Models of the Distribution of Persistent Organic Pollutants in the Marine Environment

Persistent organic pollutants (POPs) is a group of chemicals that are toxic, undergo long-range transport and accumulate in biota. Due to their persistency the distribution and recirculation in the environment often continues for a long period of time. Thereby they appear virtually everywhere within the biosphere, and poses a toxic stress to living organisms. In this thesis, attempts are made to contribute to the understanding of factors that influence the distribution of POPs with focus on processes in the marine environment. The bioavailability and the spatial distribution are central topics for the environmental risk management of POPs. In order to study these topics, various field studies were undertaken. To determine the bioavailable fraction of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), polychlorinated naphthalenes (PCNs), and polychlorinated biphenyls (PCBs) the aqueous dissolved phase were sampled and analysed. In the same samples, we also measured how much of these POPs were associated with suspended particles. Different models, which predicted the phase distribution of these POPs, were then evaluated. It was found that important water characteristics, which influenced the solid-water phase distribution of POPs, were particulate organic matter (POM), particulate soot (PSC), and dissolved organic matter (DOM). The bioavailable dissolved POP-phase in the water was lower when these sorbing phases were present. Furthermore, sediments were sampled and the spatial distribution of the POPs was examined. The results showed that the concentration of PCDD/Fs, and PCNs were better described using PSC- than using POM-content of the sediment. In parallel with these field studies, we synthesized knowledge of the processes affecting the distribution of POPs in a multimedia mass balance model. This model predicted concentrations of PCDD/Fs throughout our study area, the Grenlandsfjords in Norway, within factors of ten. This makes the model capable to validate the effect of suitable remedial actions in order to decrease the exposure of these POPs to biota in the Grenlandsfjords which was the aim of the project. Also, to evaluate the influence of eutrophication on the marine occurrence PCB data from the US Musselwatch and Benthic Surveillance Programs are examined in this thesis. The dry weight based concentrations of PCB in bivalves were found to correlate positively to the organic matter content of nearby sediments, and organic matter based concentrations of PCB in sediments were negatively correlated to the organic matter content of the sediment.

Phonological features of Yazghulami : A field study

Yazghulami is a South-East Iranian language spoken in the Pamir area of Tajikistan by about 9000 people. This study gives an account of the phonology of the language by describing contrastive segments and their distribution and realizations, as well as describing suprasegmental features such as syllable structure and stress patterns. Field research was carried out in a community of Yazghulami speakers in Dushanbe, the capital of Tajikistan, by recording, transcribing and annotating spoken language. Yazghulami is analyzed as having 8 vowel phonemes of which one pair contrasts in length, and 36 consonant phonemes with a considerable display of palatal, velar and uvular phonemes, of which a set of three labialized plosives and three labialized fricatives is found. The syllable structure of Yazghulami allows for clusters of no more than two consonants in the onset and two in the coda; clusters in both positions do not occur in one and the same syllable. The stress generally falls on the last syllable of a word, although when nouns are inflected with suffixes, the stress instead falls on the last syllable of the stem. With these results, a foundation for further efforts to develop and increase the status of this endangered language is laid.