P3L-3 Viscosity measurement of Newtonian liquids using the complex reflection coefficient

This work presents the implementation of the ultrasonic shear reflectance method for viscosity measurement of Newtonian liquids using wave mode conversion from longitudinal to shear waves and vice-versa. The method is based on measuring the complex reflection coefficient (magnitude and phase) at a solid-liquid interface. Viscosity measurements were made in the range from 1 to 3.5MHz at 22.5°C for automotive oil (SAE40) and at 15°C for olive oil. Moreover, measurements of the olive oil were also conducted in the range from 15 to 30°C at 3.5MHz. The experimental results agree with those provided by a rotational viscometer. © 2006 IEEE.

Experimental study of the complex reflection coefficient of shear waves from the solid-liquid interface

The determination of the reflection coefficient of shear waves reflected from a solid-liquid interface is an important method in order to study the viscoelastic properties of liquids at high frequency. The reflection coefficient is a complex number. While the magnitude measurement is relatively easy and precise, the phase measurement is very difficult due to its strong temperature dependence. For that reason, most authors choose a simplified method in order to obtain the viscoelastic properties of liquids from the measured coefficient. In this simplified method, inconsistent viscosity results are obtained because pure viscous behavior is assumed and the phase is not measured. This work deals with an effort to improve the experimental technique required to measure both the magnitude and phase of the reflection coefficient and it intends to report realistic values for oils in a wide range of viscosity (0.092 - 6.7 Pa.s). Moreover, a device calibration process is investigated in order to monitor the dynamic viscosity of the liquid.

The role of counterion on the thermotropic phase behavior of DODAB and DODAC vesicles

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Water at interfaces and its influence on the electrical properties of adsorbed films

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Mechanism of phase formation in Pb(ZrxTi1-x)O3 synthesized by a partial oxalate method

The phase formation mechanism, as well as the morphotropic phase boundary, of lead zirconate titanate (PZT) processed by a partial oxalate method was investigated by simultaneous thermal analysis (TG-DTA) and by qualitative and quantitative X-ray diffraction (XRD). The results show that the ZrxTi1-xO2 (ZT) phase reacts with PbO forming the PZT phase without intermediate phases. XRD analysis showed the coexistence of rhombohedral and tetragonal phases for 0.47 ≤ x ≤ 0.55 with the phase boundary composition for x = 0.51. For low calcination temperatures, preferential formation of the PZT rhombohedral phase was observed. A model for phase formation of PZT by the partial oxalate method is proposed based on the existence of two interfaces of reaction (PbO-PZT and PZT-ZT) and diffusion of cations.

Mechanical behaviour of strain aged dual phase steels

Dual phase steels, characterised by good formability and excellent surface finish, are suitable for applications where processing involves cold deformation. In this context an investigation has been conducted into the cold deformation aging susceptibility of carbon steel API-5L-B and microalloyed steel API-5L-X52, both with dual phase microstructures. Changes in mechanical properties such as phase microhardness, ultimate tensile strength, and yield strength in both types of steel were observed at aging temperatures of 25, 80, and 150°C. This aging is associated with dislocation structures formed on ferrite grains in the vicinity of ferrite/martensite interfaces during intercritical treatments, which become preferential sites for solute atom diffusion. © 1999 IoM Communications Ltd.

Phase transitions and interface phenomena in the cryogenic temperature domain of a niobate nanostructured ceramic

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)