Hydrochemical evaluation of bottled mineral waters and spring at Corumbataí city, São Paulo State, Brazil

This investigation was carried out within São Paulo State, Brazil, and involved the sampling of well-known mineral bottled waters for performing a comparative hydrochemical study and of a spring occurring at Corumbataí city, in order to evaluate its suitability for bottling. Several methods were utilized for acquiring the hydrochemical data like the methyl orange end-point titration, potentiometry, ion selective electrode, colorimetry, flame photometry and inductively-coupled plasma spectrometry. The results obtained for the analyzed samples were compared with the guideline values established by the National Commission of Rules and Standards for Food of the Brazilian Health Ministry published in 1976. The Brazilian Code for Mineral Waters that was established by Register 7841 published on 8 August 1945 was also taken into account for verifying if the spring waters are mineralized. The hydrochemical data allowed identify some constituents impoverishing the water quality, thus, implying on its nonutilization for commercial purposes (bottling). In one specific case, the spring water only can become appropriate for human consumption after previous chemical treatment. © 201 WIT Press.

Characterization of high density polyethylene (HDPE) reinforced with banana peel fibers

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

2,4-Dichlorophenoxyacetic acid (2,4-D) degradation promoted by nanoparticulate zerovalent iron (nZVI) in aerobic suspensions

Reactive species generated by Fe0 oxidation promoted by O2 (catalyzed or not by ligands) are able to degrade contaminant compounds like the herbicide 2,4-dichlorophenoxyacetic acid. The degradation of 2,4-D was influenced by the concentrations of zero valent iron (ZVI) and different ligands, as well as by pH. In the absence of ligands, the highest 2,4-D degradation rate was obtained at pH 3, while the highest percentage degradation (50%) was achieved at pH 5 after 120 min of reaction. Among the ligands studied (DTPA, EDTA, glycine, oxalate, and citrate), only ethylenediaminetetraacetic acid (EDTA) and diethylenetriaminepentaacetic acid (DTPA) significantly enhanced oxidation of 2,4-D. This increase in oxidation was observed at all pH values tested (including neutral to alkaline conditions), indicating the feasibility of the technique for treatment of contaminated water. In the presence of EDTA, the oxidation rate was greater at pH 3 than at pH 5 or 7. Increasing the EDTA concentration increased the rate and percentage of 2,4-D degradation, however increasing the Fe0 concentration resulted in the opposite behavior. It was found that degradation of EDTA and 2,4-D occurred simultaneously, and that the new methodology avoided any 2,4-D removal by adsorption/coprecipitation. © 2013 Elsevier Ltd.

Coagulation-flocculation of anaerobically treated sugarcane stillage

Anaerobic digestion applied to stillage usually results in treatment performances. However, effluents from anaerobic reactors still present a residual polluting load due to the presence of organic recalcitrant compounds. Additional treatment methods, such as coagulation-flocculation, may be utilized to improve the final effluent quality. In this study, we assessed the processes of coagulation and flocculation for sugarcane stillage samples previously submitted to anaerobic digestion, aiming to obtain optimal conditions for the physicochemical treatment. Natural corn starch and ferric chloride were tested as coagulants. While starch was considered as not suitable for the treatment for the tested conditions, ferric chloride assays presented satisfactory results. The investigated parameters included coagulant solution dose, rapid mixing gradient and time, flocculation gradient and time, and sedimentation time. Their adjusted values at which better performances obtained were, respectively, 1.6 g L-1, 325 rpm, 10 s, 65 rpm, 20 and 20 min. The best color, turbidity, and chemical oxygen demand removal efficiencies were 95, 97, and 65%, respectively. Stillage pH variation to alkaline conditions did not result in improved removal efficiencies. Although relatively high removal efficiencies of constituents were obtained, the final effluent characteristics did not fit regulations of water reuse in the agriculture through fertigation. However, stillage can definitely become more easily managed if better final effluent quality control parameters are achieved, enabling for example effluents discharge in water bodies. © 2013 Copyright Balaban Desalination Publications.

Biosorption of cadmium (II) and lead (II) from aqueous solution using exopolysaccharide and biomass produced by Colletotrichum sp.

The biosorption of Cd(II) and Pb(II) ions on biomass and exopolysaccharide (EPS) produced by Colletotrichum sp. fungus has been investigated as a function of contact time, initial pH, initial metal ion concentration, and initial adsorbent concentration in a batch system. Adsorption equilibrium was described by Freundlich and Langmuir isotherms. Adsorption was characterized through granulometry, SEM and EDX analysis. Then, studies were performed to regenerate the adsorbent. Biosorption of metals by biomass and EPS were best described by the Langmuir and Freundlich isotherm, respectively. Results of thermodynamic investigations showed that adsorption reactions were spontaneous (ΔG° < 0), exothermal, and mainly physical. The EPS was able to remove 79 and 98% of cadmium and lead, respectively, and the biomass removed 85 and 84% of cadmium and lead, respectively, in a solution with initial concentration 100 mg L-1, and the four adsorption-desorption cycles of all adsorbents showed up with great regenerative capacity and relative stability after these four cycles, the high potential of these biological materials in sorption has been shown. © 2013 Copyright Balaban Desalination Publications.

The effect of dimethyl sulfoxide (DMSO) on dentin bonding and nanoleakage of etch-and-rinse adhesives

Objective The objective was to examine the effect of a solvent dimethyl sulfoxide (DMSO) on resin-dentin bond durability, as well as potential functional mechanisms behind the effect. Methods Microtensile bond strength (μTBS) was evaluated in extracted human teeth in two separate experiments. Dentin specimens were acid-etched and assigned to pre-treatment with 0.5 mM (0.004%) DMSO as additional primer for 30 s and to controls with water pre-treatment. Two-step etch-and-rinse adhesive (Scotchbond 1XT, 3M ESPE) was applied and resin composite build-ups were created. Specimens were immediately tested for μTBS or stored in artificial saliva for 6 and 12 months prior to testing. Additional immediate and 6-month specimens were examined for interfacial nanoleakage analysis under SEM. Matrix metalloproteinase (MMP) inhibition by DMSO was examined with gelatin zymography. Demineralized dentin disks were incubated in 100% DMSO to observe the optical clearing effect. Results The use of 0.5 mM DMSO had no effect on immediate bond strength or nanoleakage. In controls, μTBS decreased significantly after storage, but increased significantly in DMSO-treated group. The control group had significantly lower μTBS than DMSO-group after 6 and 12 months. DMSO also eliminated the increase in nanoleakage seen in controls. 5% and higher DMSO concentrations significantly inhibited the gelatinases. DMSO induced optical clearing effect demonstrating collagen dissociation. Significance DMSO as a solvent may be useful in improving the preservation of long-term dentin-adhesive bond strength. The effect may relate to dentinal enzyme inhibition or improved wetting of collagen by adhesives. The collagen dissociation required much higher DMSO concentrations than the 0.5 mM DMSO used for bonding. © 2013 Academy of Dental Materials.

Adubação mineral, esterco de curral e lodo de esgoto no desenvolvimento inicial do cafeeiro

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Epidemiologia de doenças infecciosas: cólera e doença do caranguejo letárgico

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Avaliação clínica e microbiológica da irrigação subgengival com iodo-povidine 10% como adjunto à terapia periodontal não-cirúrgica

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Sistema com aeração, decantação e filtragem para melhoria da qualidade da água para irrigação localizada

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Isolamento e identificação de micobacterias e microrganismos indicadores de contaminação em águas tratadas provenientes do sistema de abstecimento público de Araraquara-SP

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Ensaios de tratamento de efluentes de indústria de chapa dura de fibra de madeira

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Desinfecção da água utilizando aquecimento solar

Pós-graduação em Agronomia (Energia na Agricultura) - FCA

Síntese de supercondutores cerâmicos à base de bismuto produzidos pelo método Pechini associado ao processo de hidrotermalização assistido por micro-ondas

Pós-graduação em Ciência dos Materiais - FEIS

Atividade antioxidante, compostos fenólicos totais e cor em abacate ‘hass’ submetido a diferentes tratamentos físicos

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)