6 resultados para Coordination chemistry of gold(I)

em Digital Commons - Montana Tech


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The accepted chemical reactions in the dissolution of gold by cyanide solutions require the presence of gold, cyanide, water, and oxygen. The importance of dissolved oxygen in cyanide solutions as a factor is recognized by those familiar with cyanidation. Manufacturers of cyanidation equipment realize the necessity of oxygen, as shown by the appliances they have developed which are attached to the agitators in order to saturate the cyanide solutions with air.

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Since the development of cyanidation into a highly efficient process for treating gold ores, many papers have been written on its various aspects. Although, there has been much work done on it, the chemistry of the reaction is not yet completely understood.

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Charcoal has been known for a considerable length of time to have the property of recovering gold, silver, and copper from cyanide solutions of these metals. Quantita­tive data that may shed light on the mechanism of the re­moval of these metals is very limited except that char­coal in a form known as activated has the power to abstract gold and silver in considerable quantities from the above solutions.

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Gold is widely distributed in the earth's crust in small quantities. Gold is found in nature in two forms; the element itself and the compound gold telluride. In all cases, silver in some proportion is an alloying constituent.

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An amalgam is an alloy of mercury with other metals, and amalgamation is the art of making or forming amalgams. In metallurgical language the word is limited to the means adopted for the recovery of gold and silver from their ores by the use of mercury.

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Carbon and carbonaceous material have been known to have a deleterious effect upon the cyanidation of gold and silver ores since the very beginning of the process. Organic matter is a common source of impu­rities in cyanide solution, its reducing effect being notorious.