Geochemistry and Stable Isotopes of Surface Water and Groundwater in the Continental Pit in Butte, Montana, USA

The Continental porphyry Cu‐Mo mine, located 2 km east of the famous Berkeley Pit lake of Butte, Montana, contains two small lakes that vary in size depending on mining activity. In contrast to the acidic Berkeley Pit lake, the Continental Pit waters have near-neutral pH and relatively low metal concentrations. The main reason is geological: whereas the Berkeley Pit mined highly‐altered granite rich in pyrite with no neutralizing potential, the Continental Pit is mining weakly‐altered granite with lower pyrite concentrations and up to 1‐2% hydrothermal calcite. The purpose of this study was to gather and interpret information that bears on the chemistry of surface water and groundwater in the active Continental Pit. Pre‐existing chemistry data from sampling of the Continental Pit were compiled from the Montana Bureau of Mines and Geology and Montana Department of Environmental Quality records. In addition, in March of 2013, new water samples were collected from the mine’s main dewatering well, the Sarsfield well, and a nearby acidic seep (Pavilion Seep) and analyzed for trace metals and several stable isotopes, including dD and d18O of water, d13C of dissolved inorganic carbon, and d34S of dissolved sulfate. In December 2013, several soil samples were collected from the shore of the frozen pit lake and surrounding area. The soil samples were analyzed using X‐ray diffraction to determine mineral content. Based on Visual Minteq modeling, water in the Continental Pit lake is near equilibrium with a number of carbonate, sulfate, and molybdate minerals, including calcite, dolomite, rhodochrosite (MnCO3), brochantite (CuSO4·3Cu(OH)2), malachite (Cu2CO3(OH)2), hydrozincite (Zn5(CO3)2(OH)6), gypsum, and powellite (CaMoO4). The fact that these minerals are close to equilibrium suggests that they are present on the weathered mine walls and/or in the sediment of the surface water ponds. X‐Ray Diffraction (XRD) analysis of the pond “beach” sample failed to show any discrete metal‐bearing phases. One of the soil samples collected higher in the mine, near an area of active weathering of chalcocite‐rich ore, contained over 50% chalcanthite (CuSO4·5H2O). This water‐soluble copper salt is easily dissolved in water, and is probably a major source of copper to the pond and underlying groundwater system. However, concentrations of copper in the latter are probably controlled by other, less‐soluble minerals, such as brochantite or malachite. Although the acidity of the Pavilion Seep is high (~ 11 meq/L), the flow is much less than the Sarsfield Well at the current time. Thus, the pH, major and minor element chemistry in the Continental Pit lakes are buffered by calcite and other carbonate minerals. For the Continental Pit waters to become acidic, the influx of acidic seepage (e.g., Pavilion Seep) would need to increase substantially over its present volume.

Some Notes on the Composition of "Copper Pitch"

A supply of so-called "copper pitch" ore was received by the Montana Bureau of Mines and Geology in response to a request by them from a resident of Kalispell, who had previously sent a specimen to the Bureau for a mineralogical analysis. Since this material was little known and had apparently received but little study under a reflec­ting microscope, it was thought that such a study might throw some light on the mineralogical and chemical composition of the material.

Groundwater Under the Butte Hill - The East Camp Mining System and the Berkeley Pit

This lecture discusses monitoring activities of the Berkeley Pit for the past 31 years at the Montana Bureau of Mines and Geology in Butte, Montana.

The Amplifier - v. 4, no. 8

In this issue...Mines Hockey, Ed Simonich, Faculty Wives Club, convocation, Mineral Research Center, Drama Club, Memoir 36, Montana Bureau of Mines and Geology

The Amplifier - v. 5, no. 9

In this issue...Engineering Days, Mine Rescue and First Aid, Chemistry Department, Mineral Club, Anderson-Carlisle Society, Honor Roll, Continental Oil Company, Intramural basketball

The Amplifier - v. 6, no. 9

In this issue...M Days, beard contest, Anderson - Carlisle Society, Honor Roll, South Africa, Magma, International Club, First Aid, Bob Hauck, Continental Oil Company, Montana Power

The Amplifier - v. 7, no. 8

in this issue...Sweetheart Swirl Dance, R J Trio, Air Force Base, Civil Rights, Bill Barry's Boxing Club, International Club, Donald E. Mahagin, Main Hall

Magma 1975

In this issue...Honors Convocation, Students, M Days, M Day Smoker, Sports, Montana Bureau of Mines and Geology, Awards, Cheerleaders

The Amplifier - v. 11, no. 1

In this issue...Student Council, Montana Bureau of Mines, Geology Camp, Dillon, Montana, Senator Mike Mansfield, All-State Basketball, Dolly Labranche, Alumni Association

The Amplifier - v. 16, no. 5

In this issue...Sweetheart Dance, Butte Symphony, Mineral Report, Montana Bureau of Mines and Geology, Noon Lecture Series, Poetry Contest, History of Tech, Library Fund

Age Relationships of Ore Deposits of Southwestern Montana (A Microscopic Study)

Although considerable work has been undertaken by some prominent geologists, the best known of which is that of Paul Billingsley and J. A. Grimes', in investigating the ore deposits of the Boulder Batholith and surrounding area, there has not been any complete microscopic investigation of these deposits, as a whole, published in the literature. With this in mind it was suggested to the writer by Professor Paul A. Schafer, of the Montana School of Mines, that a microscopic study of the ores of this region would be a worthwhile geologic problem. It was thought that the mineral association and the mode of mineral occurrence might afford methods of classify­ing these deposits so that they could be correlated with the age relationships worked out by Billingsley and Grimes.

The Electrowinning of Manganese from Rhodochrosite

Manganese is commonly known to be a metal of great strategic importance. It is essential in the production of all steels, first as a scavenger to remove oxygen and sulfur, and second as an alloying element in wear-resis­tant steels.

Spectrographic Analysis of Montana Limestones

Spectrographic analysis of limestones as a possible method of correlation of geologic formations is an altogether new line of investigation. As far as known the only previous work consists of a few analyses made by Fred Lines in his bachelor thesis work at Montana School of mines in the spring of 1942.

A Preliminary Investigation of the Hydrometallurgy of Philipsburg Manganese

In the past the steel industry of the United States has depended almost wholly on imports for its supplies of manganese. Although it is well known that there are enormous deposits of low grade manganese ore in the United States the production of substantial amounts of ferro-grade mater­ial from domestic sources presents a field for con­structive and practical research.

Laboratory Model Shaking Table; An Investigation of Defects and Suggested Improvements

The laboratory model is considered in this thesis. Information gained from this investigation has not been trans­ferred to the larger industrial machines. Some of the factors noted concerning the efficiency of the laboratory shaking table are inherent in this small scale model only.