Magnetic properties of ODP Site 191-1179 sediments

As reported by Shipboard Scientific Party (2001b, doi:10.2973/odp.proc.ir.191.104.2001) in the Site 1179 chapter of the Initial Reports volume, Leg 191 Site 1179 is located on abyssal seafloor northwest of Shatsky Rise, ~1650 km east of Japan. This part of the Pacific plate was formed during the Early Cretaceous, as shown by northeast-trending M-series magnetic lineations that become younger toward the northwest (Larson and Chase, 1972, doi:10.1130/0016-7606(1972)83[3627:LMEOTW]2.0.CO;2; Sager et al., 1988, doi:10.1029/JB093iB10p11753; Nakanishi et al., 1989, doi:10.1029/1999JB900002). The site is situated on magnetic Anomaly M8 (Nakanishi et al., 1999, doi:10.1029/1999JB900002), corresponding to an age of ~129 Ma and the Hauterivian stage of the Early Cretaceous (Gradstein et al., 1994, doi:10.1029/94JB01889; 1995). The sediments recovered at Site 1179 are split into four lithostratigraphic units based on composition and color (Shipboard Scientific Party, 2001b, doi:10.2973/odp.proc.ir.191.104.2001). Unit I (0-221.52 meters below seafloor [mbsf]) is a dominantly olive-gray clay- and radiolarian-bearing diatom ooze. Unit II (221.52-246.0 mbsf) is a yellowish brown to light brown clay-rich and diatom-bearing radiolarian ooze. Unit III (246.0-283.53 mbsf) is composed of brown pelagic clay. Unit IV (283.53-377.15 mbsf) is composed of chert and some porcellanite; any softer sediments present were washed out of the core barrel by the fluid circulating during the coring process.

Illustration of manganese nodules and crust collected from the Suiko Seamount, Northwestern Pacific Ocean

An initial investigation has been undertaken on the chemical composition of the manganese nodules. The results of chemical analyses on each layer of single nodules reveal the periodic patterns of distribution for Mn, Fe, Cu, Pb, Zn, Ni and Co contents. The variations strongly suggest that those of the elements in nodules from this region are, at least, climatically controlled.

Illustration of manganese nodules and crust collected from the Suiko Seamount, Northwestern Pacific Ocean

Manganese nodules from the Suiko Seamount exhibit the significant characteristics in mineral compositions. Well crystallized todorokite and birnessite, which are principal manganese mineral phase in nodules, only occur in the oxide layer directly incasing pebbles and coarse sand. The preferential formation of todorokite or birnessite phases seem to be principally controlled by the reaction rate of iron-manganese oxides with trace elements such as Cu, Ni, Co, Zn, Pb concentrated in nodules, rather than redox characteristics of sedimentary environment or mineralogical diagenetic process.