Síntese e emprego do ciclometalado [Pd(dmba)(N3)(PPh3)] em processos catalíticos envolvendo a n-carbonilação redutiva de nitroarenos a carbamatos e na síntese de derivados da uréia

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Síntese e emprego do [Pd(dmba)(NCO)(PPh3)] em processos catalíticos envolvendo a preparação de derivados da uréia e de alcoxicarbonil complexos

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Reactores aeróbios de lecho fluidizado trifásico con circulación interna: Caracterización hidrodinámica y del soporte

Aerobic internal-loop reactors use active biomass attached in a supporting media (biofilm) with the advantage of retaining a big biomass concentration in a small physical space, removing carbonaceous matter and nitrogen in only one reactor. Liquid circulation occurs due to hydrostatic pressure difference produced by air injection in the riser. In biphasic conditions liquid circulation velocities, gas holdup and oxygen transfer coefficient in four different reactor configurations were studied. For the three-phase conditions, the same parameters in just one of those configurations were evaluated. Also, there were three granular supporting media characterized. On the other hand, the relationship between internal and external tube areas and supporting media concentrations influence the liquid velocity, gas holdup and oxygen mass transfer values and some important supporting media characteristics were observed and compared.

Remoción de fósforo de diferentes aguas residuales en reactores aeróbios de lecho fluidizado trifásico con circulación interna

The wastewater discharge produces impacts on receiving water bodies. Nutrients as P produce implications on lentic systems because they accelerate the eutrophication processes. Several technologies for P removal from the wastewater have been used: physic chemical treatment systems with important effects by coagulant products addition; biological processes based on anaerobic and aerobic conditions with great implications on the required volume; natural systems as stabilization ponds and irrigation require bigger areas and post-treatment processes. The aerobic fluidized bed reactors with internal circulation (AFBRIC) are compact options with high concentrations of active biomass that have demonstrated their capacity for organic matter and N removal. For sewage from the wastewater pumping station of Ilha Solteira city and effluents of a recirculation aquaculture system (RAS) for semi-intensive tilapia farming, the reactive P and total P removal efficiency in three AFBRIC with 250 mm external tube diameter and different internal tube diameter (ITD), for two different support media at different concentrations was evaluated. The average reactive P removal efficiency for domestic wastewater to hydraulic retention time (HRT) of 3 hours and 125 mm ITD reactor varied from 25,6 to 38,4% and with 150 mm ITD reactor varied from 27,5 to 32,5%; the average total P removal for the RAS wastewater at a HRT of 0,19 hours and 100 mm ITD was of 32,7%.

Fatores que influenciam na atividade de titanocenos em catálise homogênea de polimerização de estireno

É apresentada uma revisão bibliográfica com 42 referências abordando aspectos históricos dos compostos organometálicos de titânio, sua aplicação em sistemas catalíticos utilizando metalocenos de titânio e os fatores que influenciam a catálise de alfa-olefinas com as conseqüentes repercussões nas estruturas dos polímeros.

Preparação de catalisadores de reforma de glicerol para células a combustível de eletrólito sólido

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Síntese, caracterização e propriedades da matriz sílica-carbono impregnada com níquel obtida pelo método dos precursores poliméricos

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Desenvolvimento de um sensor de amálgama sólido para a determinação de enxofre em microemulsões de biodiesel

Pós-graduação em Química - IQ

Estudos estruturais experimentais e teóricos com proteínas do veneno da serpente Bothrops jararacussu

Pós-graduação em Ciências Biológicas (Genética) - IBB

Análise experimental da reforma a vapor de etanol: aspectos técnicos, econômicos e ecológicos

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Vitrocerâmicas porosas via conformação e consolidação com amidos

The search for new methods of manufacture of glass-ceramics with controlled porosity and permeability is interesting of the industrial and commercial point of view, and a challenge of great complexity. Porous glass-ceramics produced by sintering and crystallization of glasses can find applications, for example, as filters, materials with bactericidal properties, bio-implants, as catalytic and enzymes supports, among others. An alternative and low cost method of ceramic manufacture reaching different levels of porosity, for diverse purposes, is the conformation assisted by addition of starch, known as consolidation with starch. The objective of this project is to study the process of conformation with starch for making porous glass-ceramics from a commercial glass in the system Na2O-CaO-SiO2, whose kinetics of sintering by viscous flow and surface crystallization are known. The method of conformation with starches is innovative for glass-ceramics and its development opens the way for obtaining a new class of materials. We found a possible route for the production of porous compacts of glass particles, from the powder preparation to the removal of starch. It was observed that a glass powder obtained by dry milling in a ball mill with alumina balls for 24 h, afterwards mixed with water in an eccentric ball mill for 2 h, without the addition of a deflocculant, and subsequently mixed with starch also in an eccentric ball mill for 5 min resulted in slurries stable against sedimentation

Análise e expressão de genes de PKS II e de carboidrases provenientes de bibliotecas metagenômicas

Pós-graduação em Microbiologia Agropecuária - FCAV

Nanozeólitas como suportes sólidos para imobilização enzimática: Síntese, caracterização de complexos nanozeólitas/enzimas e sua aplicação como catalisadores heterogêneos para produção de biodiesel via rota etílica

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Dimetilsulfóxidos como ligantes ancilares em complexos de rutênio: catalisadores duais para a combinação da ROMP de norborneno e ATRP de metacrilato de metila

Pós-graduação em Química - IBILCE

Produção de biodiesel etílico utilizando óxidos mistos derivados de hidróxidos duplos lamelares como catalisadores

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)