Annotated record of the detailed examination of Mn deposits from ARIES Expedition stations

The cores and dredges described in this report were taken on the ARIES Expedition from November 1970 until October 1971 by the Scripps Institution of Oceanography from the R/V Thomas Washington. A total of 65 cores and dredges were recovered and are available at Scripps for sampling and study.

Annotated record of the detailed examination of Mn deposits from DSDP Hole 2-8

The Atlantic Advisory Panel proposed that Site 8 should be drilled on the rise between the Hatteras and Sohm Abyssal Plains (lat 35° 2l'N., long 67° 3l'W.) This location was considered to offer the best opportunity for realizing two primary objectives. The first of these objectives was to sample and date the oldest available rock in a region adjacent to the North American continent and as far as possible from the Mid-Atlantic Ridge. The second objective relates to the potential paleobiological and paleoecological information that could be derived from the sedimentary column in this general area.

Annotated record of the detailed examination of Mn deposits from DSDP Hole 2-12C

Site 12 of this report formerly was designated 14 by the Atlantic Advisory Panel. It was drilled in the Cape Verde Basin (latitude 19° 42'N, longitude 26° 01'W), which is underlain by 2000 to 2100 feet (0.9 to 1.1 seconds reflection time) of sediment. The bottom topography of the basin is fairly smooth but not to the degree of an abyssal plain. Site 12 was selected to provide material for paleontological investigations.

Annotated record of the detailed examination of Mn deposits from DSDP Site 159, Leg 16 (Cores 16-159-6 and 16-159-12)

DSDP 159 is one of a series of sites in the eastern equatorial Pacific on the west flank of the East Pacific Rise. It was selected by the Pacific Site Selection Panel on the premise that if hydrothermal processes on the crest of the East Pacific Rise supply the transition metals, a broad zone of such deposits should be present immediately above basement over the entire flank of the Rise.

Annotated record of the detailed examination of Mn deposits from PR II, CORPUS 4 Cruise, R/V Atlantic Twin off the coast of Puerto Rico

The dredges described in this report were taken on the PR II, CORPUS 4 Expedition in January 1969 by the USGS Woods Hole Coastal and Marine Science Center from the R/V Atlantic Twin. Dredges recovered and are available at USGS Woods Hole Coastal and Marine Science Center for sampling and study.

Annotated record of the detailed examination of Mn deposits from DSDP Site 20, Leg 3 (Holes 3-20, 3-20A and 3-20C)

Prior to arrival on this site, the only survey data available was from the Vema-20 crossing of the area. The recommended site location was over a relatively smooth valley in the bottom topography at about 4750 meters (15,580 feet) depth (uncorrected), about 10 kilometers wide E-W between peaks (or ridges) on either side. Sediment thickness was unknown. The center of the valley is near the peak of a wide (40 to 50 kilometers) positive magnetic anomaly, identified as Magnetic Anomaly 30 in the hypothesized geomagnetic time scale with an age of 72 million years.

Annotated record of the detailed examination of Mn deposits from DSDP Hole 2-9A

The Atlantic Advisory Panel proposed that Site 9 should be drilled on the northeastern flank of the Bermuda Rise (lat. 32° 37' N., long. 59° 10' W.), which is about 100 miles west of the Sohm Abyssal Plain. The bottom of this region consists of low linear ridges that are roughly parallel and oriented in a northwest-southeasterly direction. Scattered seamounts, some of which have peaks 2000 fathoms (3660 meters) below sea level, arise from the otherwise featureless sea floor between the ridges. The primary purpose in drilling Site 9 was to examine a sedimentary column where seismic reflectors were largely absent and to determine the age of sediments overlying acoustical basement in the examination of sea floor spreading.

Annotated record of the detailed examination of Mn deposits from R/V Tokaidaigaku Maru II Cruise GDP-1 stations

The present paper, deals with the results of the bottom sampling. Sampling devices were a gravity corer for heat flow measurement and dredges of bucket type.

Annotated record of the detailed examination of Mn deposits from DSDP Site 156, Leg 16 (Core 16-156-1)

This site was accidentally spudded on a small basement pinnacle and was abandoned when hard rock was reached within a few meters from the surface. The section penetrated consisted of coarse winnowed calcareous sand over thin chalk ooze resting on a hard crust of ferromanganese oxide presumably covering basalt.

Annotated record of the detailed examination of Mn deposits from DSDP Hole 3-13 and Hole 3-15

The preliminary planning and approach to site 13 were taken from the JOIDES Atlantic Advisory Panel Report and from a previous detailed survey of the site by R/V Vema of the Lamont Geological Observatory. Several CSP profiles crossing the selected site in various directions show an uplifted portion of the sea floor roughly circular in shape of about 10 kilometers in diameter. In contrast to the smooth bottom of the surrounding abyssal plain, the topography of the small rise selected for the site has a small-scale roughness of amplitude of 40 to 80 meters. The work reported here is a biostratigraphic summary of available samples. Only the most important and biostratigraphically significant components of the faunas have been noted. No attempt has been made to give an exhaustive faunal analysis of the samples seen.

Annotated record of the detailed examination of Mn deposits from BLM Leg Alpha Cruise, R/V Kana Keoki off the south-western coastal area of the Gulf of Mexico off Texas

The BLM-OCS (Bureau of Land Management-Outer Continental Shelf) program was designed to establish chemical, biological, and geological baseline on the South Texas Continental Shelf. The focus for the geological program was to establish the nature and amount of the suspended sediment in the water column, of the Holocene sediments on the shelf, and to identify and locate regions of geology conditions which may be hazardous to OCS operations. To accomplish these goals three cruises were planned. The report constitutes results of the first cruise. The results of these cruises associated with the subsequent laboratory analysis, enabled to establish a detailed baseline in order to provide significant geologic and biologic data for environmental assessment. Dredges recovered are available at University of Texas (see: BLM/OCS South Texas Outer Continental Shelf (STOCS) Project Sediment Data http://www.ngdc.noaa.gov/docucomp/page?xml=NOAA/NESDIS/NGDC/MGG/Geology/iso/xml/G02888.xml&view=getDataView&header=none).

Annotated record of the detailed examination of Mn deposits from R/V Xiang Yang Hong 16 stations (1983) in the Pacific Ocean

Electron microprobe and X-ray diffraction data for north Pacific manganese nodules reveal that the transition metal distributions are controlled by the mineralogy. Microlayers rich in 10Å-manganates generally have high Mn/Fe ratios and positive correlations between Ni, Cu and Mn, and between Co and Fe. Microlayers rich in vernadite, on the other hand, show low Mn/Fe ratios, and Co, Ni and Cu all show positive correlations with Mn. The 10Å-manganates form mainly in porewaters with high Mn/Fe ratios. The Ni2+ and Cu2+ ions are post-depositionally incorporated into the interlayers of the manganates, whereas Co3+ is substituted for Fe3+ in ferric oxyhydroxides. In seawater with a low Mn/Fe ratio, on the other hand, the adsorption of positively charged ferric oxyhydroxides on negatively charged [MnO6] octahedral layers suppresses the growth of 10Å-manganates, enhancing the formation of vernadite. Positively charged hydroxides of Co3+, Ni2+ and Cu2+ are also adsorbed on the [MnO6] layers. These mechanisms of mineral formation and metal uptake are corroborated by data for other oceanic non-hydrothermal manganese nodules and crusts.

Annotated record of the detailed examination of Mn deposits from R.R.S. "Discovery" Cruise 11 stations

During Discovery Cruise 11, April-May 1966, eleven hauls were made on the crest and on the southern facing slope of Palmer Ridge in the Peake Deep area in order to fill out the information gained last year. Limestones were collected ranging in age from lowest Eocene through to Upper Tertiary, and several hauls successfully sampled the basement beneath these, producing weathered basalts, metamorphosed basalts and dolerites. In Peake Deep on the north slope of Palmer Ridge hard Eocene sediments were core sampled near the base of the slope but no cores could be got near the top.

Annotated record of the detailed examination of Mn deposits from BLM Leg Bravo Cruise, R/V Kana Keoki off the south-western coastal area of the Gulf of Mexico off Texas

The BLM-OCS (Bureau of Land Management-Outer Continental Shelf) program was designed to establish chemical, biological, and geological baseline on the South Texas Continental Shelf. The focus for the geological program was to establish the nature and amount of the suspended sediment in the water column, of the Holocene sediments on the shelf, and to identify and locate regions of geology conditions which may be hazardous to OCS operations. To accomplish these goals three cruises were planned. The report constitutes results of the second cruise. The results of these cruises associated with the subsequent laboratory analysis, enabled to establish a detailed baseline in order to provide significant geologic and biologic data for environmental assessment. Dredges recovered are available at University of Texas (see: BLM/OCS South Texas Outer Continental Shelf (STOCS) Project Sediment Data http://www.ngdc.noaa.gov/docucomp/page?xml=NOAA/NESDIS/NGDC/MGG/Geology/iso/xml/G02888.xml&view=getDataView&header=none).

Annotated record of the detailed examination of Mn deposits from DSDP Site 42, Leg 5 (Cores 5-42-5, 5-42-6, 5-42-9)

Site 42 is one of the series of sites selected by the Pacific Advisory Panel along the 140th meridian to sample the longitudinal variation in sediment composition in the eastern Pacific. The site is located in an area of abyssal hills between the Clarion and Clipperton Fracture Zones, and is at the northern margin of the thick development of acoustically transparent sediment extending along the equator.