Description and analyses of manganese nodules from the South-Western Pacific

Manganese nodules from the Campbell Plateau and Macquarie Ridge have been chemically analysed and their compositions compared with other Pacific nodules. No significant differences in composition are apparent. Foraminifera from nodule nucleii are late Tertiary or Quaternary, indicating the late geological formation of manganese nodules in this region. Nodule formation may be related to late Tertiary or Quaternary submarine volcanism.

Chemical composition of ultrabasites and gabbro from rift zones of the Indian Ocean

Results of petrographic studies of ultrabasites and gabbro from rift zones of the Indian Ocean are discussed using materials of Cruise 36 of R/V Vityaz. Rocks sampled from two sites 2700 km apart are close to each other in their composition. Petrographically ultrabasic rocks are divided into four subgroups: I - dunite; II - harzburgite, serpentinite; III - plagioclase lherzolite; and IV - metamorphically altered rocks. Petrographic description and chemical composition of basic rock varieties are presented as well as description of rock-forming minerals and their optical properties. Formation of pyroxene and plagioclase is shown to be related to autometasomatosis. Formation of ultrabasite in rift zones is related to complicated processes.

Chemical composition of ultrabasite and gabbro from the rift zones of the Arabian-Indian and Western Indian ridges

Results of petrographic studies of ultrabasite and gabbro from the rift zones of the Indian Ocean ridges are discussed using materials of R/V Vityaz Cruise 36. Rocks sampled from two sites 2700 km apart are close to each other in their composition. Petrographically ultrabasic rocks are divided into four subgroups: I - dunite; II - harzburgite, serpentinite; III - plagioclase lherzolite; and IV - metamorphically altered rocks. Petrographic description and chemical composition of basic rock varieties are presented as well as description of rock-forming minerals and their optical properties. Formation of pyroxene and plagioclase is shown to be related to autometasomatosis, which concludes the magmatic phase proper in rock mass formation accompanied by activity of residual intragranular liquid. Formation of ultrabasite in the rift zones is related to complicated processes.

Stable oxygen isotopes of Globigerinoides ruber and biostratigraphic datums at ODP Site 165-1002

Ocean Drilling Program Site 1002 in the Cariaco Basin was drilled in the final two days of Leg 165 with only a short transit remaining to the final port of San Juan, Puerto Rico. Because of severe time constraints, cores from only the first of the three long replicate holes (Hole 1002C) were opened at sea for visual description, and the shipboard sampling was restricted to the biostratigraphic examination of core catchers. The limited sampling and general scarcity of biostratigraphic datums within the late Quaternary interval covered by this greatly expanded hemipelagic sequence resulted in a very poorly defined age model for Site 1002 as reported in the Leg 165 Initial Reports volume of the Proceedings of the Ocean Drilling Program. Here, we present for the first time a new integrated stratigraphy for Site 1002 based on the standard of late Quaternary oxygen-isotope variations linked to a suite of refined biostratigraphic datums. These new data show that the sediment sequence recovered by Leg 165 in the Cariaco Basin is continuous and spans the time interval from 0 to ~580 ka, with a basal age roughly twice as old as initially suspected from the tentative shipboard identification of a single biostratigraphic datum. Lithologic subunits recognized at Site 1002 are here tied into this new stratigraphic framework, and temporal variations in major sediment components are reported. The biogenic carbonate, opal, and organic carbon contents of sediments in the Cariaco Basin tend to be high during interglacials, whereas the terrigenous contents of the sediments increase during glacials. Glacioeustatic variations in sea level are likely to exert a dominant control on these first-order variations in lithology, with glacial surface productivity and the nutrient content of waters in the Cariaco Basin affected by shoaling glacial sill depths, and glacial terrigenous inputs affected by narrowing of the inner shelf and increased proximity of direct riverine sources during sea-level lowstands.

Petrography and geochemistry of lithic clasts in sediments obtained from ODP Leg 180 sites

This report includes the petrographic description and reviews the distribution of lithic clasts in sediments drilled during Leg 180 in the Woodlark Basin (southwest Pacific). The lithic clasts include (1) metamorphic rocks; (2) granites; (3) serpentinites, gabbros, dolerites, and basalts likely derived from the Papuan ophiolite belt; (4) rare alkaline volcanites reworked in middle Miocene sediments; (5) medium- to high-K calc-alkaline island arc volcanites, in part as reworked clasts, and explosive products deposited by fallout or reworked by turbiditic currents; and (6) rare sedimentary fragments. At the footwall sites the clast assemblage evidences the association of dolerites and evolved gabbroic rocks; the serpentinite likely pertaining to the same ophiolitic complex are likely derived from onland outcrops and transported by means of turbidity currents. On the whole, extensional tectonics active at least since the middle Pliocene can be inferred. The calc-alkaline volcanism is in continuity with the arc-related products from the Papua Peninsula and D'Entrecasteaux Islands and with the latest volcanics of the Miocene Trobrian arc. However, the medium- to high-K and shoshonitic products do not display a significant temporal evolution within the stratigraphic setting. Lava clasts, volcanogenic grains, and glass shards are associated with turbidity currents, whereas in the Pliocene of northern margin the increasing frequency of tephra (glass shards and vesicular silicic fragments) suggests more explosive activity and increasing contribution to the sediments from aerial fallout materials. Evidence of localized alkalic volcanism of presumable early to middle Miocene age is a new finding. It could represent a rift phase earlier than or coeval to the first opening of the Woodlark Basin or, less probably, could derive from depositional trajectories diverted from an adjacent basin.

Chemical composition of hydrogarnet and celadonite from ODP Hole 206-1256D

Mid-ocean-ridge basalts recovered from Hole 1256D during Ocean Drilling Program Leg 206 exhibit the effects of various low-temperature (<100°C) alteration processes, including the formation of black or dark green alteration halos adjacent to celadonite-bearing veins. In several samples from the deepest basalts, a Ti-rich hydrogarnet occurs. To our knowledge, such a mineral has never been reported in the oceanic crust. This report presents a brief description and microprobe analyses of this hydrogarnet and associated celadonite. More detailed characterizations of this mineral and a description of its relationship to other secondary minerals will be undertaken in a future study, in an attempt to determine the mineral's formation conditions and its place in the general alteration history of the Hole 1256D basalts.

DATED-1: compilation of dates and time-slice reconstruction of the build-up and retreat of the last Eurasian (British-Irish, Scandinavian, Svalbard-Barents-Kara Seas) Ice Sheets 40-10 ka

DATED-1 comprises a compilation of dates related to the build-up and retreat of the Eurasian (British-Irish, Scandinavian, Svalbard-Barents-Kara Seas) Ice Sheets, and time-slice maps of the Eurasian Ice sheet margins. Dates are sourced from the published literature. Ice margins are based on published geological and chronological data and include uncertainty bounds (maximum, minimum) as well as what we consider to be the most-credible (mc) based on the available evidence. DATED-1 has a census date of 1 January 2013. Full description and caveats for use are given in: Hughes, A.L.C., Gyllencreutz, R., Lohne, Ø.S., Mangerud, J., Svendsen, J.I. (2015) The last Eurasian Ice Sheets - a chronological database and time-slice reconstruction, DATED-1.

Seawater carbonate chemistry and pteropod Limacina helicina antarctica shell dissolution during experiments, 2012

Anthropogenic ocean acidification is likely to have negative effects on marine calcifying organisms, such as shelled pteropods, by promoting dissolution of aragonite shells. Study of shell dissolution requires an accurate and sensitive method for assessing shell damage. Shell dissolution was induced through incubations in CO2 enriched seawater for between 4 and 14 days. We describe a procedure that allows the level of dissolution to be assessed and classified into three main types: Type I with partial dissolution of the prismatic layer; Type II with exposure of underlying crossed-lamellar layer, and Type III, where crossed-lamellar layer shows signs of dissolution. Levels of dissolution showed a good correspondence to the incubation conditions, with the most severe damage found in specimens held for 14 d in undersaturated condition (Ohm ~ 0.8). This methodology enables the response of small pelagic calcifiers to acidified conditions to be detected at an early stage, thus making pteropods a valuable bioindicator of future ocean acidification.

Annotated record of the detailed examination of ferromanganese concretions from the Bothnia Gulf, the Baltic Sea and the Barents sea collected by Boström, K. and Ingri, J. (Technical University of Lulea)

The collection of ferromanganese nodules at Naturhistoriska Riksmuseet, Stockholm, Sweden has been donated by Pr. Boström, K. and Ingri, J. from the Technical University of Lulea. They have been collected in the Bothnia Gulf, the Baltic Sea anfd the Barents sea from 1976 until 1985. In 1997 it is was put to the care custody of the Laboratory for Isotope Geology (LIG) of NRM. As part of the Access Project at LIG, Curt Boman has gone through the collection and established a database with detailed information about the samples it contains. Ferromanganese nodules typically display a rounded shape and are formed by redox processes at the interface between the seabed sediment and water. In addition to iron and manganese they also contain other metal elements. Nodules chemical composition reflects the substances found in the sediment to which they are associated. Since the nodules grow continuously, they reflect changes in the sedimentary environment chemistry on a yearly basis, which makes them very interesting as environmental archives. The nodules can be found locally in large quantities and due to their metal content they are also economically interesting as a source of raw materials.