Main characteristics of the emission from elliptical galaxies

Elliptical galaxies are one of the most characteristic objects we can find in the sky. In order to unveil their properties, such as their structure or chemical composition, one must study their spectral emission. In fact they seem to behave rather differently when observed with different eyes. This is because their light is mainly brought by two different components: optical radiation arises from its stars, while the X emission is primarly due to a halo of extremely hot gas in which ellipticals seem to be embedded. After a brief classification, the two main processes linked to these phenomena will be described, together with the informations we can collect thanks to them. Eventually, we will take a quick look at the other regions of the electromagnetic spectrum.

Antarctic cloud spectral emission from ground-based measurements, a focus on far infrared signatures

The present work belongs to the PRANA project, the first extensive field campaign of observation of atmospheric emission spectra covering the Far InfraRed spectral region, for more than two years. The principal deployed instrument is REFIR-PAD, a Fourier transform spectrometer used by us to study Antarctic cloud properties. A dataset covering the whole 2013 has been analyzed and, firstly, a selection of good quality spectra is performed, using, as thresholds, radiance values in few chosen spectral regions. These spectra are described in a synthetic way averaging radiances in selected intervals, converting them into BTs and finally considering the differences between each pair of them. A supervised feature selection algorithm is implemented with the purpose to select the features really informative about the presence, the phase and the type of cloud. Hence, training and test sets are collected, by means of Lidar quick-looks. The supervised classification step of the overall monthly datasets is performed using a SVM. On the base of this classification and with the help of Lidar observations, 29 non-precipitating ice cloud case studies are selected. A single spectrum, or at most an average over two or three spectra, is processed by means of the retrieval algorithm RT-RET, exploiting some main IR window channels, in order to extract cloud properties. Retrieved effective radii and optical depths are analyzed, to compare them with literature studies and to evaluate possible seasonal trends. Finally, retrieval output atmospheric profiles are used as inputs for simulations, assuming two different crystal habits, with the aim to examine our ability to reproduce radiances in the FIR. Substantial mis-estimations are found for FIR micro-windows: a high variability is observed in the spectral pattern of simulation deviations from measured spectra and an effort to link these deviations to cloud parameters has been performed.

Towards NIR emission: 2-(1H-tetrazol-1-yl)pyridine as versatile ligand for the synthesis of two new families of cationic and neutral Ir(III) complexes.

In the last decades, cyclometalated Ir(III) complexes have drawn a large interest for their unique properties: they are excellent triplet state emitters, thus the emission is phosphorescent in nature; typically high quantum yields and good stability make them good candidates for luminescent materials. Moreover, through an opportune choice of the ligands, it is possible to tune the emission along the whole visible spectra. Thanks to these interesting features, Ir(III) complexes have found different applications in several areas of applied science, from OLEDs to bioimaging. In particular, regarding the second application, a remarkable red-shift in the emission is required, in order to minimize the problem of the tissue penetration and the possible damages for the organisms. With the aim of synthesizing a new family of NIR emitting Ir(III) complexes, we envisaged the possibility to use for the first time 2-(1H-tetrazol-1-yl)pyridine as bidentate ligand able to provide the required red-shift of the emission of the final complexes. Exploiting the versatility of the ligand, I prepared two different families of heteroleptic Ir(III) complexes. In detail, in the first case the 2-(1H-tetrazol-1-yl)pyridine was used as bis-chelating N^N ligand, leading to cationic complexes, while in the second case it was used as cyclometalating C^N ligand, giving neutral complexes. The structures of the prepared molecules have been characterised by NMR spectroscopy and mass spectrometry. Moreover, the neutral complexes’ emissive properties have been measured: emission spectra have been recorded in solution at both room temperature and 77K, as well as in PMMA matrix. DFT calculation has then been performed and the obtained results have been compared to experimental ones.

Classical electrodynamics: retarded potentials and power emission by accelerated charges

L'obiettivo di questo lavoro è quello di analizzare la potenza emessa da una carica elettrica accelerata. Saranno studiati due casi speciali: accelerazione lineare e accelerazione circolare. Queste sono le configurazioni più frequenti e semplici da realizzare. Il primo passo consiste nel trovare un'espressione per il campo elettrico e il campo magnetico generati dalla carica. Questo sarà reso possibile dallo studio della distribuzione di carica di una sorgente puntiforme e dei potenziali che la descrivono. Nel passo successivo verrà calcolato il vettore di Poynting per una tale carica. Useremo questo risultato per trovare la potenza elettromagnetica irradiata totale integrando su tutte le direzioni di emissione. Nell'ultimo capitolo, infine, faremo uso di tutto ciò che è stato precedentemente trovato per studiare la potenza emessa da cariche negli acceleratori.

Theoretical study on generating luminous and controlled figures by spontaneous emission

La presente tesi si pone come obiettivo lo studio di meccanismi in grado di generare figure luminose nello spazio. Il metodo proposto è quello di riuscire a illuminare un piccolo punto nello spazio e di muoverlo ad una velocità tale da dare l'illusione di osservare un immagine fissa. Tale punto si assume che possa essere replicato più volte, in modo tale da costruire immagini più complesse grazie alla combinazione degli effetti. Il principio fisico a supporto dell'idea è stato trovato nei fenomeni di emissione spontanea, quindi in quei processi che vedono un atomo passare spontaneamente da uno stato elettronico eccitato a uno ad energia minore, liberando fotoni. Si sceglie di utilizzare uno schema di transizioni a quattro livelli energetici e di studiare la dinamica delle popolazioni di ciascun livello in funzione del tempo; la scelta di uno schema a quattro livelli è suggerita dalla possibilità di ottenere un emissione di fotoni "visibili", quindi con frequenza appartenente allo spettro visibile, a seguito di un eccitazione da parte di due laser "non visibili", in particolare infrarossi. Questa configurazione è particolarmente efficace se si considerano atomi con un unico elettrone di valenza. Inoltre, si vuole ricercare un elemento chimico che rispetti esattamente le condizioni richieste per eseguire le transizioni specificate; tra i vari elementi possibili è stato scelto il rubidio in stato gassoso, con i relativi livelli energetici da utilizzare.

Investigating the origin of radio emission from the intra-cluster bridge A399-A401

Radio bridges are a newly observed class of phenomena, they are large scale filamentary structures that span between pairs of clusters in a pre-merger phase. In my Thesis, starting from the observed synchrotron emission in the bridge A399-A401, I apply a Fermi I shock re-acceleration model under different conditions to the bridge. The purpose of my work is to check the likelihood of the above mentioned model. In particular the Inverse Compton emission that the model predicts is above the current observational constraints on Inverse Compton for the bridge A399-A401, this means that a Fermi I re-acceleration model is unlikely to describe the emission from the bridge, while a Fermi II turbulent re-acceleration model could still explain the origin of the emission in the bridge.

Exploration of X-ray, optical and radio emission of the radio-galaxy 3C 277.3

This thesis explores the X-ray nuclear and extended properties of the radio galaxy 3C 277.3, where a recent optical observation performed with the multi-unit spectroscopic explorer (MUSE) has revealed star-forming regions triggered by the propagation of non-thermal plasma in the intergalactic medium. This work aims to study the nuclear engine and its environment and, possibly, discover signatures of non-thermal plasma-gas interaction at high energies. 3C 277.3 was observed with the Chandra satellite five times from 2010 to 2014 for a total of about 200 ks. Data in the Chandra public archive were retrieved and analyzed. When necessary, the different pointings were combined to improve the signal-to-noise ratio. A detailed analysis of the Chandra image (obtained by combining all the observations) has revealed several emission regions. In addition to a bright nucleus, two jet knots and the northern hot spot were clearly detected by overlapping the X-ray data to a VLA map of the source at 1.4 GHz. An X-ray spectral analysis was performed for all these structures. Finally, the X-ray image was over-imposed on the MUSE data.