d18O, lithologies, mineralogy and determination of temperature and depth of formation of DSDP Site 69-504 siliceous rocks

Seven opal-CT-rich and five quartz-rich porcellanites and cherts from Site 504 have a range in oxygen-isotope values of 24.4 and 29.4 per mil. In opal-CT rocks, d18O becomes larger with sub-bottom depth and with age. Quartz-rich rocks do not show these trends. Boron, in general, increases with decreasing d18O for porcellanites and cherts considered together, supporting the conclusion that boron is incorporated within the quartz crystal structure during precipitation of the SiO2. Silicification of the chalks at Site 504 began 1 m.y. ago - that is, 5 m.y. after sedimentation commenced on the oceanic crust. Temperatures of chert formation determined from oxygen-isotope compositions reflect diagenetic temperatures rather than bottom-water temperatures, and are comparable to temperatures of formation determined by down-hole measurements. Opal-A in the chalks began conversion to opal-CT when a temperature of 50°C was reached in the sediment column. Conversion of opal-CT to quartz started at 55 °C. Silicification occurred over a stratigraphic thickness of about 10 meters when the temperature at the top of the 10 meters reached about 50°C. It took about 250,000 years to complete the silica transformation within each 10-meter interval of sediment at Site 504. Quartz formed over a stratigraphic range of at least 30 meters, at temperatures of about 54 to 60°C. The time and temperatures of silicification of Site 504 rocks are more like those at continental margins than those in deep-sea, open-ocean deposits.

Holocene d18O diatom from ODP Hole 178-1098A

The causes for rising temperatures along the Antarctic Peninsula during the late Holocene have been debated, particularly in light of instrumental records of warming over the past decades (Russell and McGregor, 2010, doi:10.1007/s10584-009-9673-4). Suggested mechanisms range from upwelling of warm deep waters onto the continental shelf in response to variations in the westerly winds (Bentley et al., 2009, doi:10.1177/0959683608096603), to an influence of El Niño-Southern Oscillation on sea surface temperatures (Shevenell et al., 2011, doi:10.1038/nature09751). Here, we present a record of Holocene glacial ice discharge, derived from the oxygen isotope composition of marine diatoms from Palmer Deep along the west Antarctic Peninsula continental margin. We assess atmospheric versus oceanic influences on glacial discharge at this location, using analyses of diatom geochemistry to reconstruct atmospherically forced glacial ice discharge and diatom assemblage (Taylor and Sjunneskog, 2002, doi:10.1029/2000PA000564) ecology to investigate the oceanic environment. We show that two processes of atmospheric forcing-an increasing occurrence of La Niña events (Makou et al., 2010, doi:10.1130/G30366.1) and rising levels of summer insolation-had a stronger influence during the late Holocene than oceanic processes driven by southern westerly winds and upwelling of upper Circumpolar Deepwater. Given that the evolution of El Niño-Southern Oscillation under global warming is uncertain (Yeh et al., 2009, doi:10.1038/nature08316), its future impacts on the climatically sensitive system of the Antarctic Peninsula Ice Sheet remain to be established.

Geochemistry of low-temperatuer altered basalts of ODP Hole 136-843B

The mineralogy and chemistry of altered basalts and the stable isotopic compositions of secondary vein carbonates were studied in cores from Ocean Drilling Program Hole 843B, located in 95-Ma crust of the Hawaiian Arch. Millimeter- to centimeter-sized dark alteration halos around veins are 5%-15% altered to celadonite and Fe-oxyhydroxides, plus minor saponite and calcite. Adjacent gray host rocks are about 15% altered to saponite and calcite. The dark halos are enriched in H2O+, CO2, FeT, K2O, MnO, and Fe3+/FeT and depleted in SiO2, Al2O3, MgO, and TiO2 relative to gray host rocks. Brown alteration halos occur around veins where veins are more abundant, and are similar to dark halos, but contain more Fe-oxyhydroxides and exhibit greater Fe2O3T contents and higher Fe3+/FeT. Stable isotopic compositions of vein carbonates are consistent with their precipitation from seawater at temperatures of 5°-40°C. Crosscutting relationships of veins and zoned vein and vesicle fillings reveal a sequence of secondary mineral formation and alteration conditions. Celadonite and Fe-oxyhydroxides formed and dark alteration halos developed relatively early, under oxidizing conditions at low temperatures (<50°C). Saponite formed later at lower seawater/rock ratios and under more reducing conditions. Calcite and pyrite formed last in veins and vesicles from more evolved, seawaterderived fluids at temperatures of 5°-40°C. A second stage of celadonite, with compositions distinct from the early celadonite, also occurred relatively late (within the "calcite stage"), and may be related to refracturing of the crust and introduction of less-evolved seawater solutions into the rocks. Trends to higher K2O contents are attributed to alteration, but high K/Ti, Ba, and Zr contents indicate the presence of enriched or transitional MORB. CO2 contents of Pacific ODP cores exhibit a general increase with age suggesting progressive fixation of CO2 as calcite in the crust, but this could be complicated by local heterogeneities in fracturing and calcite formation in the crust.

Annual-layer thickness, d18O and sodium values on Akademii Nauk ice core (AD 900-1998) based on core chronology AN 2012

Understanding recent Arctic climate change requires detailed information on past changes, in particular on a regional scale. The extension of the depth-age relation of the Akademii Nauk (AN) ice core from Severnaya Zemlya (SZ) to the last 1100 yr provides new perspectives on past climate fluctuations in the Barents and Kara seas region. Here, we present the easternmost high-resolution ice-core climate proxy records (d18O and sodium) from the Arctic. Multi-annual AN d18O data as near-surface air-temperature proxies reveal major temperature changes over the last millennium, including the absolute minimum around 1800 and the unprecedented warming to a double-peak maximum in the early 20th century. The long-term cooling trend in d18O is related to a decline in summer insolation but also to the growth of the AN ice cap as indicated by decreasing sodium concentrations. Neither a pronounced Medieval Climate Anomaly nor a Little Ice Age are detectable in the AN d18O record. In contrast, there is evidence of several abrupt warming and cooling events, such as in the 15th and 16th centuries, partly accompanied by corresponding changes in sodium concentrations. These abrupt changes are assumed to be related to sea-ice cover variability in the Barents and Kara seas region, which might be caused by shifts in atmospheric circulation patterns. Our results indicate a significant impact of internal climate variability on Arctic climate change in the last millennium.

Monthly interpolated coral d18O records from Bonaire corals

Several proxy-based and modeling studies have investigated long-term changes in Caribbean climate during the Holocene, however, very little is known on its variability on short timescales. Here we reconstruct seasonality and interannual to multidecadal variability of sea surface hydrology of the southern Caribbean Sea by applying paired coral Sr/Ca and d18O measurements on fossil annually banded Diploria strigosa corals from Bonaire. This allows for better understanding of seasonal to multidecadal variability of the Caribbean hydrological cycle during the mid- to late Holocene. The monthly resolved coral Delta d18O records are used as a proxy for the oxygen isotopic composition of seawater (d18Osw) of the southern Caribbean Sea. Consistent with modern day conditions, annual d18Osw cycles reconstructed from three modern corals reveal that freshwater budget at the study site is influenced by both net precipitation and advection of tropical freshwater brought by wind-driven surface currents. In contrast, the annual d18Osw cycle reconstructed from a mid-Holocene coral indicates a sharp peak towards more negative values in summer, suggesting intense summer precipitation at 6 ka BP (before present). In line with this, our model simulations indicate that increased seasonality of the hydrological cycle at 6 ka BP results from enhanced precipitation in summertime. On interannual to multidecadal timescales, the systematic positive correlation observed between reconstructed sea surface temperature and salinity suggests that freshwater discharged from the Orinoco and Amazon rivers and transported into the Caribbean by wind-driven surface currents is a critical component influencing sea surface hydrology on these timescales.