28 resultados para Copper zinc tin sulphide


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Powder metallurgy, the most recent innovation in met­allurgical process, is not a new art; although not until recently did it become a matter of general interest, this being due not only to the products formed but also to the possibilities of future developments. The manufacture and application of metal powders is now beginning to take a position as a recognized part of the science of metallurgy.

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The ore investigated in this thesis is a zinc-copper-lead ore. Microscopic analysis of this complex sulphide ore showed it to contain pyrite, sphalerite, arsenopyrite, galena, chalcopyrite, tetrahedrite, and covellite, with quartz as the gangue constituent.

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In the deposition of metallic zinc by electro­lysis from neutral or acid solution, little difficulty is experienced provided certain impurities are absent from the electrolyte. The use of the process has long been considered as a potential source, patents on the process having been issued as early as 1880. However, the early experimenters failed to realize the importance of impurities in the electrolyte, and for this reason, the process suffered several severe setbacks when commercial plants were built.

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There are many elements which are detrimental to the current efficiency in the electrolysis of zinc sulphate solution. Fortunately the majority of these elements are easily removed in the purification process and cause no further trouble. The elements that are likely to cause trouble in ordinary plant operations are antimony, arsenic, cobalt, nickel, manganese and germanium. The following tests were made to determine the mutual effect on the current efficiency when several of the impurities were present in the electrolyte.

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Throughout the entire experiment the electrolysis were conducted in an eight-hundred cubic centimeter beaker. An excellent circulation of the solution was assured by means of an electric stirrer, vigorous gas evolution from the anodes, and by means of a regulated feed-discharge system. By means of this balance, solution of the same impurity concentration as that of the electrolyte was fed in the cell just as fast as the discharge was syphoned out.

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It has been proven by research and years of experience, that before electrolytic zinc is possible, the electrolyte, as zinc sulfate solution must be prepared as pure as is economical. In other words, the ideal electrolyte must only be a solution of one metal - zinc. Every other metal and carbon must be excluded if good recovery and a firm deposit is to be obtained.

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A hydrometallurgical process for the recovery of copper from flotation concentrates has long been con­sidered an attractive possibility. The object of such a method is to produce electrolytic copper without resorting to expensive matte smelting and converting.

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This investigation, carried on in the metallur­gical laboratories at the Montana School of Mines, was undertaken with the desire to work out a rapid method for the estimation, or the determination, of the amount of lead in zinc.

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The purpose of this investigation was to ascertain if advantage could be taken of the copper in the precipitates as a collecting agent of the precious metals in the direct smelting furnace.The products produced to be low grade anode bullion and a slag low in precious metals, high in zinc and lead.

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At the present time ore bodies being mined are becoming more and more complex in mineral association, thus presenting a more difficult problem in their concentration. Lead-zinc sulphide ores are among the more common ores which present such difficulties.

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In 1947, out of the 100,000 long tons of tin con­sumed in the United States, 25,000 tons went into solder. Tin plate took 39,000 tons while babbit, bronze and coll­apsible tubes accounted for approximately 17,000 tons. Solder ranked second to tin plate and required more than the next three major uses combined.

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In this investigation, attention is directed to the phases covered by a 28 per cent tin alloy. When the investigation was started, consideration was given to the possibility of making a Time - Temperature - Transformation curve for this parti­cular alloy. As the work progressed and further research was carried on, this phase of the work was abandoned.

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The purpose of this investigation is to determine the effect of the factors listed previously by conducting a series of tests that will indicate the ex­tent to which the purification is influenced by time, temperature, zinc oust size, zinc dust quantity, iron concentration, two stage precipitation, and aeration.