Evaluation of Th and U contamination in the CUORE experiment using a delayed coincidence analysis

The discovery of the neutrino mass is a direct evidence of new physics. Several questions arise from this observation, regarding the mechanism originating the neutrino masses and their hierarchy, the violation of lepton number conservation and the generation of the baryon asymmetry. These questions can be addressed by the experimental search for neutrinoless double beta (0\nu\beta\beta) decay, a nuclear decay consisting of two simultaneous beta emissions without the emission of two antineutrinos. 0\nu\beta\beta decay is possible only if neutrinos are identical to antineutrinos, namely if they are Majorana particles. Several experiments are searching for 0\nu\beta\beta decay. Among these, CUORE is employing 130Te embedded in TeO_2 bolometric crystals. It needs to have an accurate understanding of the background contribution in the energy region around the Q-value of 130Te. One of the main contributions is given by particles from the decay chains of contaminating nuclei (232Th, 235-238U) present in the active crystals or in the support structure. This thesis uses the 1 ton yr CUORE data to study these contamination by looking for events belonging to sub-chains of the Th and U decay chains and reconstructing their energy and time difference distributions in a delayed coincidence analysis. These results in combination with studies on the simulated data are then used to evaluate the contaminations. This is the first time this analysis is applied to the CUORE data and this thesis highlights the feasibility of it while providing a starting point for further studies. A part of the obtained results agrees with ones from previous analysis, demonstrating that delayed coincidence searches might improve the understanding of the CUORE experiment background. This kind of delayed coincidence analysis can also be reused in the future once the, CUORE upgrade, CUPID data will be ready to be analyzed, with the aim of improving the sensitivity to the 0\nu\beta\beta decay of 100Mo.

Double-stimulus sensitive (temperature and pH) self-assemblable polymers

The rheological properties of block co-polymers in water solution at different pH have been investigated. The block copolymers are based on different architectures containing poly(ethylene glycol), poly(propylene glycol) and different blocks of polymer that change their hydrophobic/hydrophilic behavior as a function of pH. The polymer chains of the starting material were extended at their functional ends with the pH-sensitive units using ATRP; this mechanism of controlled radical polymerization was chosen because of the need to minimize polydispersity and avoid transfer reactions possibly leading to homopolymeric inpurities. The starting material were modified in order to use them as macroinitiator for ATRP. The kinetic of each ATRP reaction has been investigated, in order to be able to synthesize polymers with different degree of polymerization, stopping the reaction when the desired polymers chain length has been reached. We will use polymer chains with different basicity and degree of polymerization to link any possible effect of their presence to the conditions under which they become hydrophobic. It has been shown that the rate of polymerization changes changing the type of macroinitiator and the type of monomer synthesized. The slowest rate of polymerization is the one with the most hindered monomer synthesized using the macroinitiator with the highest molecular weight. The water solubility of the synthesized polymers changes depending on the pH of the solution and on the structure of the polymers. It has been shown using 1H-NMR that some of the synthesized polymers are capable to self-aggregation in water solution. The self-aggregation and the type of aggregation is influenced from the structure of the polymer and from the pH of the solution. Changing the structure of the polymers and the pH it is possible to obtain different type of aggregates in solution. This aggregates differ for the volume occupied from them, and for their hardness. Rheological measurements have been demonstrated that the synthesized polymers are capable to form gel phases. The gelation temperature changes changing the structure of the aggregates in solution and it is possible to correlate the changing in the gelation temperature with the changing in the structure of the polymer.