Environmental assessment of industrial chemical and primary sector processes from a life cycle perspective

During the PhD program in chemistry at the University of Bologna, the environmental sustainability of some industrial processes was studied through the application of the LCA methodology. The efforts were focused on the study of processes under development, in order to assess their environmental impacts to guide their transfer on an industrial scale. Processes that could meet the principles of Green Chemistry have been selected and their environmental benefits have been evaluated through a holistic approach. The use of renewable sources was assessed through the study of terephthalic acid production from biomass (which showed that only the use of waste can provide an environmental benefit) and a new process for biogas upgrading (whose potential is to act as a carbon capture technology). Furthermore, the basis for the development of a new methodology for the prediction of the environmental impact of ionic liquids has been laid. It has already shown good qualities in identifying impact trends, but further research on it is needed to obtain a more reliable and usable model. In the context of sustainable development that will not only be sector-specific, the environmental performance of some processes linked to the primary production sector has also been evaluated. The impacts of some organic farming practices in the wine production were analysed, the use of the Cereal Unit parameter was proposed as a functional unit for the comparison of different crop rotations, and the carbon footprint of school canteen meals was calculated. The results of the analyses confirm that sustainability in the industrial production sector should be assessed from a life cycle perspective, in order to consider all the flows involved during the different phases. In particular, it is necessary that environmental assessments adopt a cradle-to-gate approach, to avoid shifting the environmental burden from one phase to another.

Assessment of sea-level variability for the Emilia-Romagna coastal area in the framework of the Mediterranean Sea

Sea–level change is one of the ocean characteristics closely connected to climate change. Understanding its variation is essential since a large portion of the world’s population is located in low–lying locations. Two main techniques are employed to measure sea level: satellite altimetry and tide gauges. Satellite altimetry monitors sea–level relative to a geocentric reference, is unaffected by crustal processes and covers nearly the entire surface of the oceans since 1993. Conversely, tide gauges measure sea level at specific coastal locations and relative to a local ground benchmark, therefore are impacted by vertical land movements. In this study, the linear and non–linear geocentric and relative sea–level trends along the Emilia–Romagna coast (Northern Italy) have been analyzed over different periods. In order to assess the local sea–level variability, data from satellite altimetry and tide gauges have been compared over a common time interval (1993–2019), hence disentangling the contribute of vertical land movements. Non–linearity has been also evaluated at the broader scale of the Mediterranean Sea, in order to depict the main variability in geocentric sea–level trends from regional to sub–basin scale. Furthermore, the anthropogenic and natural influence at the river basin scale has been addressed, in order to shed light on the factors inducing the drastic reduction of riverine sediment supply to the Emilia–Romagna coast over the period 1920–2020. The findings of this analysis indicate that the sediment delivery reduction to the coast by rivers has been driven by several anthropogenic processes, acting on various spatiotemporal scales. Moreover, the local absolute sea–level trend is far from linear and appear "contaminated" by the presence of natural oscillations that act at the multi–decadal, quasi–decadal and inter–annual scale, mainly driven by both large–scale climatic modes and variations in local oceanography.

Towards a sustainable approach for Cultural Heritage Conservation: developing micro-structured green materials and analytical protocols for their performance assessment

Cleaning is one of the most important and delicate procedures that are part of the restoration process. When developing new systems, it is fundamental to consider its selectivity towards the layer to-be-removed, non-invasiveness towards the one to-be-preserved, its sustainability and non-toxicity. Besides assessing its efficacy, it is important to understand its mechanism by analytical protocols that strike a balance between cost, practicality, and reliable interpretation of results. In this thesis, the development of cleaning systems based on the coupling of electrospun fabrics (ES) and greener organic solvents is proposed. Electrospinning is a versatile technique that allows the production of micro/nanostructured non-woven mats, which have already been used as absorbents in various scientific fields, but to date, not in the restoration field. The systems produced proved to be effective for the removal of dammar varnish from paintings, where the ES not only act as solvent-binding agents but also as adsorbents towards the partially solubilised varnish due to capillary rise, thus enabling a one-step procedure. They have also been successfully applied for the removal of spray varnish from marble substrates and wall paintings. Due to the materials' complexity, the procedure had to be adapted case-by-case and mechanical action was still necessary. According to the spinning solution, three types of ES mats have been produced: polyamide 6,6, pullulan and pullulan with melanin nanoparticles. The latter, under irradiation, allows for a localised temperature increase accelerating and facilitating the removal of less soluble layers (e.g. reticulated alkyd-based paints). All the systems produced, and the mock-ups used were extensively characterised using multi-analytical protocols. Finally, a monitoring protocol and image treatment based on photoluminescence macro-imaging is proposed. This set-up allowed the study of the removal mechanism of dammar varnish and semi-quantify its residues. These initial results form the basis for optimising the acquisition set-up and data processing.