(Table S1) Opal content of sediment core OXMZ01MV-GC31

The North American monsoon (NAM), an onshore wind shift occurring between July and September, has evolved in character during the Holocene largely due to changes in Northern Hemisphere insolation. Published paleoproxy and modeling studies suggest that prior to ~8000 cal years BP, the NAM affected a broader region than today, extending westward into the Mojave Desert of California. Holocene proxy SST records from the Gulf of California (GoC) and the adjacent Pacific provide constraints for this changing NAM climatology. Prior to ~8000 cal years BP, lower GoC SSTs would not have fueled northward surges of tropical moisture up the GoC, which presently contribute most of the monsoon precipitation to the western NAM region. During the early Holocene, the North Pacific High was further north and SSTs in the California Current off Baja California were warmer, allowing monsoonal moisture flow from the subtropical Pacific to take a more direct, northwesterly trajectory into an expanded area of the southwestern U.S. west of 114°W. A new upwelling record off southwest Baja California reveals that enhanced upwelling in the California Current beginning at ~7500 cal year BP may have triggered a change in NAM climatology, focusing the geographic expression of NAM in the southwest USA into its modern core region east of ~114°W, in Arizona and New Mexico. Holocene proxy precipitation records from the southwestern U.S. and northwestern Mexico, including lakes, vegetation/pollen, and caves are reviewed and found to be largely supportive of this hypothesis of changing Holocene NAM climatology.

Body measurements and blood plasma lipid, PCB and OH-PCB content of polar bear (U. maritimus) mothers and cubs, Svalbard

The aim of this study was to examine the plasma concentrations and prevalence of polychlorinated biphenyls (PCBs) and hydroxylated PCB-metabolites (OH-PCBs) in polar bear (Ursus maritimus) mothers (n = 26) and their 4 months old cubs-of-the-year (n = 38) from Svalbard to gain insight into the mother-cub transfer, biotransformation and to evaluate the health risk associated with the exposure to these contaminants. As samplings were performed in 1997/1998 and 2008, we further investigated the differences in levels and pattern of PCBs between the two sampling years. The plasma concentrations of Sum(21)PCBs (1997/1998: 5710 ± 3090 ng/g lipid weight [lw], 2008: 2560±1500 ng/g lw) and Sum(6)OH-PCBs (1997/1998: 228 ± 60 ng/g wet weight [ww], 2008: 80 ± 38 ng/g ww) in mothers were significantly lower in 2008 compared to in 1997/1998. In cubs, the plasma concentrations of Sum(21)PCBs (1997/1998: 14680 ± 5350 ng/g lw, 2008: 6070 ± 2590 ng/g lw) and Sum(6)OH-PCBs (1997/1998: 98 ± 23 ng/g ww, 2008: 49 ± 21 ng/g ww) were also significantly lower in 2008 than in 1997/1998. Sum(21)PCBs in cubs was 2.7 ± 0.7 times higher than in their mothers. This is due to a significant maternal transfer of these contaminants. In contrast, Sum(6)OH-PCBs in cubs were approximately 0.53 ± 0.16 times the concentration in their mothers. This indicates a lower maternal transfer of OH-PCBs compared to PCBs. The majority of the metabolite/precursor-ratios were lower in cubs compared to mothers. This may indicate that cubs have a lower endogenous capacity to biotransform PCBs to OH-PCBs than polar bear mothers. Exposure to PCBs and OH-PCBs is a potential health risk for polar bears, and the levels of PCBs and OH-PCBs in cubs from 2008 were still above levels associated with health effects in humans and wildlife.

(Table 1) Lipid and kerogen content at DSDP Leg 64 Holes

Diatomaceous mud and an organically-rich claystone from holes at Sites 474 and 476 at the mouth of the Gulf of California were analyzed by organic geochemical methods to characterize their organic matter. The lipids of all three samples are primarily marine autochthonous, with the exception of Sample 474-5-3, 105-107 cm, which also contains some vascular plant wax. Based on the lipid composition, the sediment was deposited mainly under oxic environmental conditions. The kerogens were aliphatic and autochthonous marine. Two lignite fragments were also analyzed, and the data indicate that they are driftwood that absorbed marine bitumen from the surrounding sediment during coalification.