrast, processes controlling the high relative abundances of P. obliquiloculata during the LGM may be unique to the southern SCS. We propose a scenario involving a stronger (winter) mixing or enhanced upwelling due to an intensified winter monsoon that prevented shallow-dwelling, warm indicators to establish larger populations during the LGM. Our results indicate that a no-analog behaviour of planktonic foraminifera faunas is responsible for the warm glacial conditions in this part of the western Pacific warm pool as implied by foraminiferal transfer functions and that a more significant surface cooling in the region as implied by terrestrial and geochemical (Mg/Ca ratios; alkenone unsaturation index) marine proxies is a more likely scenario.

Paleotemperature reconstructions on sediment core GIK161603-3

Different proxies for sea surface temperature (SST) often exhibit divergent trends for deglacial warming in tropical regions, hampering our understanding of the phase relationship between tropical SSTs and continental ice volume at glacial terminations. To reconcile divergent SST trends, we report reconstructions of two commonly used paleothermometers (the foraminifera G. ruber Mg/Ca and the alkenone unsaturation index) from a marine sediment core collected in the southwestern tropical Indian Ocean encompassing the last 37,000 years. Our results show that SSTs derived from the alkenone unsaturation index (UK'37) are consistently warmer than those derived from Mg/Ca by ~2-3°C except for the Heinrich Event 1. In addition, the initial timing for the deglacial warming of alkenone SST started at ~15.6 ka, which lags behind that of Mg/Ca temperatures by 2.5 kyr. We argue that the discrepancy between the two SST proxies reflects seasonal differences between summer and winter rather than post-depositional processes or sedimentary biases. The UK'37 SST record clearly mimics the deglacial SST trend recorded in the North Atlantic region for the earlier part of the termination, indicating the early deglacial warming trend attributed to local summer temperatures was likely mediated by changes in the Atlantic Meridional Overturning Circulation at the onset of the deglaciation, In contrast, the glacial to interglacial SST pattern recorded by G. ruber Mg/Ca probably reflects cold season SSTs. This indicates that the cold season SSTs was likely mediated by climate changes in the southern hemisphere, as it closely tracks the Antarctic timing of deglaciation. Therefore our study reveals that the tropical southwestern Indian Ocean seasonal SST was closely linked to climate changes occurring in both hemispheres. The austral summer and winter recorded by each proxy is further supported with seasonal SST trends modeled by AOGCMs for our core site. Our interpretation that the alkenone and Mg/Ca SSTs are seasonally biased may also explain similar proxy mismatches observed in other tropical regions at the onset of the last termination.

Radiocarbon dataing, stable oxygen isotopes, and Mg/Ca ratios in surface sediment samples of the tropical eastern Indian Ocean

Shell chemistry of planktic foraminifera and the alkenone unsaturation index in 69 surface sediment samples in the tropical eastern Indian Ocean off West and South Indonesia were studied. Results were compared to modern hydrographic data in order to assess how modern environmental conditions are preserved in sedimentary record, and to determine the best possible proxies to reconstruct seasonality, thermal gradient and upper water column characteristics in this part of the world ocean. Our results imply that alkenone-derived temperatures record annual mean temperatures in the study area. However, this finding might be an artifact due to the temperature limitation of this proxy above 28°C. Combined study of shell stable oxygen isotope and Mg/Ca ratio of planktic foraminifera suggests that Globigerinoides ruber sensu stricto (s.s.), G. ruber sensu lato (s.l.), and G. sacculifer calcify within the mixed-layer between 20 m and 50 m, whereas Globigerina bulloides records mixed-layer conditions at ~50 m depth during boreal summer. Mean calcifications of Pulleniatina obliquiloculata, Neogloboquadrina dutertrei, and Globorotalia tumida occur at the top of the thermocline during boreal summer, at ~75 m, 75-100 m, and 100 m, respectively. Shell Mg/Ca ratios of all species show a significant correlation with temperature at their apparent calcification depths and validate the application of previously published temperature calibrations, except for G. tumida that requires a regional Mg/Ca-temperature calibration (Mg/Ca = 0.41 exp (0.068*T)). We show that the difference in Mg/Ca-temperatures of the mixed-layer species and the thermocline species, particularly between G. ruber s.s. (or s.l.) and P. obliquiloculata, can be applied to track changes in the upper water column stratification. Our results provide critical tools for reconstructing past changes in the hydrography of the study area and their relation to monsoon, El Niño-Southern Oscillation, and the Indian Ocean Dipole Mode.

Index properties, calcium carbonate content and opal concentration of ODP Core 167-1016B-17H sediments

Physical properties measurements provide a relatively inexpensive and fast way to obtain high-resolution estimates of the variations in sedimentological properties. To better resolve the validity and cause of the geophysical signals measured by the Ocean Drilling Program (ODP) shipboard multisensor track (MST) instruments, 223 x 10 cm**3 core samples were collected at 4 cm intervals in Core 167-1016B-17H at the California Margin Conception Transect for the measurements of index properties, carbonate content, and opal content. This core was chosen because hole-to-hole stratigraphic correlation of MST data suggested that Core 17H corresponds to a depth interval that displays the greatest range of amplitude of many physical properties.