Last Glacial Maximum carbon isotopic composition

We present Holocene and last glacial maximum (LGM) oxygen and carbon isotope measurements on Planulina wuellerstorfi in six southeast Pacific cores. Sedimentation rates are low in this part of the ocean, and measurements were made on individual foraminiferal shells in order to identify the Holocene and glacial individuals on the basis of their extreme d18O. The new d13C data were combined with previous P. wuellerstorfi data for interpretation of global thermohaline circulation. Data from the Southern Ocean were examined closely for regional coherency and a few anomalous d13C values suspected of having productivity overprint were removed. The resulting global d13C distributions and gradients indicate that the deep water circulation was similar during the Holocene and LGM. This interpretation brings d13C data to a better agreement with Cd/Ca data and marks a sharp contrast with a widely held view based on d13C measurements that the glacial Southern Ocean was the terminus of the thermohaline circulation. The proposed presence of glacial North Atlantic Deep Water does not necessarily contradict the postulated presence of Glacial North Atlantic Intermediate Water.

Sea surface temperature estimation for MIS 16 of IODP Site 306-U1313

Hudson Strait (HS) Heinrich Events, ice-rafting events in the North Atlantic originating from the Laurentide ice sheet (LIS), are among the most dramatic examples of millennial-scale climate variability and have a large influence on global climate. However, it is debated as to whether the occurrence of HS Heinrich Events in the (eastern) North Atlantic in the geological record depends on greater ice discharge, or simply from the longer survival of icebergs in cold waters. Using sediments from Integrated Ocean Drilling Program (IODP) Site U1313 in the North Atlantic spanning the period between 960 and 320 ka, we show that sea surface temperatures (SSTs) did not control the first occurrence of HS Heinrich(-like) Events in the sedimentary record. Using mineralogy and organic geochemistry to determine the characteristics of ice-rafting debris (IRD), we detect the first HS Heinrich(-like) Event in our record around 643 ka (Marine Isotope Stage (MIS) 16), which is similar as previously reported for Site U1308. However, the accompanying high-resolution alkenone-based SST record demonstrates that the first HS Heinrich(-like) Event did not coincide with low SSTs. Thus, the HS Heinrich(-like) Events do indicate enhanced ice discharge from the LIS at the end of the Mid-Pleistocene Transition, not simply the survivability of icebergs due to cold conditions in the North Atlantic.

Age model, stable isotopes, major element proportions and endmember unmixing results from four western tropical Atlantic cores

We investigate changes in the delivery and oceanic transport of Amazon sediments related to terrestrial climate variations over the last 250 ka. We present high-resolution geochemical records from four marine sediment cores located between 5 and 12° N along the northern South American margin. The Amazon River is the sole source of terrigenous material for sites at 5 and 9° N, while the core at 12° N receives a mixture of Amazon and Orinoco detrital particles. Using an endmember unmixing model, we estimated the relative proportions of Amazon Andean material ("%-Andes", at 5 and 9° N) and of Amazon material ("%-Amazon", at 12° N) within the terrigenous fraction. The %-Andes and %-Amazon records exhibit significant precessional variations over the last 250 ka that are more pronounced during interglacials in comparison to glacial periods. High %-Andes values observed during periods of high austral summer insolation reflect the increased delivery of suspended sediments by Andean tributaries and enhanced Amazonian precipitation, in agreement with western Amazonian speleothem records. Increased Amazonian rainfall reflects the intensification of the South American monsoon in response to enhanced land-ocean thermal gradient and moisture convergence. However, low %-Amazon values obtained at 12° N during the same periods seem to contradict the increased delivery of Amazon sediments. We propose that reorganizations in surface ocean currents modulate the northwestward transport of Amazon material. In agreement with published records, the seasonal North Brazil Current retroflection is intensified (or prolonged in duration) during cold substages of the last 250 ka (which correspond to intervals of high DJF or low JJA insolation) and deflects eastward the Amazon sediment and freshwater plume.

Benthic foraminifera and ostracoda in ODP Hole 107-650A

Twenty-three sediment intervals from top of Site 650 down to 510 m below seafloor have been studied. Their thicknesses vary between 0.25 m and about 40 m. The studied deposits are turbidites or parts of them except one which is interpreted as an ash-fall layer. The composition of the turbidites signalizes sources from shallow water/coastal areas as well as from deep water levels. Repeated mobilization and displacement seems to have been common. Volcaniclastic material is the dominant component of the whole studied part of Site 650 sedimentary sequence. Ashfall deposits as well as normal open marine sediments are rare.

Geochemistry of dark-light rhythm sediments of the Japan Sea

Ocean Drilling Program Legs 127 and 128 in the Japan Sea have revealed the existence of numerous dark-light rhythms of remarkable consistency in sediments of late Miocene, latest Pliocene, and especially Pleistocene age. Light-colored units within these rhythms are massive or bioturbated, consist of diatomaceous clays, silty clays, or nannofossil-rich clays, and are generally poor in organic matter. Dark-colored units are homogeneous, laminated, or thinly bedded and include substantial amounts of biogenic material such as well-preserved diatoms, planktonic foraminifers, calcareous nannofossils, and organic matter (maximum 7.4 wt%). The dark-light rhythms show a similar geometrical pattern on three different scales: First-order rhythms consist of a cluster dominated by dark-colored units followed by a cluster dominated by light-colored units (3-5 m). Spectral analysis of a gray-value time series suggests that the frequencies of the first-order rhythms in sediments of latest Pliocene and Pleistocene age correlate to the obliquity and the eccentricity cycles. The second-order dark-light rhythms include a light and a dark-colored unit (10-160 cm). They were formed in time spans of several hundred to several ten thousand years, with variance centering around 10,500 yr. This frequency may correspond to half the precessional cycle. Third-order rhythms appear as laminated or thinly bedded dark-light couplets (2-15 mm) within the dark-colored units of the second-order rhythms and may represent annual frequencies. In interpreting the rhythms, we have to take into account that (1) the occurrence of the first- and second-order rhythms is not necessarily restricted to glacial or interglacial periods as is shown by preliminary stable-isotope analysis and comparison with the published d18O record; (2) they appear to be Milankovitch-controlled; and (3) a significant number of the rhythms are sharply bounded. The origin of the dark-light rhythms is probably related to variations in monsoonal activity in the Japan Sea, which show annual frequencies, but also operates in phase with the orbital cycles.

A 31,000-year high-resolution record from two sediment cores off northwest Africa

Benthic foraminiferal assemblage compositions and sedimentary geochemical parameters were analyzed in two radiocarbon dated sediment cores from the upwelling area off NW Africa at 12°N, to reconstruct productivity changes during the last 31 kyr. High-latitude cold events and variations in low-latitude summer insolation influenced humidity, wind systems, and the position of the tropical rain belt over this time period. This in turn caused changes in intensity and seasonality of primary productivity off the southern Northwest African continental margin. High accumulation rates of benthic foraminifera, carbonate, and organic carbon during times of north Atlantic melt water events Heinrich 2 (25.4 to 24.3 kyr BP) and 1 (16.8 to 15.8 kyr BP) indicate high productivity. Dominance of infaunal benthic foraminiferal species and high numbers of deep infaunal specimens during that time indicate a strong and sustained supply of refractory organic matter reworked from the upper slope and shelf. A more southerly position of the tropical rainbelt and the Northeast trade wind belt during Heinrich 2 and 1 may have enhanced wind intensity and almost permanent upwelling, driving this scenario. A phytodetritus-related benthic fauna indicates seasonally pulsed input of labile organic matter but generally low year-round productivity during the Last Glacial Maximum (23 to 18 kyr BP). The tropical rainbelt is more expanded to the North than during Heinrich Events, and relatively weak NE trade winds resulted in seasonal and weak upwelling, thus lower productivity. High productivity characterized by a seasonally high input of labile organic matter, is indicated for times of orbital forced warming, such as the African Humid Period (9.8 to 7 kyr BP). An intensified African monsoon during boreal summer and the northernmost position of the tropical rainbelt within the last 31 kyr resulted in enhanced river discharge from the northward-extended drainage area (or river basin) initiating intense phytoplankton blooms. In the late Holocene (4 to 0 kyr BP) strong carbonate dissolution may have been caused by even more enhanced organic matter fluxes to the sea floor. Increasing aridity on the continent and stronger NE trade winds induced intensive, seasonal coastal upwelling.

Living benthic foraminiferal assemblages in surface samples of the Arabian Sea

The distribution, biomass, and diversity of living (Rose Bengal stained) deep-sea benthic foraminifera (>30 µm) were investigated with multicorer samples from seven stations in the Arabian Sea during the intermonsoonal periods in March and in September/October, 1995. Water depths of the stations ranged between 1916 and 4425 m. The distribution of benthic foraminifera was compared with dissolved oxygen, % organic carbon, % calcium carbonate, ammonium, % silica, chloroplastic pigment equivalents, sand content, pore water content of the sediment, and organic carbon flux to explain the foraminiferal patterns and depositional environments. A total of six species-communities comprising 178 living species were identified by principal component analysis. The seasonal comparison shows that at the western stations foraminiferal abundance and biomass were higher during the Spring Intermonsoon than during the Fall Intermonsoon. The regional comparison indicates a distinct gradient in abundance, biomass, and diversity from west to east, and for biomass from north to south. Highest values are recorded in the western part of the Arabian Sea, where the influence of coastal and offshore upwelling are responsible for high carbon fluxes. Estimated total biomass of living benthic foraminifera integrated for the upper 5 cm of the sediment ranged between 11 mg Corg m**-2 at the southern station and 420 mg Corg m**-2 at the western station. Foraminifera in the size range from 30 to 125 ?m, the so-called microforaminifera, contributed between 20 and 65% to the abundance, but only 3% to 28% to the biomass of the fauna. Highest values were found in the central and southern Arabian Sea, indicating their importance in oligotrophic deep-sea areas. The overall abundance of benthic foraminifera is positively correlated with oxygen content and pore volume, and partly with carbon content and chloroplastic pigment equivalents of the sediment. The distributional patterns of the communities seem to be controlled by sand fraction, dissolved oxygen, calcium carbonate and organic carbon content of the sediment, but the critical variables are of different significance for each community.

Sedimentology of ODP sites in the Cape Basin, southeast Atlantic Ocean

Middle/late Miocene to early Pliocene sedimentary sequences along the continental margin of southwest Africa have changes that correspond to the carbonate crash (12-9 Ma) and biogenic bloom events (~7-4 Ma) described in the equatorial Pacific by Farrell et al. (1995, doi:10.2973/odp.proc.sr.138.143.1995). To explore the origins of these changes, we analyzed the carbon and coarse fraction contents of sediments from ODP Sites 1085, 1086, and 1087 at a time resolution of 5 to 30 kyr. Several major drops in CaCO3 concentration between 12 and 9 Ma are caused by dilution from major increases in clastic input from the Oranje River during global sea level regressions. Abundant pyrite crystals and good preservation of fish debris reflect low oxygenation of bottom/pore waters. Regional productivity was enhanced during the time equivalent to the carbonate crash period. Higher benthic/planktic foraminiferal ratios indicate that CaCO3 dissolution at Site 1085 peaked between 9 to 7 Ma, which was after the global carbonate crash. This period of enhanced dissolution suggests that Site 1085 was located within a low-oxygen water mass that dissolved CaCO3 more easily than North Atlantic Deep Water, which began to bathe this site at 7 Ma. At 7 to 6 Ma, the onset of the biogenic bloom, increases and variations in total organic carbon and benthic foraminiferal accumulation rates show that paleoproductivity increased significantly above values observed during the carbonate crash period and fluctuated widely. We attribute the late Miocene paleoproductivity increase off southwest Africa to ocean-wide increases in nutrient supply and delivery.

Quaternary through early Eocene benthic foraminifera off Peru

Stratigraphic assemblages of Quaternary through early Eocene benthic foraminifers were recovered among 10 Peru margin drill sites. Various hiatuses and intervals barren in foraminifers characterize the sections, but numerous samples contain abundant, well-preserved benthic foraminifers. Bathymetry of the extant species and California-based estimates of the paleobathymetry of the extinct species permit recognition of Quaternary sea-level fluctuations between shelf and upper bathyal depths that produced vertical migrations of oxygenated and low-oxygen habitats at the six shallow sites. Assemblages from lower-slope sites at about 9° and 11°S indicate a general subsidence of the continental margin from shelf or upper bathyal depths in Eocene time to the present lower bathyal depths. Data from 11°S suggest a major part of this subsidence occurred in late Oligocene to early Miocene time. Downslope-transported shelf specimens, particularly the small biserial species, Bolivina costata and B. vaughani, are major contributors to these lower bathyal assemblages from the middle Miocene through Quaternary time.

Occurrence and chemistry of microtektites of ODP Site 121-758

The Toba lake event, the Australasian microtektite event, and the Cretaceous/Paleogene boundary were analyzed on the basis of foraminifers, carbonate content, trace elements, and spherules (microtektites). The Toba ash event, recovered in Hole 758C, may have had minor influences on the foraminiferal populations. The Australasian tektite event has probably some influence on foraminiferal ecology, because the larger specimens become scarce just above the microtektite layer. Microtektites recovered from Hole 758B closely resemble spherules recovered from several Cretaceous/Paleogene boundary localities in North America. The Cretaceous/Paleogene spherules, however, are usually larger and are completely altered to goyazite in the terrestrial environment and to smectite in a marine environment. The Cretaceous/Paleogene boundary of Hole 752B does not show obvious anomalous trace-element concentrations, and iridium concentrations are below our detection limits. The trace-element pattern is dominated by the alternation of chalk with volcanic ash layers above the Cretaceous/Paleogene boundary.

Data on multidisciplinary research in the Tajura Rift (Gulf of Aden) during Cruise 7 of R/V Akademik Mstislav Keldysh in winter 1983-1984

In the collective monograph results of geological and geophysical studies in the Tadjura Rift carried out by conventional outboard instruments and from deep/sea manned submersibles "Pisces" in winter 1983-1984 are reported. Main features of rift tectonics, geology, petrology, and geochemistry of basalts from the rift are under consideration. An emphasis is made on lithology, stratigraphy, and geochemistry of bottom sediments. Roles of terrigenous, edafogenic, biogenic, and hydrothermal components in formation of bottom sediments from the rift zone are shown.

Geochemistry of middle Eocene-lower Oligocene pelagic sediments of ODP Hole 105-647A

Geochemical analyses of the middle Eocene through lower Oligocene lithologic Unit IIIC (260-518 meters below seafloor [mbsf]) indicate a relatively constant geochemical composition of the detrital fraction throughout this depositional interval at Ocean Drilling Program (ODP) Site 647 in the southern Labrador Sea. The main variability occurs in redox-sensitive elements (e.g., iron, manganese, and phosphorus), which may be related to early diagenetic mobility in anaerobic pore waters during bacterial decomposition of organic matter. Initial preservation of organic matter was mediated by high sedimentation rates (36 m/m.y.). High iron (Fe) and manganese (Mn) contents are associated with carbonate concretions of siderite, manganosiderite, and rhodochrosite. These concretions probably formed in response to elevated pore-water alkalinity and total dissolved carbon dioxide (CO2) concentrations resulting from bacterial sulfate reduction, as indicated by nodule stable-isotope compositions and pore-water geochemistry. These nodules differ from those found in upper Cenozoic hemipelagic sequences in that they are not associated with methanogenesis. Phosphate minerals (carbonate-fluorapatite) precipitated in some intervals, probably as the result of desorption of phosphorus from iron and manganese during reduction. The bulk chemical composition of the sediments differs little from that of North Atlantic Quaternary abyssal red clays, but may contain a minor hydrothermal component. The silicon/ aluminum (Si/Al) ratio, however, is high and variable and probably reflects original variations in biogenic opal, much of which is now altered to smectite and/or opal CT. An increase in the sodium/potassium (Na/K) ratio in the upper Eocene corresponds to the beginning of coarsergrained feldspar flux to the site, possibly marking the onset of more vigorous deep currents. Although the Site 647 cores provide a nearly complete high-resolution, high-latitude Eocene-Oligocene record, the high sedimentation rate and somewhat unusual diagenetic conditions have led to variable alteration of benthic foraminifers and fine-fraction carbonate and have overprinted the original stable-isotope records. Planktonic foraminifers are less altered, but on the whole, there is little chance of sorting out the nature and timing of environmental change on the basis of our stable-isotope analyses.

Benthic foraminiferal genera in DSDP Hole 95-612

On the basis of lithologic, foraminiferal, seismostratigraphic, and downhole logging characteristics, we identified seven distinctive erosional unconformities at the contacts of the principal depositional sequences at Site 612 on the New Jersey Continental Slope (water depth 1404 m). These unconformities are present at the Campanian/Maestrichtian, lower Eocene/middle Eocene, middle Eocene/upper Eocene, upper Eocene/lower Oligocene, lower Oligocene/upper Miocene, Tortonian/Messinian, and upper Pliocene/upper Pleistocene contacts. The presence of coarse sand or redeposited intraclasts above six of the unconformities suggests downslope transport from the adjacent shelf by means of sediment gravity flows, which contributed in part to the erosion. Changes in the benthic foraminiferal assemblages across all but the Campanian/Maestrichtian contact indicate that significant changes in the seafloor environment, such as temperature and dissolved oxygen content, took place during the hiatuses. Comparison with modern analogous assemblages and application of a paleoslope model where possible, indicate that deposition took place in bathyal depths throughout the Late Cretaceous and Cenozoic at Site 612. An analysis of two-dimensional geometry and seismic fades changes of depositional sequences along U.S.G.S. multichannel seismic Line 25 suggests that Site 612 was an outer continental shelf location from the Campanian until the middle Eocene, when the shelf edge retreated 130 km landward, and Site 612 became a continental slope site. Following this, a prograding prism of terrigenous debris moved the shelf edge to near its present position by the end of the Miocene. Each unconformity identified can be traced widely on seismic reflection profiles and most have been identified from wells and outcrops on the coastal plain and other offshore basins of the U.S. Atlantic margin. Furthermore, their stratigraphic positions and equivalence to similar unconformities on the Goban Spur, in West Africa, New Zealand, Australia, and the Western Interior of the U.S. suggest that most contacts are correlative with the global unconformities and sea-level falls of the Vail depositional model.