Reservoir characterization of the Cardium Formation in the Ferrier Oilfield, west-central Alberta, Canada.

This thesis has the main aim of defining the lithostratigraphy, depositional architecture, post-depositional modifications and reservoir characteristics of the Cardium Formation in the Ferrier Oilfield, and how these characteristics can have great impact over production rates, GOR and produced fluid discrimination. In the Ferrier area, the Cardium Formation is composed by a NE prograding clastic sequence made up of offshore to shoreface deposits sealed by marine shales. The main reservoir is composed by sandstones and conglomerates interpreted to have deposited in a shoreface depositional environment. Lithofacies and net reservoir thickness mapping led to more detailed understanding of the 3D reservoir architecture, and cross-sections shed light on the Cardium depositional architecture and post-deposition sediment erosion in the Ferrier area. Detailed core logging, thin section, SEM and CL analyses were used to study the mineralogy, texture and pore characterization of the Cardium reservoir, and three main compartments have been identified based on production data and reservoir characteristics. Finally, two situations showing odd production behaviour of the Cardium were resolved. This shed light on the effect of structural features and reservoir quality and thickness over hydrocarbon migration pathways. The Ferrier example offers a unique case of fluid discrimination in clastic reservoirs due both to depositional and post-depositional factors, and could be used as analogue for similar situations in the Western Canadian Sedimentary Basin.

Optimization and characterization of a wheat-based biocomposite for additive manufacturing

In recent years plastic is a key material, fundamental for a large variety of implications. But its large utilization has the direct consequence of the disposal of tons of wastes, that in the major amount cannot be recycled. To pose a solution to the issue of the increasing amount of plastics that are rapidly accumulating all over the world, it is necessary to switch to biodegradable materials. This dissertation is focused on a biodegradable and biobased plastic (polylactic acid, PLA), in order to set free the material from the market and issues of oil, but the PLA is very expensive. For this reason it was added a part of natural component derived from wastes (wheat middling), that acts as reinforcement and decreases the cost of the final material forming a biocomposite. Since their interaction is difficult, the purpose of this dissertation is to improve the affinity between the PLA and the wheat middling.

Study and characterization of low molecular weight polymer solutions for application in lubricating oils

The aim of this thesis is to evaluate the possibility of using short linear polymer chains as additives in lubricating oil applications. Through previous works, it has been seen that they are particularly resistant to mechanical degradation, which is the main reason why lubricating oils need to be changed after a while. This is the main reason why they could be proposed as alternatives in the market. The results of this work have been split into two major phases: the first concentrated on characterizing a target product obtained through thermal degradation, starting from the original long chain parent polymer, and the second focused on the technological advancement of heat exchangers. Through the studies carried out, we’ve characterized our innovative polymers and the solutions made with them and base oil at different concentrations. The most promising result is that these short random coiled polymeric chains obey to a more general universal function which express the value of specific viscosity as function of a dimensionless quantity c/c*. For the design of the unit operation, several alternatives were proposed and these all shared the same final goal: cooling the polymer without the presence of oxygen to avoid oxidation and formation of unwanted substances. We’ve analyzed the main difficulties related to the presence of these highly viscous substances and, more importantly, how to deal with this situation (e.g. by considering radial static mixer or even more complex conformations).