Examining the Role of Vocational Rehabilitation on Access to Care and Public Health Outcomes for People Living with HIV/AIDS

The purpose of this study is to examine the role of vocational rehabilitation services in contributing to the goals of the National HIV/AIDS strategy. Three key research questions are addressed: (a) What is the relationship among factors associated with the use of vocational rehabilitation services for people living with HIV/AIDS? (b) Are the factors associated with use of vocational rehabilitation also associated with access to health care, supplemental employment services and reduced risk of HIV transmission? And (c) What unique role does use of vocational rehabilitation services play in access to health care and HIV prevention? Survey research methods were used to collect data from a broad sample of volunteer respondents who represented diverse racial (37% Black, 37% White, 18% Latino, 7% other), gender (65% male, 34% female, 1% transgender) and sexual orientation (48% heterosexual, 44% gay, 8% bisexual) backgrounds. The fit of the final structural equation model was good (root mean square error of approximation = .055, Comparative Fit Index=.953, Tucker Lewis Index=.945). Standardized effects with bootstrap confidence intervals are reported. Overall, the findings support the hypothesis that vocational rehabilitation services can play an important role in health and prevention strategies outlined in the National HIV/AIDS strategy.

Absolute pKa Determinations for Substituted Phenols

The CBS-QB3 method was used to calculate the gas-phase free energy difference between 20 phenols and their respective anions, and the CPCM continuum solvation method was applied to calculate the free energy differences of solvation for the phenols and their anions. The CPCM solvation calculations were performed on both gas-phase and solvent-phase optimized structures. Absolute pKa calculations with solvated phase optimized structures for the CPCM calculations yielded standard deviations and root-mean-square errors of less than 0.4 pKa unit. This study is the most accurate absolute determination of the pKa values of phenols, and is among the most accurate of any such calculations for any group of compounds. The ability to make accurate predictions of pKa values using a coherent, well-defined approach, without external approximations or fitting to experimental data, is of general importance to the chemical community. The solvated phase optimized structures of the anions are absolutely critical to obtain this level of accuracy, and yield a more realistic charge separation between the negatively charged oxygen and the ring system of the phenoxide anions.

The Syntax of the EPP in Irish

In this paper, I will provide a detailed analysis of the EPP, a principle of theoretical syntax, in Modern Irish. I will document previous scholarship on this issue to give a comprehensive view of ways of reconciling the syntax with the language data, as language data is key to testing theoretical predictions. I will also provide my own model incorporating the EPP into Irish. First, I will provide necessary information about the background and development of the EPP and the Minimalist system in syntax, as well as a discussion of the Irish language and the features which make it relevant to the study of the EPP. Then, I will present the models of Irish and the considerations of the EPP which have shaped and influenced my own. These models include both instances of altering the definition of the EPP to increase its universal application and of adapting models of VSO languages to fit the prevailing definition of the EPP. Lastly, I will detail my own model for Irish sentence structure, which suggests an alternate subject position in the syntax which would allow for the EPP to adapt to fit VSO word order. An analysis of passive and the unaccusative constructions, as well as support from contemporary syntactic theory, will support this model. To complete my consideration of Irish and the EPP, I will also provide a discussion of whether of not pleonastic pronouns function in Irish and how they would be accounted for in my model.