Mineral composition of 0.1-0.05 mm grain size fraction from the surface layer of bottom sediments in the West European province of the Atlantic Ocean

Rock material sampled from the Mir manned deep-sea submersibles and by dradges, grabs, and sediment cores over a vast area of the North Atlantic was analyzed to show that this material is of continental origin, unlike original rocks of the ocean floor. It is proved to be related to iceberg rafting during Quaternary glaciations. Independent data on distribution and composition of sandy and silty grains in sediment cores also support this relation to the recent glaciation. New criteria for identification of iceberg rock matter in pelagic sediments are presented on the base of analysis of all available data.

Sequential variation of carbonate cycles in South Atlantic DSDP locations

We report well-dated Late Cretaceous and Early Tertiary precessional climatic cycles, recorded by rhythmic carbonate maxima and minima in South Atlantic deep sea sites. Spectral analyses of digitized sediment color, a suitable carbonate proxy, show prominent regularities in the spacing marl-carbonate beds. Magnetostratigraphic dating over a number of magnetic chrons constrains the duration of the cycles, which can be detected over at least 20 Myr of sedimentation at 7 coring locations. Their mean absolute period of 23.5 +/- 4.4kyr agrees closely with the predicted late Cretaceous precessional period of 20.8 kyr. Because they can be matched to a physical forcing mechanism with a known repeat time, the cycles offer a new high-resolution tool to measure rates of climate change before and after the Cretaceous-Tertiary (K/T) boundary. From counts of carbonate cycles, we derive the position of the K/T boundary within C29R at 350 kyr after the base of the reversal. The constancy of cycle thickness (linearly related to sedimentation rate) and amplitude up to the "boundary clay" does not give evidence for climate instability preceding the boundary. Orbital chronometry records a step-function decrease in sediment accumulation rate at the Cretaceous-Tertiary boundary that is consistent with a geologically instantaneous event.

Compilation of 231Protactinium/230 Thorium excess ratios in various surface sediment samples from the South Atlantic

In large areas of the world's oceans, there is a relationship between the mass flux of particulate matter and the unsupported 231Pa/230Th (xs231Pa/xs230Th) activity ratio of recent sediments. This observation forms the basis for using the xs231Pa/xs230Th ratio as a proxy for past changes in export productivity. However, a simple relationship between xs231Pa/xs 230Th ratio and particle flux requires that the water residence time in an ocean basin is far in excess of the scavenging residence time of 231Pa, and that the composition of sinking particles maintains a strong preference for the adsorption of 230Th over 231Pa with a constant 230Th/231Pa fractionation factor (F). The best correlation between xs231Pa/xs230Th ratio and mass flux is found in the Pacific Ocean. In the Atlantic, the contrast in the xs231Pa/xs230Th ratios between open ocean (low flux regions) and ocean margins (high flux regions) is much less pronounced due to the shorter residence time of deep water, resulting in less effective boundary scavenging of 231Pa. In the Southern Ocean, south of the Polar Front, there is no more a simple relationship between xs231Pa/xs230Th and particle flux. This is a result of a southward decrease in F, probably reflecting the increased opal content of sinking particles. Opal does not fractionate 231Pa and 230Th significantly. This lack of fractionation results in high xs231Pa/xs230Th ratios in opal-dominated regions, even in areas of very low particle fluxes such as the Weddell Sea. The xs231Pa/xs230Th ratio can therefore only be used as a paleoproductivity proxy if, in the time interval of interest, changes in the basin ventilation rate and differential scavenging of both radionuclides due to changes in the chemical composition of particulate matter can be excluded.

Geochemistry of sediment cores GeoB13820-1 and GeoB13863-1 from the western South Atlantic

Here, we present results from sediments collected in the Argentine Basin, a non-steady state depositional marine system characterized by abundant oxidized iron within methane-rich layers due to sediment reworking followed by rapid deposition. Our comprehensive inorganic data set shows that iron reduction in these sulfate and sulfide-depleted sediments is best explained by a microbially mediated process-implicating anaerobic oxidation of methane coupled to iron reduction (Fe-AOM) as the most likely major mechanism. Although important in many modern marine environments, iron-driven AOM may not consume similar amounts of methane compared with sulfate-dependent AOM. Nevertheless, it may have broad impact on the deep biosphere and dominate both iron and methane cycling in sulfate-lean marine settings. Fe-AOM might have been particularly relevant in the Archean ocean, >2.5 billion years ago, known for its production and accumulation of iron oxides (in iron formations) in a biosphere likely replete with methane but low in sulfate. Methane at that time was a critical greenhouse gas capable of sustaining a habitable climate under relatively low solar luminosity, and relationships to iron cycling may have impacted if not dominated methane loss from the biosphere.

Nutrient concentrations along a North-South transect in the North Atlantic measured during Maria S. Merain cruise MSM03/1 (VISION) cruise

Samples were taken along a transect in the North Atlantic Ocean from 66°139.27'N; 29°136.65'W to 34°124.87'N; 28°128.90'W during the VISION cruise (diVersIty, Structure and functION) MSM03/01 on board the research vessel Maria S. Merian from September 21 to September 30, 2006. Along this transect, each station was sampled at 12 depths, from 10m down to 250m or 500m. Samples were collected with a rosette of 20-l Niskin bottles mounted on a conductivity-temperature-density profiler. Water samples for nutrients analysis were filtered directly after sampling through 0.45-µm in-line filters attached to a 60-ml pre-cleaned syringe into two 12-ml polystyrole tubes. Samples were stored at 4°C (dissolved silicate) or 80°C (ammonium, phosphate, nitrate and nitrite) The samples were spectrophotometrically measured with a continuous-flow analyzer using standard AA3 methods (Seal Analytical, Norderstedt, Germany) using a variant of the method of Grasshoff et al. (1983).

Geochemistry of surface sediment samples from the equatorial Atlantic south of the Azores

In order to recognize the distribution of hydrothermal tracers south of the Azores, a series of cores has been sampled during the GEOFAR cruise. The distribution of the Mn concentrations shows that the hydrothermal influence is maximum within and to the north-west of the Lucky Strike segment. North of the East-Azores Fracture Zone the sediments are enriched in Ba which could be derived from different sources. The chemical composition of the interstitial water shows that water advection is limited. Mn, Cu, Ni fluxes evaluated in one site have increased during isotopic stages 4 and 2 and the deglaciation.

Standard meteorological measurements on board of POLARSTERN during expedition ANT-IV (PS08, 4 cruises, south summer 1985/86) in the Atlantic and Weddell Sea, Antarctica

During the fourth Antarctic voyage ANT-IV of the research icebreaker POLARSTERN standard meteorological measurements have been performed. The measurements include 3-hourly synoptic observations as well as daily upper air soundings. The measurements started on September 6 1985 at Bremerhaven and were terminated at April 28 1986 in Punta Arenas. The 3-hourly synoptic observations are performed following the instructions of the FM 13 ships code defined by the World Meteorological Organization (WMO). The datasets include automatic measurements such as mean ship's speed, wind velocity, wind direction, air temperature, water temperature as well as visual observations such as total cloud amount, present weather, clouds, height and period of swell waves, ice classification. The visual observation are not performed during night time. For the upper air soundings VAISALA RS80 radiosondes, carried by helium-filled balloons (TOTEX 350 - 1500) were used. Data reception and evaluation were carried out by a MicroCora System (VAISALA). The upper air soundings include profile measurements of pressure, temperature, relative humidity and wind vector. Usually the soundings started at the heliport (10 m above sea level) and terminated between 15 and 37 km. The height of the measurements was calculated by applying the barometric formula. The wind vector was determined with the aid of the OMEGA navigation system.

Geochemical and isotopic composition of basalts from the axial Mid-Atlantic Ridge, South Atlantic

One of the essential problems of oceanic tectonics is estimation of the influence of plumes of the deep hot mantle on processes in the axial spreading zone. Areas of two giant (St. Helena and Tristan da Cunha) plumes in the Mid-Atlantic Ridge (MAR) rift zone (South Atlantic) are characterized by the effusion of basalts that differ from typical depleted riftogenic tholeiites by anomalously high contents of lithophile components and specific isotopic compositions. Moreover, the rift valley floor with basalt effusion is significantly uplifted above the adjacent sectors of the rift. The formation of the St. Helena Seamount located 400 km east of the MAR axis is related to magmatism that is active to this day. St. Helena Island is a member of the structural ensemble of large volcanic seamounts (Bonaparte, Bagration, and Kutuzov). Like St. Helena Island, each seamount incorporates a series of smaller rises of different morphologies and dimensions. Thus, a system of subparallel series of NE-trending (~45°) rises extend from the seamount ensemble to the African continent. According to the plate tectonics concept, the seamount series represent hotspots related to a deep mantle plume that can be projected onto the present-day St. Helena Island area (St. Helena plume). At the same time, the inferred topographic map based on satellite altimetry data shows that the seamount series also extend along the opposite southwestern direction (~225°) toward the axial MAR and even intersect the latter structure. This fact cannot be explained by the hotspot hypothesis, which suggests stationary positions of plumes relative to the mobile oceanic plate. In the course of Cruise 10 of the R/V Akademik Ioffe (2002), detailed geological and geophysical investigations were carried out at the junction of one structural series with the MAR rift zone located near the Martin Vaz Fracture Zone (Martin Vaz test area, 19°-20° S). The present communication is devoted to the study of lithology, geochemistry, and isotopy of basalts dredged at the test area.

Middle Eocene-Early Pliocene Subantarctic planktic foraminiferal biostratigraphy of ODP Site 1090 on the Agulhas Ridge, South Atlantic

The analysis of planktic foraminiferal assemblages from Site 1090 (ODP Leg 177), located in the central part of the Subantarctic Zone south of South Africa, provided a geochronology of a 330-m-thick sequence spanning the Middle Eocene to Early Pliocene. A sequence of discrete bioevents enables the calibration of the Antarctic Paleogene (AP) Zonation with lower latitude biozonal schemes for the Middle-Late Eocene interval. In spite of the poor recovery of planktic foraminiferal assemblages, a correlation with the lower latitude standard planktic foraminiferal zonations has been attempted for the whole surveyed interval. Identified bioevents have been tentatively calibrated to the geomagnetic polarity time scale following the biochronology of Berggren et al. (1995). Besides planktic foraminiferal bioevents, the disappearance of the benthic foraminifera Nuttallides truempyi has been used to approximate the Middle/Late Eocene boundary. A hiatus of at least 11.7 Myr occurs between V78 and V71 m composite depth extending from the Early Miocene to the latest Miocene-Early Pliocene. Middle Eocene assemblages exhibit a temperate affinity, while the loss of several planktic foraminiferal species by late Middle to early Late Eocene time reflects cooling. During the Late Eocene-Oligocene intense dissolution caused impoverishment of planktic foraminiferal assemblages possibly following the emplacement of cold, corrosive bottom waters. Two warming peaks are, however, observed: the late Middle Eocene is marked by the invasion of the warmer water Acarinina spinuloinflata and Hantkenina alabamensis at 40.5 Ma, while the middle Late Eocene experienced the immigration of some globigerinathekids including Globigerinatheka luterbacheri and Globigerinatheka cf. semiinvoluta at 34.3 Ma. A more continuous record is observed for the Early Miocene and the Late Miocene-Early Pliocene where planktic foraminiferal assemblages show a distinct affinity with southern mid- to high-latitude faunas.

(Table 1) Elemental composition of benthic foraminifera from South Atlantic core top samples

The ocean plays a major role in the global carbon cycle, and attempts to reconstruct past changes in the marine carbonate system are increasing. The speciation of dissolved uranium is sensitive to variations in carbonate system parameters, and previous studies have shown that this is recorded in the uranium-to-calcium ratio (U/Ca) of the calcite shells of planktonic foraminifera. Here we test whether U/Ca ratios of deep-sea benthic foraminifera are equally suited as an indicator of the carbonate system. We compare U/Ca in two common benthic foraminifer species (Planulina wuellerstorfi and Cibicidoides mundulus) from South Atlantic core top samples with the calcite saturation state (Delta [CO3**2-] = [CO3**2-]in situ - [CO3**2-]sat) of the ambient seawater and find significant negative correlations for both species. Compared with planktonic foraminifera, the sensitivity of U/Ca in benthic foraminifera to changes in Delta [CO3**2-] is about 1 order of magnitude higher. Although Delta [CO3**2-] exerts the dominant control on the average foraminiferal U/Ca, the intertest and intratest variability indicates the presence of additional factors forcing U/Ca.