329 resultados para Liga aquea

em Repositório Institucional UNESP - Universidade Estadual Paulista "Julio de Mesquita Filho"


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The interface formed between the metal and the porcelain of a LASER welded Ni-Cr-Mo alloy was studied. The characterization was carried out through optical microscopy, scanning electron microscopy, X-ray dispersive spectroscopy-EDS and mechanical testing by three-point flexion test-TPE in the region LASER welded with and without the porcelain. The porcelain adhesion with the alloy alone is possible after the oxidation of the metallic surface and subsequent application of an adhesive called opaco. The applied porcelain, on the base metal and fusion zone presented some distinct behaviors. After the TPF test the base metal presented fractures while that in the fusion zone was completely gone. One noticed that the region submitted to the LASER welding showed less porcelain adhesion than the region of the base metal due to the microestructural refinement of the fusion zone. These results can be evidenced by the EDS of the studied regions. The TPF had demonstrated that the Ni-Cr-Mo alloy submitted to the LASER welding, undergone significant alterations in its mechanical properties after the application of the porcelain.

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A reação de precipitação de prata na liga Cu-8%Al-6%Ag foi estudada usando medidas de variação da microdureza com a temperatura e o tempo de envelhecimento, difratometria de raios X (DRX), calorimetria exploratória diferencial (DSC), microscopia eletrônica de varredura (MEV). Os resultados obtidos indicaram que o mecanismo da reação de precipitação da prata é um processo controlado pela difusão da prata e a velocidade desta reação atinge um máximo em torno de 500°C.

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The authors studied linear alterations processed on copper-aluminum casten MOD blocks, obtained from two expansion techniques (termic and hygroscopic by immersion). UNITERMS: Investment expansion. Thermic expansion. Hygroscopic expansion. Casten Technique.

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A very new method application for digital image processing and analysis to classify shape and evaluate size and morphology parameters of pit corrosion is used in this paper. This method seems to be very effective to analysis surfaces with low or high degree of pitting formation. Pits formed on 2024 alloy surface by chloride and by chloride + molibdate anions have similar mean area, are found to be widther than deeper and exhibit predominantly conical or near-conical and irregular geometries.

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New classes of martensitic stainless steels, with low carbon levels, have been developed aiming to meet the needs of the petroleum industry segment. However, their use has been restricted due to the fact it is a recent development and many of its properties are still under investigation. This work determines the values of initial and final temperatures for the austenitic transformation and the initial and final temperatures of martensitic formation for alloy 13Cr2Ni0,1C, by means of dilatometric tests under continuous cooling. Based on these results the optimized conditions for quench and temper heat treatments were obtained. The microstructural characterization of the alloys under coarse fusion condition was carried out by optical microscopy and the presence of delta-ferrite in the martensitic matrix was observed.

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In this work, surface modification of the Ti-6Al-4V alloy by irradiation with a Nd:YAG laser beam was studied. The matrix spacing was varied and the other parameters were kept constant. After theirradiation, the samples were immersed into SBF solution (Simulated Body Fluid) for 7 days at 37 ° C for nucleation and formation of calcium phosphates. After this period, the samples were subjected to a heat treatment at 600 °C. X-ray diffraction results indicated the formation of a mixture of phases containing hydroxyapatite and tricalcium phosphate. Infrared analysis demonstrated the presence of bands related to hydroxyapatite. SEM micrographs showed that different matrix spacing used leads to the formation of different morphologies.The 0.01 cm spacing induced the formation of microspheres, characteristic of the hydroxyapatite phase, while for 0.02 cm spacing, only a non-homogeneous coating was obtained. Therefore, the use of laser in the production of active surfaces for deposition of bioceramics proved to be viable, and the final coating has potential for applications in the field of dental implants.

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Pós-graduação em Ciências Sociais - FFC