Characterization of X-ray detectors based on organic semiconducting single crystals

Negli anni recenti, lo sviluppo dell’elettronica organica ha condotto all’impiego di materiali organici alla base di numerosi dispositivi elettronici, quali i diodi ad emissione di luce, i transistor ad effetto di campo, le celle solari e i rivelatori di radiazione. Riguardo quest’ultimi, gli studi riportati in letteratura si riferiscono per la maggiore a dispositivi basati su materiali organici a film sottile, che tuttavia presentano problemi relativi ad instabilità e degradazione. Come verrà illustrato, l’impiego di singoli cristalli organici come materiali alla base di questi dispositivi permette il superamento delle principali limitazioni che caratterizzano i rivelatori basati su film sottili. In questa attività sperimentale, dispositivi basati su cristalli organici semiconduttori verranno caratterizzati in base alle principali figure di merito dei rivelatori. Tra i campioni testati, alcuni dispositivi basati su singoli cristalli di 6,13-bis (triisopropylsilylethynyl)-pentacene (TIPS-Pentacene) e 5,6,11,12-tetraphenyltetracene (Rubrene) hanno mostrato interessanti proprietà e sono stati quindi maggiormente studiati.

Novel materials for direct X-ray detectors based on semiconducting organic polymers

Conventional inorganic materials for x-ray radiation sensors suffer from several drawbacks, including their inability to cover large curved areas, me- chanical sti ffness, lack of tissue-equivalence and toxicity. Semiconducting organic polymers represent an alternative and have been employed as di- rect photoconversion material in organic diodes. In contrast to inorganic detector materials, polymers allow low-cost and large area fabrication by sol- vent based methods. In addition their processing is compliant with fexible low-temperature substrates. Flexible and large-area detectors are needed for dosimetry in medical radiotherapy and security applications. The objective of my thesis is to achieve optimized organic polymer diodes for fexible, di- rect x-ray detectors. To this end polymer diodes based on two different semi- conducting polymers, polyvinylcarbazole (PVK) and poly(9,9-dioctyluorene) (PFO) have been fabricated. The diodes show state-of-the-art rectifying be- haviour and hole transport mobilities comparable to reference materials. In order to improve the X-ray stopping power, high-Z nanoparticle Bi2O3 or WO3 where added to realize a polymer-nanoparticle composite with opti- mized properities. X-ray detector characterization resulted in sensitivties of up to 14 uC/Gy/cm2 for PVK when diodes were operated in reverse. Addition of nanoparticles could further improve the performance and a maximum sensitivy of 19 uC/Gy/cm2 was obtained for the PFO diodes. Compared to the pure PFO diode this corresponds to a five-fold increase and thus highlights the potentiality of nanoparticles for polymer detector design. In- terestingly the pure polymer diodes showed an order of magnitude increase in sensitivity when operated in forward regime. The increase was attributed to a different detection mechanism based on the modulation of the diodes conductivity.

Construction and detectors’ characterization of a new detection system for FAMU Experiment

From 2010, the Proton Radius has become one of the most interest value to determine. The first proof of not complete understanding of its internal structure was the measurement of the Lamb Shift using the muonic hydrogen, leading to a value 7σ lower. A new road so was open and the Proton Radius Puzzle epoch begun. FAMU Experiment is a project that tries to give an answer to this Puzzle implementing high precision experimental apparatus. The work of this thesis is based on the study, construction and first characterization of a new detection system. Thanks to the previous experiments and simulations, this apparatus is composed by 17 detectors positioned on a semicircular crown with the related electronic circuit. The detectors' characterization is based on the use of a LabView program controlling a digital potentiometer and on other two analog potentiometers, all three used to set the amplitude of each detector to a predefined value, around 1.2 V, set on the oscilloscope by which is possible to observe the signal. This is the requirement in order to have, in the final measurement, a single high peak given by the sum of all the signals coming from the detectors. Each signal has been acquired for almost half of an hour, but the entire circuit has been maintained active for more time to observe its capacity to work for longer periods. The principal results of this thesis are given by the spectra of 12 detectors and the corresponding values of Voltages, FWHM and Resolution. The outcomes of the acquisitions show also another expected behavior: the strong dependence of the detectors from the temperature, demonstrating that an its change causes fluctuations in the signal. In turn, these fluctuations will affect the spectrum, resulting in a shifting of the curve and a lower Resolution. On the other hand, a measurement performed in stable conditions will lead to accordance between the nominal and experimental measurements, as for the detectors 10, 11 and 12 of our system.

Detectors in black hole quantum coherent states

The corpuscular model describes black holes as leaky bound states of gravitons. To account for the role of matter, a coherent state is built and a semiclassical description is given to the gravitational field by connecting the classical source with the quantum state for gravitons. The properties of this state can be analysed with the help of an Unruh-DeWitt detector, coupled to the quantum state of the system. The presence of a detector in general regularises the usual diverging behaviour of the field in the deep ultraviolet region, and will allow us to probe the coherent state structure and the graviton emission. In particular, a Newtonian analogue of the Unruh effect will be discussed and the coherent state will be modified to properly account for the spherical symmetry of the potential at the level of the quantum state. This correction will ensure that vacuum contributions responsible for the Unruh thermal spectrum are present in a coherent state emission process.

The FAMU experiment: characterization of innovative detectors for high precision spectroscopy

The incompatibility between the proton radius values measured in recent years has given rise to what is now called the proton radius puzzle. This discrepancy is nowadays without explanation. In order to find a solution to the proton radius puzzle a new experiment has been proposed. The aim of this experiment, called FAMU, is to obtain a new and more precise measure of the Zemach radius of the proton, ie the quantity that has the highest uncertainty in high precision spectroscopy. If this measurement confirmed the results obtained before 2010, the starting date of the puzzle, then the discrepancy would be caused by procedural errors or ignored corrections. Otherwise, the new value would indicate the presence of new physics still unkown.

Monitoraggio di rilasci accidentali di sostanze pericolose in un impianto chimico

Il monitoraggio dei rilasci può essere indoor o outdoor; l’attenzione del presente lavoro è rivolta a sistemi di monitoraggio di gas infiammabili e/o tossici in ambienti esterni di stabilimenti onshore. L’efficacia dei sistemi di Gas Detection è profondamente influenzata dalla disposizione dei sensori nelle aree di rischio. Esistono codici e standard che forniscono informazioni molto dettagliate per la progettazione dei sistemi di Fire Detection e linee guida per la scelta, l’installazione ed il posizionamento ottimale dei sensori di incendio. La stessa affermazione non si può fare per i sistemi di Gas Detection, nonostante dall’individuazione tempestiva di un rilascio dipendano anche le successive azioni antincendio. I primi tentativi di sviluppare linee guida per il posizionamento dei sensori di gas sono stati effettuati per le applicazioni off-shore, dove l’elevato livello di congestione e il valore delle apparecchiature utilizzate richiedono un efficiente sistema di monitoraggio dei rilasci. Per quanto riguarda gli impianti on-shore, i criteri di posizionamento dei rilevatori di gas non sono ufficialmente ed univocamente definiti: il layout dei gas detectors viene in genere stabilito seguendo criteri di sicurezza interni alle compagnie affiancati da norme di “buona tecnica” e regole empiriche. Infatti, nonostante sia impossibile garantire l’individuazione di ogni rilascio, vi sono linee guida che propongono strategie di posizionamento dei gas detectors in grado di massimizzare la probabilità di successo del sistema di monitoraggio. Il presente lavoro è finalizzato alla verifica del corretto posizionamento dei gas detectors installati presso l’impianto pilota SF2 dello stabilimento Basell Poliolefine Italia di Ferrara.

Seasonality and diel variation in blue whale D calls recorded in the Southern California Bight

Passive acoustic data have been collected using HARPs (High-frequency Acoustic Recording Packages) and were used to assess (1) the seasonality of blue whale D calls in the Southern California Bight, (2) their interannual abundance during 2007-2012 and (3) their diel variation. This goal has been achieved running the GPL (Generalized Power-Law) automated detector. (1) Blue whale D calls were detected in the Southern California Bight from May through November with a peak in July, even though few detections were from December to April as well. A key predictor for blue whale distribution and movement in the California Current region has been identified with zooplankton aggregations, paying a particular attention to those euphausiid species, such as E. pacifica and T. spinifera, which are blue whale favorite krill. The Southern California Bight experiences seasonal upwelling, resulting in an increase of productivity and prey availability. The summer and early fall have been marked as the most favorable periods. This supports the presence of blue whales in the area at that time, supposing these marine mammals exploit the region as a feeding ground. (2) As to the interannual abundance during 2007-2012, I found a large variability. I observed a great increase of vocalizations in 2007 and 2010, whereas a decrease was shown in the other years, which is well marked in 2009. It is my belief that these fluctuations in abundance of D calls detections through the deployed period are due to the alternation of El Nino and La Nina events, which occurred in those years. (3) The assessment of the daily timing of D calls production shows that D calls are more abundant during the day than during the night with a peak at 12:00 and 13:00. Assuming that D calling is associated with feeding, the daily pattern of D calls may be linked to the prey availability. E. pacifica and T. spinifera are among those species of krill which undertake daily vertical migrations, remaining at depth during the day and slowly coming up towards the surface at night. Because of some anatomical arrangements, these euphausiids are very sensitive to the light. Given that we believe D calls have a social function, I hypothesize that blue whales may recognize the hours at the highest solar incidence as the best moment of the day in terms of prey availability, exploiting this time window to advert their conspecifics.