K-Ar age and chemical composition of volcanites from the Sea of Okhotsk

Volcanogenic rocks from the Sea of Okhotsk are divided into seven age complexes: Late Jurassic, Early Cretaceous, Late Cretaceous, Eocene, Late Oligocene, Late Miocene, and Pliocene-Pleistocene. All these complexes are united into two groups - Late Mesozoic and Cenozoic. Each group reflects a certain stage of development of the Sea of Okhotsk region. Late Mesozoic volcanites build the geological basement of the Sea of Okhotsk, and their petrochemical features are similar to those of the volcanic rocks from the Okhotsk-Chukotka Volcanogen. Pliocene-Pleistocene volcanites reflect stages of tectono-magmatic activity; the latter destroyed the continental margin and produced riftogenic troughs. Geochemical features of volcanites from the Sea of Okhotsk indicate influence of the sialic crust on magma formation and testify formation of the Okhotsk Sea Basin on the destructive margin of the Asian continent.

(Table 1) Basalt geochemsitry at DSDP Hole 72-516F

Basalts from Hole 516F, DSDP Leg 72 on the Rio Grande Rise are tholeiitic in character but differ from normal mid-ocean ridge basalts in the South Atlantic in higher concentrations of incompatible elements such as Ti, K, V, Sr, Ba, Zr, Nb, and light rare-earth elements and in lower concentrations of Mg, Cr, and Ni. They contrast with previously reported basalts from the Rio Grande Rise, which were highly alkalic in character. The Rio Grande Rise basalts from Hole 516F (age 84.5 Ma) are generally similar to basalts from the eastern end of the Walvis Ridge (80-100 Ma). It is suggested that they either originated, like the Walvis Ridge, from a mantle hot spot that is different from the present-day hot spot (Tristan da Cunha) and that has changed composition with time, or from a spreading center that was shallow and chemically influenced by the adjacent hot spot, similar to the present-day Mid-Atlantic Ridge near the Azores and Tristan da Cunha.

Geochemistry of metasedimentary units of the Cambro-Ordovician Ross Orogen in North Victoria Land and Oates Land, Antarctica

Metasediments in the three early Palaeozoic Ross orogenic terranes in northern Victoria Land and Oates Land (Antarctica) are geochemically classified as immature litharenites to wackes and moderately mature shales. Highly mature lithotypes with Chemical Index of Weathering values of >=95 are typically absent. Geochemical and Rb-Sr and Sm-Nd isotope results indicate that the turbiditic metasediments of the Cambro-Ordovician Robertson Bay Group in the eastern Robertson Bay Terrane represent a very homogeneous series lacking significant compositional variations. Major variations are only found in chemical parameters which reflect differences in degree of chemical weathering of their protoliths and in mechanical sorting of the detritus. Geochemical data, 87Sr/ 86Sr t=490 Ma ratios of 0.7120 - 0.7174, epsilonNd, t=490 Ma values of -7.6 to -10.3 and single-stage Nd-model ages of 1.7 - 1.9 Ga are indicative of an origin from a chemically evolved crustal source of on average late Palaeoproterozoic formation age. There is no evidence for significant sedimentary infill from primitive "ophiolitic" sources. Metasediments of the Middle Cambrian Molar Formation (Bowers Terrane) are compositionally strongly heterogeneous. Their major and trace element data and Sm-Nd isotope data (epsilonNd, t=500 Ma values of -14.3 to -1.2 and single-stage Nd-model ages of 1.7 - 2.1 Ga) can be explained by mixing of sedimentary input from an evolved crustal source of at least early Palaeoproterozoic formation age and from a primitive basaltic source. The chemical heterogeneity of metasediments from the Wilson Terrane is largely inherited from compositional variations of their precursor rocks as indicated by the Ni vs TiO2 diagram. Single-stage Nd-model ages of 1.6 -2.2 Ga for samples from more western inboard areas of the Wilson Terrane (epsilonNd, t=510 Ma -7.0 to -14.3) indicate a relatively high proportion of material derived from a crustal source with on average early Palaeoproterozoic formation age. Metasedimentary series in an eastern, more outboard position (epsilonNd, t=510 Ma -5.4 to -10.0; single-stage Nd model ages 1.4 - 1.9) on the contrary document stronger influence of a more primitive source with younger formation ages. The chemical and isotopic characteristics of metasediments from the Bowers and Wilson terranes can be explained by variable contributions from two contrasting sources: a cratonic continental crust similar to the Antarctic Shield exposed in Georg V Land and Terre Adélie some hundred kilometers west of the study area and a primitive basaltic source probably represented by the Cambrian island-arc of the Bowers Terrane. While the data for metasediments of the Robertson Bay Terrane are also compatible with an origin from an Antarctic-Shield-type source, there is no direct evidence from their geochemistry or isotope geochemistry for an island-arc component in these series.