Microwave Spectroscopy and Structures of Several Substituted Acetylenes and Fluorocarbons

The structures of two substituted acetylene compounds have been characterized from their microwave rotational spectra. In the first study, two structures of 6-methyl-3-heptyne have been determined. This compound can be thought of as an ethyl group separated from an isobutyl group by a C≡C spacer. Both structures have the ethyl and isobutyl groups eclipsed, consistent with the dominant interaction determining the orientation about the acetylene axis being the weak dispersion attraction between the end groups. One structure is with the isobutyl group in a symmetric conformation and the other with the isobutyl group asymmetric. In addition, the microwave spectrum of the butane analogue 3,5-octadiyne has been observed. This compound consists of two ethyl groups separated by two C≡C spacers. The study is still in progress, but it appears that the ethyl end groups are freely rotating. Therefore, it seems that the dispersion attractions between the end groups are too weak at this longer distance of about 7 Å. The structures of several fluorocarbons have also been studied by microwave spectroscopy. The structures of perfluoropentane and perfluorohexane have been shown to be helical, like the polymer polytetrafluoroethylene (Teflon©). The structure of perfluoropropane and two conformers of 1H-heptafluoropropane have been determined to be non-helical. It is apparent that the steric and dipole repulsions between fluorine atoms that have been attributed to the helical structure of longer fluorocarbon chains are not sufficient in a three carbon chain to cause a twist in the structures.

A Student Manual for Venture Consulting

This manual is written to provide students taking the venture consulting class a better understanding of how to consult a small or medium sized business. It covers topics such as how to find a client, how to determine the business problem, how to collect data from customers as well as managers and employees, and how to come up with solution recommendations. By reading the manual, students will gain a better understanding of the consulting industry and will have a guide to help them through the project.

Trapped in the Bell Jar: Mental Illness in College Students

This is a magazine article that explores the rising problem of mental health in college students, focusing on Connecticut. It explores the experiences of three college students dealing with depression and bipolar disorder, a family who lost a child to suicide, and the measures taken by colleges in Connecticut to curb the problem.

Adolescent Meaning Making of Past Experience

This study examined the meaning making processes of self-defining memories in adolescents, as well as how they co-construct the narratives of these events with their parents. The sample consisted of 53 students, aged 12-14, who came in for recorded laboratory sessions to discuss self-defining memories with their parents. These sessions were later coded on levels of meaning making and co-construction. These codes were, then, analyzed with the adolescents’ questionnaire scores regarding friendship quality, internalizing, and externalizing behaviors. The data revealed that adolescents and parents were both rated higher for more complex levels of meaning making and that those rated higher for more complex meaning making abilities had better friendship qualities. The implications of these findings were discussed in terms of their importance for parents supporting their children’s emotional expressivity, narrative abilities, and meaning making strategies.

Oceans and Human Heath: Hand in Hand

Healthy oceans and healthy humans are inseparable. This article discusses new pharmaceuticals that are coming from the sea, and also ocean problems like harmful algal blooms that impact humans.

Looking Ahead to Spring's Returning Bounty: Natal Homing

Natal homing plays a part in fisheries restoration. This article describes research by Dr. Jason Vokoun and his students on otoliths in migratory finfish such as river herring, alewives, etc.

Marine Spatial Planning is coming to an ocean near you

There are too many conflicting uses of the ocean in a time where resources are rapidly dwindling. Marine Spatial Planning is catching on globally, and may soon come to Long Island Sound, but it may be difficult to decide who gets to do what, where.

DNA, Red Tide and the Sea: a new exhibit at Mystic Aquarium & IFE

DNA, Red Tide and the Sea is a new exhibit at Mystic Aquarium & IFE. It was developed by UConn Marine Sciences Professor Senjie Lin, and Mystic Aquarium. Children can extract DNA from fruit and learn about genetic codes and red tides in the ocean.

A Muddy Mystery: What's Causing Sudden Vegetation Dieback in Connecticut's Marshes?

Some of Connecticut's salt marshes are experiencing unprecedented sudden vegetation dieback, leaving bare mud where Spartina grass used to grow. In a Sea Grant project, Dr. Wade Elmer has investigated possible causes.

Protected Habitat is a Legacy of Generations

Land stewardship ethics must pass from one generation to the next in order to be effective. Some examples in Connecticut are presented.

Connecticut Sea Grant Alumni-to There from Here

Graduating seniors who have become Sea Grant John A. Knauss Fellows spend a year on Capitol Hill helping to shape the nation's coastal and ocean policies. But where do they go from there?

Pine Island: an Island Exploration

Pine Island, now owned by the University of Connecticut, has a rich and colorful history. Just off the Avery Point campus, the island has been home to a fertilizer factory, then a playground, and now a study site for UConn students.

Scoping Out the Shorebirds of Summer

The best places to go birding along Connecticut's shoreline and the delightful avian life you'll find there, are featured. Illustrated lavishly with photos from Connecticut Audubon.

Letter from the Editor Spring/Summer 2010

Despite the horrific oil spill in the Gulf and possible extinction of Kemp's Ridley sea turtles, there are still reasons to celebrate the shore--for example, Connecticut's shorebirds.