Supercritical extraction of pupunha (Guilielma speciosa) oil in a fixed bed using carbon dioxide

The pupunha (Guilielma speciosa) is the fruit of a palm tree typical of the Brazilian Northern region, whose stem is used as a source of heart of palm. The fruit, which is about 65% pulp, is a source of oil and carotenes. In the present work, an analysis of the kinetics of supercritical extraction of oil from the pupunha pulp is presented. Carbon dioxide was used as solvent. The extractions were carried out at 25 MPa and 323 K and 30 MPa and 318 K. The chemical composition of the extracts in terms of fatty acids was determined by gas chromatography. The amount of oleic acid, a saturated fatty acid, in the CO2 extracts was larger than that in the extract obtained with hexane. The overall extraction curves were modeled using the single-parameter model proposed in the literature to describe the desorption of toluene from activated coal.

Characterization and distribution of pyrogenic carbon in a fraction of archaeological black earth from Caxiuanã

This study aims to determine the atomic ratio of O/C in an archaeological black earth (ABE) profile of the Ilha de Terra site, a region of Caxiuanã in the Pará State, Brazil, to determine the types of pyrogenic carbon (PyC) particles and to infer the source of biomass and burning temperature necessary to produce the PyC. The O/C ratios were monitored using scanning electron microscopy combined with energy dispersive spectroscopy (SEM/EDS). The results indicated atomic ratios for clay, silt and fine sand fractions that were between those registered for the PyC particles types: condensed combustion (CC) (0.09, 0.1, 0.13), charcoal (0.32, 0.31, 0.34) and char (0.43, 0.45, 0.52). CC is the predominant type of particle found because of the high firing temperature (> 350 °C), which is consistent with the probable biomass sources of wood, cellulose and lignin.