A stochastic principle behind polar properties of condensed molecular matter

A statistical mechanics view leads to the conclusion that polar molecules allowed to populate a degree of freedom for orientational disorder in a condensed phase thermalize into a bi-polar state featuring zero net polarity. In cases of orientational disorder polar order of condensed molecular matter can only exist in corresponding sectors of opposite average polarities. Channel type inclusion compounds, single component molecular crystals, solid solutions, optically anomalous crystals, inorganic ionic crystals, biomimetic crystals and biological tissues investigated by scanning pyroelectric and phase sensitive second harmonic generation microscopy all showed domains of opposite polarities in their final grown state. For reported polar molecular crystal structures it is assumed that kinetic hindrance along one direction of the polar axis is preventing the formation of a bi-polar state, thus allowing for a kinetically controlled mono-domain state. In this review we summarize theoretical and experimental findings leading to far reaching conclusions on the polar state of solid molecular matter. “… no stationary state … of a system has an electrical dipole moment.” P. W. Anderson, Science, 1972, 177, 393.

Combined LARES-LAGEOS Solutions

LARES is a new spherical geodetic satellite designed for SLR observations. It is made of solid tungsten alloy covered with 92 corner cubes. Due to a very small area-to-mass ratio, the sensitivity of LARES orbits to non-gravitational forces is greatly minimized. We processed 82 weeks (Feb12-Aug13) of LARES observations from a global SLR network and we analyzed the contribution of LARES data to the current SLR products (e.g., global scale and geocenter coordinates). The quality of the combined LARES+LAGEOS-1/2 solutions is also addressed in the paper. Introduction LARES