Exploring the Higgs-muon coupling at a multi-TeV muon collider

We investigate the potential of a high-energy muon collider in measuring the muon Yukawa coupling (y_μ) in the production of two, three and four heavy bosons via muon-antimuon annihilations. We study the sensitivity of these processes to deviations of y_μ from the Standard Model prediction, parametrized by an effective dimension-6 operator in the Standard Model Effective Field Theory (SMEFT) framework. We also consider the κ framework, in which the deviation is simply parametrized by a strength modification of the μ+μ−h vertex alone. Both frameworks lead to an energy enhancement of the cross sections with one or more vector bosons, although the κ framework yields stronger effects, especially for the production of four bosons. On the contrary, for purely-Higgs final states the cross section is suppressed in the κ framework, while it is extremely sensitive to deviations in the SMEFT. We show that the triple-Higgs production is the most sensitive process to spot new physics effects on y_μ.

Influence of cladding on robustness of multi-storey buildings

In this dissertation the influence of a precast concrete cladding system on structural robustness of a multi-storey steel-composite building is studied. The analysis follows the well-established framework developed at Imperial College London for the appraisal of robustness of multi-storey buildings. For this scope a simplified nonlinear model of a typical precast concrete façade-system is developed. Particular attention is given to the connection system between structural frame and panel, recognised as the driving component of the nonlinear behaviour of the façade-system. Only connections involved in the gravity load path are evaluated (bearing connections). Together with standard connection, a newly proposed system (Slotted Bearing Connection) is designed to achieve a more ductile behaviour of the panel-connection system. A parametric study involving the dimensions of panel-connection components is developed to search for an optimal configuration of the bearing connection. From the appraisal of structural robustness of the panelised frame it is found that the standard connection systems may reduce the robustness of a multi-storey frame due to a poor ductile behaviour while the newly proposed connection is able to guarantee an enhanced response to the panelised multi-storey frame thanks to a higher ductility.

Evaluation of most promising options for the C1 to C2-coupling: alternative formate coupling

This thesis work contains an overview of potential alternative options to couple formate produced from CO2 with other coupling partners than formate itself. Ultimately, the intent is to produce high value chemicals from CO2 at a high selectivity and conversion, whilst keeping the required utility of electrons in the electrochemical CO2 conversion at a minimum. To select and find new coupling partners, a framework was developed upon which a broad variety of candidates were assessed and ranked. A multi-stage process was used to select first potential classes of molecules. For each class, a variety of commercially available compounds was analysed in depth for its potential suitability in the reaction with the active carbonite intermediate. This analysis has shown that a wide variety of factors come into play and especially the reactivity of the hydride catalyst poses a mayor challenge. The three major potential classes of compounds suitable for the coupling are carbon oxides (CO2 & CO), and aldehydes. As a second step the remaining options were ranked to identify which compound to test first. In this ranking the reactants sustainability, ease of commercial operation and commercial attractiveness of the compound were considered. The highest-ranking compounds that proposed the highest potential are CO2, benzaldehyde and para-formaldehyde. In proof-of-principle experiments CO2 could successfully be incorporated in the form of carbonate, oxalate and potentially formate. The overall incorporation efficiency based on the hydride consumption was shown to be 50%. It is suggested to continue this work with mechanistic studies to understand the reaction in detail as, based on further gained knowledge, the reaction can then be optimized towards optimal CO2 incorporation in the form of oxalate.