Application of nanotechnology for the encapsulation of botanical insecticides for sustainable agriculture: Prospects and promises

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Isolation of nanocellulose from pineapple leaf fibres by steam explosion

Steam explosion process is employed for the successful extraction of cellulose nanofibrils from pineapple leaf fibres for the first time. Steam coupled acid treatment on the pineapple leaf fibres is found to be effective in the depolymerization and defibrillation of the fibre to produce nanofibrils of these fibres. The chemical constituents of the different stages of pineapple fibres undergoing treatment were analyzed according to the ASTM standards. The crystallinity of the fibres is examined from the XRD analysis. Characterization of the fibres by SEM. AFM and TEM supports the evidence for the successful isolation of nanofibrils from pineapple leaf. The developed nanocellulose promises to be a very versatile material having the wide range of biomedical applications and biotechnological applications, such as tissue engineering, drug delivery, wound dressings and medical implants. (C) 2010 Elsevier Ltd. All rights reserved.

Memórias de uma Escola Isolada Rural: estudo de um Livro de Visitas (1928-1948)

Cet article étudie le livre de visites de l'ancienne école mixte de la Fazenda Ponte Alta/Bela Vista, liée au groupe scolaire de la ville de Bariri, dans l'état de São Paulo (SP). À partir des registres de vingt ans d'activités (1928-1948), nous retraçons les exigences des inspecteurs primaires et si ces exigences provenaient (ou non) de professeurs et de la communauté paysanne pour ébaucher un cadre socio-historique de l'enseignement des premières lettres dans la zone rurale de l'intérieur de l'état de São Paulo. Il en résulte que le discours qui défendait l'égalité de chances pour les populations urbaines et rurales négligeait généralement le besoin de promouvoir l'égalité de conditions pour que la communauté rurale puisse profiter des chances qui lui étaient promises.

Influence of light curing source on microhardness of composite resins of different shades

Introduction: The evolution of light curing units can be noticed by the different systems recently introduced. The technology of LED units promises longer lifetime, without heating and with production of specific light for activation of camphorquinone. However, further studies are still required to check the real curing effectiveness of these units. Purpose: This study evaluated the microhardness of 4 shades (B-0.5, B-1, B-2 and B-3) of composite resin Filtek Z-250 (3M ESPE) after light curing with 4 light sources, being one halogen (Ultralux - Dabi Atlante) and three LED (Ultraled - Dabi Atlante, Ultrablue - DMC and Elipar Freelight - 3M ESPE). Methods: 192 specimens were distributed into 16 groups, and materials were inserted in a single increment in cylindrical templates measuring 4mm x 4mm and light cured as recommended by the manufacturer. Then, they were submitted to microhardness test on the top and bottom aspects of the cylinders. Results: The hardness values achieved were submitted to analysis of variance and to Tukey test at 5% confidence level. It was observed that microhardness of specimens varied according to the shade of the material and light sources employed. The LED appliance emitting greater light intensity provided the highest hardness values with shade B-0.5, allowing the best curing. On the other hand, appliances with low light intensity were the least effective. It was also observed that the bottom of specimens was more sensitive to changes in shade. Conclusion: Light intensity of LED light curing units is fundamental for their good functioning, especially when applied in resins with darker shades.

A propaganda e a publicidade na TV digital: um estudo exploratório de tendências

Pós-graduação em Televisão Digital: Informação e Conhecimento - FAAC

O corpo na escola: um estudo sobre as relações entre cultura e processos de subjetivação

Pós-graduação em Educação - IBRC

Caracterização mecânica, física e química das ligas Ti-35Nb-5Zr e Ti-35Nb-10Zr

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

As relações de trabalho nas Organizações Estratégicas no mundo contemporâneo: a ilusão da droga organização

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Princípio constitucional da eficiência, efetividade da tutela jurisdicional e responsabilidade do Estado-juiz

Pós-graduação em Direito - FCHS

Some properties of intermetallic compounds of Sn with noble metals relevant for hydrogen electrocatalysis

Using density functional theory and a model developed in our own group, we have investigated the suitability of three intermetallic compounds - AuSn, PdSn, and PtSn - as electrode materials for hydrogen oxidation in fuel cells, focusing on their CO tolerance and their catalytic properties. All three metals were found to have lower susceptibility to be poisoned by CO compared to platinum, but only PtSn promises to be a good catalyst for hydrogen oxidation. (C) 2013 Elsevier Ltd. All rights reserved.

RAMSY: Ratio Analysis of Mass Spectrometry to Improve Compound Identification

The complexity of biological samples poses a major challenge for reliable compound identification in mass spectrometry (MS). The presence of interfering compounds that cause additional peaks in the spectrum can make interpretation and assignment difficult. To overcome this issue, new approaches are needed to reduce complexity and simplify spectral interpretation. Recently, focused on unknown metabolite identification, we presented a new approach, RANSY (ratio analysis of nuclear magnetic resonance spectroscopy; Anal. Chem. 2011, 83, 7616-7623), which extracts the signals related to the same metabolite based on peak intensity ratios. On the basis of this concept, we present the ratio analysis of mass spectrometry (RAMSY) method, which facilitates improved compound identification in complex MS spectra. RAMSY works on the principle that, under a given set of experimental conditions, the abundance/intensity ratios between the mass fragments from the same metabolite are relatively constant. Therefore, the quotients of average peak ratios and their standard deviations, generated using a small set of MS spectra from the same ion chromatogram, efficiently allow the statistical recovery of the metabolite peaks and facilitate reliable identification. RAMSY was applied to both gas chromatography/MS and liquid chromatography tandem MS (LC-MS/MS) data to demonstrate its utility. The performance of RAMSY is typically better than the results from correlation methods. RAMSY promises to improve unknown metabolite identification for MS users in metabolomics or other fields.

Documentação de fé: reflexões sobre os ex-votos e a sala das promessas do Santuário Nacional de Aparecida

This article brings to light a reflection about the possibility to enlarge the notion about document. Beyond the French school explanation, and taking up again important author of Information Science campus, the debates exposes within the Brazilian Catholic dimensions is possible to extrapolate the revision about the document’s idea, which is generally restrict to informational spaces. The National Sanctuary of Aparecida protects in a specific room the votive offerings – objects leaved there whether to pay a promise or to thank for any miracle that someone believes receive it. It is mediation’ space and it is can be thought as an environment, because there are possibilities to establish mediations inside it. Although, the room of the promises is a sacred and profane place, it involves a Cathequesis mission, expositive, informational, in spite of this last characteristic does not be explicit. First of all, the article reflects about the room of the promises and follows analyzing the document’s comprehension; in a second moment we finish purposing to understand the votive offering as a faith’s document, because they assume the position as proof of miracles and received graces, and these special objects brings with them a materiality positive and a documental value which the room fo the promises give to them.

As passagens do sagrado: da mercadoria ao ex-voto no Santuário Nacional de Nossa Senhora Aparecida/Brasil

This article reflects on the votive objects exhibited in the room of promises situated in the National Sanctuary of Nossa Senhora da Conceição Aparecida, located in the city named Aparecida (São Paulo, Brazil). At the sanctuary, there is an area to receive and exhibit votive offerings, which are donated as payment or to initiate a relationship of faith. This article’s aim is to understand how, from entering the room of promises, the votive object is selected and receives new directions, within the Sanctuary or outside it. Nonetheless, a small number are kept in this specific room dedicated to votive offerings. These objects become documents, social agents, because they reveal stabilization within associative relationships. With the help of readings from Information Science and other areas, and after carrying out ethnographic research over three years, this article shows how the materiality of information is indispensable for apprehending the relationship between society and information. Through contact with the votive offerings, the visitor establishes inferences, interpretations, which assist in comprehending the space, faith, and Nossa Senhora da Conceição Aparecida.

Espectrometria de massa para análise isotópica dos bio-elementos

Mass spectrometry is an analytical technique widely used in several areas of academic research. It allows the knowledge of the information about the micro-world of atoms leading to significant advances in science today. The analysis of stable isotopes of carbon, hydrogen, oxygen, nitrogen and sulfur, also known as bio-elements, shows itself as a major area of interest in using the proposed method. The development of techniques and equipment coupled with mass spectrometry promises to deliver even greater progress in this field, in particular, for the biological sciences and related areas. The pyrolytic method in reduction of organic compounds at high temperatures provides simultaneous isotopic analysis of bio-elements H and O, by the gases released, H2 and CO after the pyrolitic process, significantly reducing analysis time and the amount of material to sample. This paper presents a review of mass spectrometry with its basic principles of operation, and pyrolytic method for reducing compounds at temperatures above 1400 ° C for isotopic analysis of bio-elements

An Informatics Technical Note on Interaction of DNA - Graphene Chemical Sensor System as Reaction-Diffusion Wave-Based Computing System in Ionised Gaseous environments and their Applications Using Theoretical Studies and Scientific Computation Overview

The physics of plasmas encompasses basic problems from the universe and has assured us of promises in diverse applications to be implemented in a wider range of scientific and engineering domains, linked to most of the evolved and evolving fundamental problems. Substantial part of this domain could be described by R–D mechanisms involving two or more species (reaction–diffusion mechanisms). These could further account for the simultaneous non-linear effects of heating, diffusion and other related losses. We mention here that in laboratory scale experiments, a suitable combination of these processes is of vital importance and very much decisive to investigate and compute the net behaviour of plasmas under consideration. Plasmas are being used in the revolution of information processing, so we considered in this technical note a simple framework to discuss and pave the way for better formalisms and Informatics, dealing with diverse domains of science and technologies. The challenging and fascinating aspects of plasma physics is that it requires a great deal of insight in formulating the relevant design problems, which in turn require ingenuity and flexibility in choosing a particular set of mathematical (and/or experimental) tools to implement them.