The Effect of Impurities on the Electrodeposition of Zinc from Zinc Sulfate Solution Containing Antimony.

It has been proven by research and years of experience, that before electrolytic zinc is possible, the electrolyte, as zinc sulfate solution must be prepared as pure as is economical. In other words, the ideal electrolyte must only be a solution of one metal - zinc. Every other metal and carbon must be excluded if good recovery and a firm deposit is to be obtained.

Alkali Leaching of Antimony Sulphide and Electrolytic Recovery of Antimony from the Resulting Leach Solution

It is the purpose of this investigation to obtain some insight into optimum conditions for leaching Stib­nite with sodium hydroxide solution and also to steady the factors affecting the electrolysis of the resulting solution.

The Measurement of Current Efficiency in Zinc Sulphate Electrolytes Containing Antimony and Cobalt by Hydrogen Evolution

The measurement of current efficiency by hydrogen evolution is based on the assumption that the portion of the current which deposits no zinc will release hydrogen. This assumption is correct for solutions containing no impurities electropositive to zinc.

Age Hardening of Copper Antimony Alloys

A large number of alloys of varying percentages of copper and antimony were prepared. These alloys were treated in various ways which might be expected to produce age hardening. The effect of cold working was studied in the range where the alloys were malleable.

Hydrogen Overvoltage of Cadmium Bismuth and Antimony Bismuth Alloys

A method to measure hydrogen overvoltage was devel­oped and checked with metals of known overvoltage. Alloys of bismuth and antimony and of bismuth and cad­mium were prepared and their overvoltages determined.

Effect of Impurities upon Current Efficiency in the Electrolysis of Zinc Sulphate Solution

There are many elements which are detrimental to the current efficiency in the electrolysis of zinc sulphate solution. Fortunately the majority of these elements are easily removed in the purification process and cause no further trouble. The elements that are likely to cause trouble in ordinary plant operations are antimony, arsenic, cobalt, nickel, manganese and germanium. The following tests were made to determine the mutual effect on the current efficiency when several of the impurities were present in the electrolyte.

Some Effects of the Addition of Tellurium to Lead Alloys

From the standpoint of its practical useful­ness, the most important characteristics of metallic lead are its cheapness, resistance to corrosion, plas­ticity, high specific gravity, low melting point, and its ability to form alloys in which some properties are modified by the addition of other elements, while other properties remain the same.

An Investigation of the Precipitation of Cobalt with Zinc Dust

Cobalt, as well as copper, cadmium, and other impurities, is removed by selective precipitation with zinc during the zinc electrolyte purification cycle, and the purification residue may be treated by a Cadmium Plant for the recovery of cadmium.