Development of a relationship between physical parameters of tsunami waves and tsunami intensity based on macroscopic effects and its application to the Italian tsunami database

Tsunamis are rare events. However, their impact can be devastating and it may extend to large geographical areas. For low-probability high-impact events like tsunamis, it is crucial to implement all possible actions to mitigate the risk. The tsunami hazard assessment is the result of a scientific process that integrates traditional geological methods, numerical modelling and the analysis of tsunami sources and historical records. For this reason, analysing past events and understanding how they interacted with the land is the only way to inform tsunami source and propagation models, and quantitatively test forecast models like hazard analyses. The primary objective of this thesis is to establish an explicit relationship between the macroscopic intensity, derived from historical descriptions, and the quantitative physical parameters measuring tsunami waves. This is done first by defining an approximate estimation method based on a simplified 1D physical onshore propagation model to convert the available observations into one reference physical metric. Wave height at the coast was chosen as the reference due to its stability and independence of inland effects. This method was then implemented for a set of well-known past events to build a homogeneous dataset with both macroseismic intensity and wave height. By performing an orthogonal regression, a direct and invertible empirical relationship could be established between the two parameters, accounting for their relevant uncertainties. The target relationship is extensively tested and finally applied to the Italian Tsunami Effect Database (ITED), providing a homogeneous estimation of the wave height for all existing tsunami observations in Italy. This provides the opportunity for meaningful comparison for models and simulations, as well as quantitatively testing tsunami hazard models for the Italian coasts and informing tsunami risk management initiatives.

Dithienopyrrole-based materials: development of new polymeric derivatives

The possibility to control molar mass and termination of the growing chain is fundamental to create well-defined, reproducible materials. For this reason, in order to apply polydithienopyrrole (PDTP) as organic conjugated polymer, the possibility of controlled polymerization needs to be verified. Another aspect that is still not completely explored is bound to the optical activity of the PDTP, which bearing appropriate substituents may adopt a helical conformation. The configuration of the helix, built up from achiral co-monomers, can be established in an enantiopure way by using only a small percentage of the chiral monomer co-polymerized with achiral co-monomer. The effect, called “sergeants and soldiers effect”, is expressed by the nonlinear increase of the chiral response vs the ratio of the chiral co-monomer used for the polymerization. To date, this effect is still not completely explored for PDTP. In this framework the project will investigate, firstly, the possibility to obtain a controlled polymerization of PDTP. Then, monomers with different side chains and organometallic functions will be screened for a CTCP-type polymerization. Also a Lewis-acid based cationic polymerization will be performed. Moreover the chemical derivatization of dithienopyrrole DTP is explored: the research is going to concern also block copolymers, built up by DTP and monomers of different nature. The research will be extended also to the investigation of optically active derivates of PDTP, using a chiral monomer for the synthesis. The possibility to develop a supramolecular distribution of the polymeric chains, together with the “sergeants and soldiers effect” will be checked investigating a series of polymers with increasing amounts of chiral monomer.

Development of a thermochemical/biological process to convert waste biomass into new resources

The increasing attention to environmental issues of recent times encourages us to find new methods for the production of energy from renewable sources, and to improve existing ones, increasing their energy yield. Most of the waste and agricultural residues, with a high content of lignin and non-hydrolysable polymers, cannot be effectively transformed into biofuels with existing technology. The purpose of the study was to develop a new thermochemical/ biological process (named Py-AD) for the valorization of scarcely biodegradable substances. A complete continuous prototype was design built and run for 1 year. This consists into a slow pyrolysis system coupled with two sequential digesters and showed to produce a clean pyrobiogas (a biogas with significant amount of C2-C3 hydrocarbons and residual CO/H2), biochar and bio-oil. Py-AD yielded 31.7% w/w biochar 32.5% w/w oil and 24.8% w/w pyrobiogas. The oil condensate obtained was fractionated in its aqueous and organic fraction (87% and 13% respectively). Subsequently, the anaerobic digestion of aqueous fraction was tested in a UASB reactor, for 180 days, in increasing organic loading rate (OLR). The maximum convertible concentration without undergoing instability phenomena and with complete degradation of pyrogenic chemicals was 1.25 gCOD L digester-1 d-1. The final yield of biomethane was equal to 40% of the theoretical yield and with a noticeable additional production equal to 20% of volatile fatty acids. The final results confirm that anaerobic digestion can be used as a useful tool for cleaning of slow pyrolysis products (both gas and condensable fraction) and the obtaining of relatively clean pyrobiogas that could be directly used in internal combustion engine.

Highlighting Interdisciplinarity between Physics and Mathematics in Historical Papers on Special Relativity: Development of an Analytical Tool for Characterising Boundary Crossing Mechanisms

Questa tesi di laurea si colloca all'interno del progetto Erasmus + IDENTITIES, il cui obiettivo è sviluppare materiali didattici interdisciplinari per la formazione iniziale degli insegnanti. Nello specifico, si dà seguito ad una ricerca condotta da Lorenzo Miani, finalizzata a mettere in evidenza come la Teoria della Relatività Speciale (STR) sia storicamente nata da una speciale interazione tra matematica e fisica. Tale co-evoluzione è stata cercata, e messa in evidenza, attraverso l’analisi dei quattro articoli fondativi della STR scritti da Lorentz (1904), Poincaré (1906), Einstein (1905) e Minkowski (1908). Per l’analisi di questi articoli abbiamo utilizzato la metafora del “confine”, esposta nella metateoria di Akkerman e Bakker (2011), riferendosi al confine tra Matematica e Fisica. È stato sviluppato uno strumento operativo di analisi di articoli originali per estrarne il rapporto tra le due discipline. Un’analisi di questo tipo può portare un contributo considerevole al Justification Problem, intercettando la possibilità di indagare sull’identità della Matematica, intesa come disciplina. Questo tipo di analisi ha permesso di comprendere gli “stili al confine” di ogni autore, e la natura delle Trasformazioni di Lorentz in quanto oggetto di confine. È inoltre illustrata la progettazione di un’attività per la formazione iniziale degli insegnanti. Questa si configura come un tutorial per lavori di gruppo, ed è stata sperimentata nel corso di Didattica della Fisica dell’Università di Bologna, tenuto dalla Professoressa Olivia Levrini. Grazie all’attività, è stato possibile riflettere sulle identità disciplinari e sull’importanza di fare “esperienze di confine” per superare stereotipi. Lo strumento elaborato nella tesi si apre a sviluppi futuri, dal momento che si presta ad essere utilizzato per l’analisi di una grande varietà di testi e per la costruzione di “boundary zone”, sempre più auspicate e incentivate nei report europei.