The late precambrian K-alkaline magmatism in the Ribeira Fold Belt: a case study of the Piracaia Pluton, State of São Paulo, SE Brazil, and its potential mineralization (Cu, Zn, Gd)

The Pluriserial Ribeira Magmatic System-590 of the Late Precambrian Ribeira Fold Belt comprises seven groups of high-K rocks of crustal or mantle origin with ages ranging between 620 and 570 Ma. One of these groups is represented by transalkaline suites akin to appinitic lamprophyres. The suites assemble one or more of following lithologies: (+/- quartz) gabbros and monzogabbros, (+/- quartz) diorites and monzodiorites, (+/- quartz) monzonites and syenites in addition to rare granites. All these rocks occur together in the Piracaia pluton, State of São Paulo. The mineralogy of the Piracaia suite comprises variable amounts of plagioclase (An 60-10), alkali-feldspars (orthoclase, microcline, albite), ortho- (Fe-hypersthene) and clinopyroxenes (augite), amphiboles (hornblende and rare late Fe-hastingsite), abundant biotite, quartz, opaques, sphene, allanite and zircon. Several magmatic pulses constructed the pluton. The Piracaia magma bulk trend evolved initially along the silica-undersaturation plane with simultaneous fractionation of accessory, mafic and felsic minerals. These are segregated in feldspar-rich cumulates. In the late stage, the evolutionary trend followed two distinct paths: one along the or-ab thermal barrier with the crystallization of syenites; the second one along the thermal valley in the or-ab-qz subsystem, producing quartz-syenites and granites. The source of the Piracaia magma was a 'vein-plus-wall-rock-system '. Together the pulses reflect increasing and decreasing participation of peridotites and mica pyroxenites, respectively, in the magmatogenic process. The magmatic pulses were stored in magma chambers, several drained by deep faults or fractures, which were successively reactivated and recharged. Each new pulse underwent mixing with earlier residual magma, followed by fractionation. During ascent through the hot and thickened post-collisional crust, the magma pulses underwent minor compositional changes by crustal contamination. The concentration of valuable elements (Cu, Zn, Gd) in the Piracaia pluton occurred during two phases of the magmatic evolution. Cu and Zn were enriched in cumulates and Gd was concentrated in residual quartz-syenitic veins. Due to their homogeneous dark colour and texture, the monzodiorites are exploited both for polished dimension stones and supports for sensitive scientific instruments. (C) 2001 Elsevier B.V. Ltd. All rights reserved.

High-pressure granulites from Carire, Borborema Province, NE Brazil: Tectonic setting, metamorphic conditions and U-Pb, Lu-Hf and Sm-Nd geochronology

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Metamorphic evolution of a subduction complex, South Shetland Islands, Antarctica

A subduction complex composed of ocean floor material mixed with arc-derived metasediments crops out in the Elephant Island group and at Smith Island, South Shetland Islands, Antarctica, with metamorphic ages of 120-80 Ma and 58-47 Ma? respectively. Seven metamorphic zones (I-VII) mapped on Elephant Island delineate a gradual increase in metamorphic grade from the pumpellyite-actinolite facies, through the crossite-epidote blueschist facies, to the lower amphibolite facies. Geothermometry in garnet-amphibole and garnet-biotite pairs yields temperatures of about 350 degrees C in zone III to about 525 degrees C in zone VII. Pressures were estimated on the basis of Si content in white mica, Al2O3 content in alkali amphibole, Na-M4/Al-IV in sodic-calcic and calcic amphibole, Al-VI/Si in calcic amphibole, and jadeite content in clinopyroxene. Mean values vary from about 6-7.5 kbar in zone II to about 5 kbar in zone VII. Results from the other islands of the Elephant Island group are comparable to those from the main island; Smith Island yielded slightly higher pressures, up to 8 kbar, with temperatures estimated between 300 and 350 degrees C. Zoned minerals and other textural indications locally enable inference of P-T-t trajectories, all with a clockwise evolution. A reconstruction in space and time of these P-T-t paths allows an estimate of the thermal structure in the upper crust during the two ductile deformation phases (D-1 & D-2) that affected the area. This thermal structure is in good agreement with the one expected for a subduction zone. The arrival and collision of thickened oceanic crust may have caused the accretion and preservation of the subduction complex. In this model, D-1 represents the subduction movements expressed by the first vector of the clockwise P-T-t path, D-2 reflects the collision corresponding to the second vector with increasing temperature and decreasing pressure, and D-3 corresponds to isostatic uplift accompanied by erosion, under circumstances of decreasing temperature and pressure.

Consolidation and break-up of the South American platform in southeastern Brazil: Tectonothermal and denudation histories

The different tectonic stages that occurred at the end of the Proterozoic and during the Phanerozoic have an important bearing on the tectonothermal history of the South American Platform and its consolidation. Geochronological data (U/Pb monazite, Ar-40/Ar-39 whole rock) and apatite fission-track analysis, from Precambrian rocks of the southeastern Brazilian coastline, permit the modeling of a long-term thermal history of the crust and constrain variable denudation rates.Using these data, a temperature-time diagram reflects a period of accelerated exhumation during the end of the Brasiliano Orogeny, followed by long stability and reactivation of the platform during the Rifting Phase of the South Atlantic Ocean.U/Pb zircon and monazite (blocking temperature of ca. 650degreesC) data from a series of igneous bodies suggest that a tangential and transpressional tectonic regime occurred between 625 and 610 Ma. During the following escape tectonics, between 610 and 590 Ma the exhumation process indicates cooling rates of ca. 12degreesC/Ma. Ar-40/Ar-39 biotite ages between 540 and 510 Ma (ca. 300degreesC) and a corrected fission-track age on apatites (100degreesC) of 480 Ma indicate an exhumation event related to block tectonics with huge vertical displacement along shear zones.A long stabilization phase, with low exhumation, and cooling rate around 0.25degreesC/Ma was recorded from the Cambro/Ordovician to the Mesozoic. At 65 Ma an acceleration of the exhumation through denudation and reworking of the South American surface with cooling rate of 1.5degreesC/Ma is observed.The uplift of the Mantiqueira and Serra do Mar mountain ranges along the southeast Brazilian coastline works as a climatic barrier provoking lateral erosional processes causing long-term scarp retreat, combined with intense, but progressive denudation towards the continent. A denudation of 2.5 to 4 km was calculated for such processes. This lateral retreat of escarpments and flexural response can provide important insights regarding marginal isostatic uplift and the evolution of offshore sedimentary basins of southeast Brazil.

Isotopic evidence for the late Brasiliano (500-550 Ma) ore-forming mineralization of the Araes gold deposit, Brazil

The Araes gold deposit, located in eastern Mato Grosso State, central Brazil, is hosted in Neoproterozoic volcanosedimentary rocks of the Paraguay belt, which formed during collision of the Amazonian craton and the Rio Apa block. Ar-40/Ar-39 geochronology and Pb and S isotopic analyses constrain the timing and sources of mineralization. Three biotite flakes from two samples of metavolcanic host rock yield Ar-40/Ar-39 plateau ages between 5941 and 531 Ma, interpreted as cooling ages following regional metamorphism. Clay minerals from a hydrothermal alteration zone yield an Ar-40/Ar-39 integrated age of 503 +/- 3 Ma. Galena grains from ore-bearing veins yield values of Pb-206/(204)pb from 17.952 to 18.383, Pb-207/Pb-204 from 15.156 to 15.811, and Pb-208/Pb-204 from 38.072 to 39.681. Pyrite grains from ore-bearing veins yield values of Pb-206/Pb-204 from 18.037 to 18.202, Pb-207/Pb-204 from 15.744 to 15.901., and Pb-208/(204)pb from 38.338 to 38.800. Pb isotope variations may be explained in terms of mixing a less radiogenic lead component (mu similar to 8.4) from mafic and ultramafic basement host-rocks (Nova Xavantina metavolcanosedimentary rocks) and a more radiogenic lead component (mu similar to 9.2) probably derived from supracrustal rocks (Cuiaba sedimentary groups). Sulfur isotope compositions are homogeneous, with delta S-34 values ranging from -1.1 parts per thousand to 0.9 parts per thousand (galena) and -0.7 parts per thousand to 0.9 parts per thousand (pyrite), suggesting a mantle-derived reservoir for the mineralizing solutions. Based on the Ar, Pb, and S isotope data, we suggest that the precious metals were remobilized from metavolcanic host rocks by hydrothermal solutions during Brasilide-Panafrican regional metamorphism. The Arabs gold deposit probably formed during a late stage of the orogeny, coeval with other mineralization events in the Paraguay Belt.

The Araguaia fold belt, Brazil: A reactivated Brasiliano-Pan-African cycle (550 Ma) geosuture

The Araguaia-Tocantins geosuture, which separates the Araguaia Fold Belt (AFB) from the Archean Amazonian Craton, was active in the late Middle Proterozoic. The Baixo Araguaia Supergroup was deposited, consisting of the Estrondo Group (lower quartzites with intercalated schists), Xambioá Formation (schists), and Canto da Vazante Formation (upper feldspathic schists); and the Tocantins Group consisting of the Couto Magalhaës Formation (phyllites, quartzites, slates, limestones, and metacherts) and Pequizeiro Formation (upper chlorite schists); and associated mafic-ultramafic bodies. The deformational history includes four regional phases of deformation within this supracrustal sequence: recumbent folds with vergence to the west; refolding with a N-S trend; an intense crenulation episode; and late thrusting from east to west. Metamorphism is of intermediate or intermediate-high pressure type with garnet, biotite, chlorite, and sericite isograds succeeded by a slightly or non-metamorphosed zone, from east to west. Rocks surrounding sparse gneissic-cored domes contain isograds of staurolite, kyanite, and fibrolite. These isograds are believed to be associated with the 1100 Ma Uruaçuano event. The Brasiliano Orogeny strongly affected the AFB with displacements due to transcurrent reactivation of great and old faults of the basement, slight folding in the supracrustal sequence, intrusion of small granite bodies, and development of domes with associated normal faults. The area underlain by the Estrondo Group was uplifted at this time, causing the deposition of the Rio das Barreiras polymictic conglomerate of the central area. K-Ar and Rb-Sr analyses date this thermo-tectonic event at 550 ± 100 Ma. The Archean basement is exposed in the cores of domes as a granite-gneiss association, the Colméia complex, which shows thermo-tectonic features that may be interpreted as polycyclic imprints (Jequié, Transamazonian?, Uruaçuano, and Brasiliano Events). © 1989.

Aspectos microestruturais e texturais dos metassedimentos da formacao eleuterio

This work describes the primary and tectonic-metamorphic structures of the Eleuterio Formation, cropping 1 km NW of the village of Eleuterio, State of Sao Paulo. The structural feature have been studied chiefly in low grade metamorphic siltites, arkoses and conglomerates. The textural evolution is marked by fragmentation, clay minerals reaction, pression solution with silica recrystallization, mechanical rotation in minerals, fluid circulation and dissolution, mica beards, the possibily crystallization of biotite and epidote, and so on. The tectonic metamorphic foliation now described is supposed to be formed by simple shear with a possible pure shear component. -English summary

Chemistry of Biotites and Whole Rocks from the Rapakivi Itu Complex (Late Precambrian), State of São Paulo, SE Brazil

Chemical analyses for biotites and their host rocks from the Cabreúva (three facies) and Salto (five facies) intrusions from the multiple-centered rapakivi Itu Complex, State of São Paulo, Brazil, are presented and compared. The Cabreúva intrusion comprises different kinds of mainly even-grained biotite and hornblende-bearing syenogranites, monzogranites and quartz syenites and the Salto intrusion several types of mainly porphyritic biotite syenogranites, some of them hornblende-bearing. The biotites from the Salto intrusion (S-micas) show a more restricted composition than those from the Cabreúva intrusion (C-micas). This reflects the chemical variability of the two bodies which is smaller in the Salto intrusion and larger in the Cabreúva pluton. In the AlIV x Fet/(Fet+Mg) diagram the S- and C-micas show similar AlIV contents, around 2.2-2.3, but C-micas have higher Fet/(Fet+Mg) ratios (0.7-0.9) compared to those of S-micas (0.5-0.6). In the Mg:(Al+Fe+3+Ti):(Fe+2+Mn) diagram the S-micas are defined as Fe+2-biotites and the C-micas occupy the area between the Fe+2-biotites and the siderophyllite/lepidomelane fields, slightly overlapping the latter. In the Al2O3 × FeOt, MgO × FeOt, Al2O3 x MgO and Alt x Mg diagrams, the S-micas always lie on the calc-alkaline/alkaline boundary (or in the subalkaline field) whereas the C-micas systematically plot in the alkaline field, reflecting the higher alkalis content of the Cabreúva intrusion. In the Fet/(Fet+Mg) x SiO2 diagram, the S-micas lie on a smooth line whereas the C-micas from the different facies are separated by distinct chemical gaps reflecting the major or minor chemical overlapping of the facies from the Salto and Cabreúva intrusions.

Geochemical Variability of the Rapakivi Itu Province, State of São Paulo, SE Brazil

This paper describes the chemical variability of the Late Precambrian Itu Rapakivi Province (IRP), State of São Paulo, SE Brazil, based on 187 selected analyses from the Itu, São Francisco, Sorocaba, Campina do Veado and Sguario/ Correa granites. The IRP has an almost uniform petrographic character conferred by the overall dominance of subalkaline biotite granites. Monzogranites (adamellites), granodiorites, quartz syenites, quartz monzonites are rare to very rare rock types and tonalites and quartz diorites are almost restricted to enclaves. Typical chemical features are the high FeO*/MgO ratio, a clustering of the K2O values between 4.5 and 6.0 wt.% and K2O/Na2O ratios which define the IRP as mildly potassic although more potassic rocks also occur. The overal Peacock Alkalinity Index is 54 defining the Province as alkali-calcic. In the Shand diagram the data cluster near the metaluminous/peraluminous boundary. Relationships between Nb, Rb and Y stress the within plate character of the IRP and the relationships between Rb, Ba and Sr reveal the importance of feldspar fractionation in magma evolution. The data also show an interbody and an intrabody chemical variability due to the variation in the composition of the crustal magma protoliths, as assigned by K/Rb relations. The presence of several magmatic cycles which built up the major intrusions reflects a magma ascent from collecting chambers successively drained and recharged, a feature in agreement with the clear link between the bodies and long lived, successively reactivated, transcurrent faults. Most of the chemical features of the IRP correspond to those of the classical Finnish rapakivi granites.

Final stages of the Brasiliano Orogenesis in SE Brazil: U-Pb and 40Ar/39Ar evidence for overprinting of the Brasília Belt by the Ribeira Belt Tectonics

Around the southern margins of the São Francisco Craton, there is a zone of tectonic interference between the Brasília belt to the west and the younger Ribeira belt to the east. U-Pb monazite and 40Ar/39Ar cooling age determinations carried out in the area reveal the cooling histories of these belts and the timing of tectonic overprint, unraveling the final stages of Brasiliano Orogeny in SE Brazil. The U-Pb monazite data from migmatized paragneisses and late-stage pegmatites in the Socorro-Guaxupé Nappe System of the southern Brasília belt show that migmatization peaked between ca. 613±1 and 607±3 Ma. 40Ar/39Ar biotite and muscovite ages of paragneisses and schists in this area indicate that the northern high-grade core of the Nappe System (Guaxupé Domain) was uplifted and cooled through the 350°C isotherm between 599±1 and 587±1 Ma. In contrast, samples from the southern high-grade core of the Nappe System, the Socorro Domain, south of the Jacutinga shear zone, yields a broader and younger spectrum of 40Ar/39Ar biotite ages between 571±1 and 562±1 Ma, attributed to a later uplift and cooling of the crust. The cooling ages can be assigned to local resetting of the 40Ar/39Ar system during transpressive tectonic overprint due to reactivation as a result of collision of the Ribeira belt. A younger group of 40Ar/39Ar mica ages (537±1 to 521±1Ma) in schists of the Socorro Domain, are associated with transpressional structures of the Ribeira belt. Rock samples from the Jacutinga and Três Corações shear zones, yield 40Ar/39Ar biotite-muscovite ages around 520 Ma. These are typical cooling ages of the Ribeira belt, and are interpreted to mark the western limit of the Ribeira belt transpressional regime within the Brasília belt. The youngest biotite-muscovite cooling ages in schists of the Socorro Domain, between 510±2 and 491±1 Ma, mark the final cooling and exhumation of that part of the Brasília belt.

Química mineral e estimativas de pressão e temperatura em rochas metassedimentares do grupo araxá na região de morrinhos, sul do estado de goiás

In the Morrinhos region, Goiás state, Brazil, the rocks of the Araxá Group have mineral assemblages related to the metamorphic peak which occurred in this region and is typical of the amphibolite facies (kyanite zone). These rocks are associated with the initial stage of the main ductile deformation that occurred in this area. Thermobarometric calculations, including the associations, garnet + plagioclase + biotite + muscovite; garnet + plagioclase +biotite + muscovite + kyanite; garnet + plagioclase + biotite + muscovite + amphibole, with quartz in excess, indicate that the metamorphic peak occurred at temperatures of approximately 610°C and pressures in the order of 10 kbar. The P-T path is probably clockwise and is in agreement with the tectonic conditions observed in collisional settings.

O Grupo Canastra em sua área-tipo, região de Tapira, sudoeste do estado de Minas Gerais

This work aimed at describing the Neoproterozoic evolution of a Southern Brasília Fold Belt segment, in Tapira area (southwest of Minas Gerais state, Brazil), using detailed geologic mapping. This area, the Canastra Group type-area, has showed great tectonic and stratigraphic complexities unlike the simplicity suggested in previous works. From recognizing the main tectonic discontinuities, it was possible to subdivide the area into some domains. In the west domain, they were individualized in tectonic sheet I, marked by pelitic rocks and pelitic-graphite rocks with psammitic intercalations, and II, pelitic rocks with psammitic and mafic-ultramafic intercalations overlapped by gneisses. In the east domain, a group of three tectonic sheets was defined, in which, in the two lower tectonic sheets, pelitic and pelitic-graphite rocks with psammitic rock intercalations prevailed, which is different in metamorphic conditions. The lower tectonic sheet is marked by mineralogical associations with muscovite + chlorite + quartz ± graphite ± albite, without biotite; however, the superior one is with muscovite + quartz + garnet ± chlorite ± biotite ± chloritoid ± graphite ± albite. In the upper tectonic sheet, pelitic rocks with local contributions of psammitic and ultramafics rocks occur. In the south domain, psammitic rocks basically occur with contributions of pelitics and rudaceous rocks, where the preservation of textures and sedimentary structures is common. Rocks of the several domains are interpreted as part of a passive continental margin basin, located in the western margin of the São Francisco paleocontinent. Thus, the south domain rocks would represent the facies of proximal platform; rocks of the lower and middle tectonic sheets (east domain) and of the tectonic sheet I (west domain) are of facies distal platform; and the ones from the upper tectonic sheet (east domain) and tectonic sheet II (west domain) were acknowledged as deposited in an environment of continental shelf and/or oceanic seafoor.

Geotermobarometria de Granulitos Associados à Supracrustais na Porção Norte do Complexo Guaxupé - Região de Arceburgo - Santa Cruz do Prata, MG

This paper is a contribution for the understanding of the geological evolution of Guaxupé Complex. New data on petrography and mineral chemistry as well as estimates of metamorphic (P-T) conditions in the region of Arceburgo - Santa Cruz do Prata (MG) Brazil, at the southern portion of the Brasília Belt, more specifically at the Guaxupé Complex (Domain) are now presented. The lithotypes are high-grade metamorphic rocks subdivided into two groups: metasediments and granulites (orthoderivates). Chemical analysis of minerals was performed in three steps including core and rim of amphibole, pyroxene, feldspar, biotite, and garnet from samples of the following rock types: enderbites, mafic granulites, charnockites, and alkali feldspar charnockites. Results obtained with geothermobarometric calculations show metamorphic peak around 900°C of T and 10 kbar of P. Enderbites and tonalite granulites (mafic) show the highest values of temperature and pressure, while alkali feldspar charnockites show the lowest probably due to their late generation in relation to mafic rock types (enderbites and mafic tonalite granulite). Chemical mineral analysis in metamorphic parageneses and geothermobarometric calculations indicate that the possible metamorphic peak may be higher than 900°C of temperature and around 10 kbar of pressure, within a isothermal decompression (ITD) regime.

Caracterização Tecnológica das Rochas Ornamentais do Maciço Capão Bonito, SP

The Capão Bonito Granitic Massif is situated in the south portion of the São Paulo State and represents an elongate body with general direction NE-SW, intrusive in epimetamorphic rocks of Açungui Group (Votuverava Formation), and in granitic rocks of the Três Córregos Complex. It is partially covered by sedimentary rocks of the Paraná Basin (Itararé Group). As the chief type we have red sienogranite, holo to leucocratic with biotite and rare hornblende, inequigranular with medium to coarse grains to porphiritic and isotropic to slightly cataclastic textures of marginal zones. This granite was analyzed for petrographics (composition, structure and texture), chemical composition (major elements), physical and mechanical (water absorption, resistance to abrasion, impact of hard body and efforts of compression and traction) and chemical attack aspects. The results were compared to suggested values for granitic rocks used for ornamental purposes. The whole massif shows compositional, textural, structural (related to isotropy) and chemical (major elements) characteristics very homogeneous. The varieties of sienogranite named commercially as Capão Bonito or Rubi Red Granite showed results very similar to each other, with some variations in the physical and mechanical resistance resulting of the penetrative brittle deformation of regional occurrence, evidenced by differences in the microfissural index.

Suíte plutônica Alumiador, grupo Amonguijá, maciço rio apa - MS

The Rio Apa Massif corresponds the southern portion of the Amazon Craton and is located in the southwest of Mato Grosso do Sul State. It consists on Paleoproterozoic rocks of Rio Apa Complex, Alto Tererê Group and Amonguijá Group, is subdivided into Alumiador Plutonic Suite and Serra da Bocaina Volcanic Suite. The volcanic suite is comprises sub volcanic, volcanic and varied volcanoclastics rocks with composition ranging from alkali-rhyolitic to rhyolite types. The plutonic suite corresponds to an N-S elongated batholith and is characterized by four main segments delimited by NW-SE faults. The southern and central main segments, discussed in this paper, are characterized by the following petrographic facies: medium to fine grained hornblende-biotite monzogranites, coarse grained biotite monzogranites, graphic biotite sienogranites and muscovite sienogranites and the northern segment is contemporaneous and is composed of two different sequences of rocks, one acid and another of basic to ultrabasic composition. The southern and central segment consists of to chemically compatible rocks with the types I and A Granites. These are calc-alkaline rocks of high potassium to the shoshonitic and subalkaline. Constitute sin-collisional granites of metaluminous the peraluminous characters of the Amonguijá Magmatic Arc, but they exhibit late litotypes with chemical characteristics of post tectonic granites from intraplate environment.