Barium/Calcium and Cadmium/Calcium ratios of sediment core RC13-229

A new benthic foraminiferal Ba/Ca and Cd/Ca data set from core RC13-229 in the deep Cape Basin indicates only small variations in bottom water nutrient concentrations in Circumpolar Deep Water (CPDW) over the last 450 kyr. Variability in the Ba record is characterized by somewhat higher values during glacial periods, consistent with a reduction in the flux of Ba-depleted North Atlantic Deep Water to the Southern Ocean during glacial periods. The small changes in the Ba and Cd records contrast with the large and systematic increase in CPDW nutrients during glacial periods implied by the benthic delta13C record. This discrepancy, essentially an extension of the well-known Southern Ocean Cd-delta13C conflict, is evaluated by transforming RC13-229 paleochemical data into carbonate parameters using the modern oceanic relationships between delta13C, Cd, and SumCO2 and between Ba and alkalinity. Calculations using Cd/Ca to estimate past variations in CPDW SumCO2 and Ba/Ca to estimate past variations in CPDW alkalinity yield carbonate ion concentrations that exceed calcite saturation throughout the record length, with generally higher carbonate ion values associated with glacial intervals (opposite in sense to the RC13-229 %CaCO3 record). Substituting delta13C to estimate SumCO2 leads to extreme calcite undersaturation at this site during glacial periods, clearly inconsistent with the preservation of calcite throughout the length of RC13-229. Accepting the carbon isotope record as a direct measure of past variations in CPDW SumCO2 concentrations requires that both the Cd and Ba evidence for limited nutrient and alkalinity changes be disregarded.

Oligocene strontium isotope stratigraphy of Indian Ocean sediments

Strontium isotope (87Sr/86Sr) ages have been established for Oligocene samples of Leg 119 Site 744, Leg 120 Sites 747 and 748, and Leg 121 Sites 756 and 757. Ages were determined using the strontium isotope age equation of Miller et al. (1988) and preliminary correlations have been made with available nannofossil biostratigraphy. The strontium isotope ages calculated here augment biostratigraphy, which for the Oligocene is characterized by long biozones, and provide additional detail where the paleomagnetic record is not clear (Sites 756 and 757). Results from the lower latitude Ninetyeast Ridge sites where standard calcareous nannofossil datums are present are compared to those of the higher latitude Kerguelen Plateau sites in order to examine biostratigraphic events across latitude in the Indian Ocean. The 87Sr/86Sr determined ages are used here as a tool for correlation.