6 resultados para Helium, Helium-3, ³He, Polarisator, hyperpolarisiert

em University of Connecticut - USA


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The 1937 paper of Gronwall which concerns an alternative form for the Schrodinger Equation of the 2-electron Helium problem is re-derived in a (hopefully) transparent (possibly pedestrian) manner.

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The difficulties of applying the Hartree-Fock method to many body problems is illustrated by treating Helium's electrons up to the point where tractability vanishes. Second, the problem of applying Hartree-Fock methods to the helium atom's electrons, when they are constrained to remain on a sphere, is revisited. The 6-dimensional total energy operator is reduced to a 2-dimensional one, and the application of that 2-dimensional operator in the Hartree-Fock mode is discussed.

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This is a corrected version of the Phys. Rev. A 74,14501 (2006) article. The result is improved slightly from that in the original paper.

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Helium Hamiltonian transformations are discussed in extreme detail.

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The Hartree-Fock method is applied to Helium's electrons to show explicitly how the coupled equations reflect the interactions between electrons.

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