Depth profiles of iodide and iodate during POLARSTERN cruise ANT-XXIV/3 to the Atlantic sector of the Southern Ocean

The biogeochemistry of iodine in the waters of the Atlantic sector of the Southern Ocean was investigated during the Polarstern cruise ANTXXIV-3 ZERO&DRAKE. The speciation and distribution of iodine (iodate and iodide) in seawater was examined across gradients of iron concentrations and phytoplankton abundance, ranging from an open ocean region along the Zero Meridian to the Weddell Sea and Drake Passage. Iodine cycling in high latitudes differs from that in low latitudes due to differences in the plankton community composition and the physicochemical characteristics. Iodate concentrations ranged between 400 and 450 nmol/L from the surface to the bottom. Surface concentrations of iodide (17 to over 60 nmol/L) were about an order of magnitude higher than below the pycnocline. The peak values of iodide lay nearly always within the euphotic zone and showed a weak, positive correlation with nitrite concentrations in the upper 200 m. In all vertical profiles a pronounced sub-surface maximum in iodide appears between 50 and 200 m depth indicating an iodide drawdown at the near surface. Iodide distribution in the Weddell Sea showed elevated levels in Weddell Sea Bottom Water (WSBW) indicating slow oxidation kinetics and the potential for iodide as a tracer of WSBW formation.

Geochemistry of surface sediment samples from the equatorial Atlantic south of the Azores

In order to recognize the distribution of hydrothermal tracers south of the Azores, a series of cores has been sampled during the GEOFAR cruise. The distribution of the Mn concentrations shows that the hydrothermal influence is maximum within and to the north-west of the Lucky Strike segment. North of the East-Azores Fracture Zone the sediments are enriched in Ba which could be derived from different sources. The chemical composition of the interstitial water shows that water advection is limited. Mn, Cu, Ni fluxes evaluated in one site have increased during isotopic stages 4 and 2 and the deglaciation.