Magnetic anisotropy reveals Neogene tectonic overprint in highly strained carbonate mylonites from the Morcles nappe, Switzerland

The anisotropy of magnetic susceptibility (AMS) has been measured with low- and high-field methods, in deformed carbonate rocks along the Morcles nappe shear zone (Helvetic Alps). High-field measurements at room temperature and 77 K enable the separation of the ferrimagnetic, paramagnetic and diamagnetic anisotropy. The ferrimagnetic sub-fabric is generally insignificant in these rocks, contributing less than 10% to the total AMS. AMS results for both the separated diamagnetic and paramagnetic subfabrics are consistent with the regional shear movement in the late-stage formation of the Helvetic nappes, as seen in the Morcles nappe, whose inverted limb indicate shear displacement towards the northwest. The diamagnetic anisotropy correlates well quantitatively with the calculated magnetic anisotropy based on the calcite texture. There is a gradational change in the degree of anisotropy related to the strain gradient along the shear zone. A more complex magnetic fabric, resulting from partial overprinting due to displacement along the Simplon–Rhône fault, is evident at one site near the root zone of the nappe. Partial overprinting of the magnetic fabric appears to have taken place in two locations farther up the shear zone as well. This late phase deformation is associated with recent exhumation of the Mont Blanc and Belledonne external massifs and orogen parallel extension, and is reflected by the AMS. Rocks with bulk susceptibility ∼0 SI, and simple mineral compositions are ideal for low temperature high-field torque, as this method helps to enhance the paramagnetic susceptibility and anisotropy, which may otherwise be masked by the mixed magnetic contributions of the composite magnetic fabric.

Strain-induced structural instability in FeRh

We perform density functional calculations to investigate the structure of the intermetallic alloy FeRh under epitaxial strain. Bulk FeRh exhibits a metamagnetic transition from a low-temperature antiferromagnetic (AFM) phase to a ferromagnetic phase at 350 K, and its strain dependence is of interest for tuning the transition temperature to the room-temperature operating conditions of typical memory devices. We find an unusually strong dependence of the structural energetics on the choice of exchange-correlation functional, with the usual local density approximation yielding the wrong ground-state structure, and generalized gradient (GGA) extensions being in better agreement with the bulk experimental structure. Using the GGA we show the existence of a metastable face-centered-cubic-like AFM structure that is reached from the ground-state body-centered-cubic-like AFM structure by following the epitaxial Bain path. We show that the behavior is well described using nonlinear elasticity theory, which captures the softening and eventual sign change of the orthorhombic shear modulus under compressive strain, consistent with this structural instability. Finally, we predict the existence of an additional unit-cell-doubling lattice instability, which should be observable at low temperature.