Evaluation of mechanical and thermal properties after chemical degradation of PVC and HDPE geomembranes

Chemical compatibility between geomembranes and site-specific waste liquids should be assessed since the waste liquids are highly complex mixtures. This paper presents some considerations about the chemical compatibility of geomembranes and some results of mechanical tests in HDPE and PVC geomembranes that were exposed to leachate and chemical residue (niobium). PVC and HDPE geomembranes of two thicknesses were tested: 1.0, 2.0 mm (PVC) and 0.8, 2.5 mm (HDPE). The results obtained show that after exposure the PVC geomembranes (1.0, 2.0 mm) were more rigid and stiffer than fresh samples. The HDPE geomembranes, on the other hand, when exposed to leachate and niobium residue presented increases in deformation. Melt flow index (MFI) tests were also carried out to verify the oxidation. © 2013 ejge.

Thermal degradation of geomembranes after exposure to heat

HDPE and PVC geomembranes are sensitive to changes in their properties when in contact with high temperatures. The effects of hot temperature on polymeric geomembranes are assessed by the ASTM D794 and ASTM D5721.This paper brings an analysis of degradation of the Poly Vinyl Chloride (PVC) and High Density Poly Ethylene (HDPE) geomembranes when exposed to conventional and air oven after specific periods.. Mechanical and physical properties were evaluated. OIT tests were also performanced to evaluate the level of oxidation degradation occurred on the HDPE geomembranes. Geomembranes of two thicknesses were tested: 1.0, 2.0 nun (PVC) and 0.8, 2.5 mm, (HDPE). The results obtained show, for example, that after the last period of exposure, the PVC geomembranes (1.0, 2.0 mm) were more rigid and stiffer than fresh samples. The HDPE geomembranes, on the other hand, when exposed to heat presented increases in deformation. OIT tests showed efficient to detect some level of degradation on the HDPE geomembranes.

The Effects of Weathering Exposure on the Physical, Mechanical, and Thermal Properties of High-density Polyethylene and Poly (Vinyl Chloride)

This paper presents results describing the physical, mechanical, and thermal properties (melt flow index - MFI and oxidative induction time - OIT) of high density polyethylene and poly (vinyl chloride) after weathering exposure (6, 12, 18, and 30 months). The materials exposed were geomembranes of two thicknesses: 1.0 and 2.0 mm (PVC) and 0.8 and 2.5 mm (HDPE). The climate parameters (average) obtained were 25 degrees C (temperature), 93 mm (precipitation), 66% (relative humidity), and 19 MJ/m(2). day (intensity of global radiation). Some results showed, for instance, that the behavior of the geomembranes changed after the exposures. A few minor variations in physical properties occurred. The density and thickness, for instance, varied 0.5-1.0% (average) for both the PVC and HDPE geomembranes. The mechanical properties changed as a function of the period of exposure. In general, some decreases were verified by the deformation of PVC. The samples became more rigid. In contrast, HDPE geomembranes became more ductile. Despite the variations in elasticity, some increases in deformability were verified. An MFI test showed some degradation in HDPE geomembranes. OIT tests revealed small values for both intact and exposed samples.

Thermo-gravimetric analysis (TGA) after different exposures of high density polyethylene (HDPE) and poly vinyl chloride (PVC) geomembranes

This paper presents the results of thermogravimetric analysis (TGA) tests in PVC (1.0; 2.0 mm) and HDPE (0.8; 2.5 mm) geomembranes exposed to weathering and leachate after 30 months. The aim of this paper is the comparison of fresh and exposed samples to assess the degradation process concerning the total loss of mass of geomembranes. The exposure was conducted in accordance with the recommendations of ASTM standards. The TGA tests were carried out according to ASTM D6370 and E2105. Results show, for instance, that for PVC geomembrane the largest reductions of plasticizers occurred for samples exposed to weathering. The loss of plasticizers after the exposure contributed to the decrease of deformation and consequent increase in stiffness. TGA tests shows to be a valuable tool to control the quality of the materials. © 2012 ejge.

Biodegradation of blend films in soil and soil with chorume. I. PVC/PCL

Blends of synthetic and biodegradable polymers can be important in attaining material plastic degradation in the environment. Biodegradation using soil and chorume (liquid waste from landfill) microorganisms is a promising area these days. This paper intends to study the PVC/PCL blend degradation in soil using aerobic biodegradation (Bartha respirometer). The morphology and structural changes of the blends were studied by FTIR, scanning electron microscopy, differential scanning calorimetry and contact angle measurements. Blend films prepared by the casting of dichloroethane solutions were buried in a Bartha respirometer containing soil and soil plus chorume and kept there for 120 days. During this time CO2 evolution was measured from time to time. The results showed that PCL films degrade faster than PVC/PCL and PVC films.

Structural and morphological changes in Poly(caprolactone)/poly(vinyl chloride) blends caused by UV irradiation

Films made from a blend of poly(epsilon-caprolactone) and poly(vinyl chloride) (PCL/PVC) retained high crystallinity in a segregated PCL phase. Structural and morphological changes produced when the films were exposed to high potency ultraviolet (UV) irradiation for 10 h were measured by UV-Vis spectroscopy (UV-Vis), Fourier Transform Infrared Spectroscopy (FTIR), and Scanning Electron Microscopy (SEM). They were different to those observed with homopolymer PCL and PVC films treated under the same conditions. The FTIR spectra of the PCL/PVC blend suggest that blending decreased the susceptibility of the PCL to crystallize when irradiated. Similarly, although scanning electron micrographs of PCL showed evidence of growth of crystalline domains, particularly after UV irradiation, the images of PCL/PVC were fairly featureless. It is apparent that the degradation behavior is strongly influenced by the interaction of the two polymers in the amorphous phase.

Mechanical properties, hydrophilicity and water activity of starch-gum film: effect of additives and deacetylated xanthan gum

The effect of deacetylated xanthan gum, additives (sucrose, soybean oil, sodium phosphate and propylene glycol) and pH modifications on mechanical properties, hydrophilicity and water activity of cassava starch-xanthan gum films has been studied. Sucrose addition resulted in the highest effect observed on cassava starch films elongation at break. The deacetylated xanthan gum had higher effect on elongation at break when comparing to the acetylated gum, although both gums presented an inferior effect in relation to the obtained with sucrose. However, when comparing to the control and PVC films, lower tensile strength resistance values were observed when adding sucrose. Increased water activity was observed for films added with sucrose, thus, increasing the material biodegradation. Sucrose and deacetylated xanthan gum addition resulted in a slight hydrophilicity increase. (C) 2004 Elsevier Ltd. All rights reserved.

Characterization of high density polyethylene (HDPE) reinforced with banana peel fibers

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Análise da eficiência do cobre, alumínio e PVC como condutores hidráulicos em aquecedores solares

One of society concerns are preserving the environment and the growing energy demand. These two issues are in conflict since most of the energy used today in some way harms the environment. Then is essential to develop and implement ways to clean and renewable energy. In this way, solar energy stands out as a source of clean energy, renewable, abundant and acessible. Solar energy can be harnessed by photovoltaic cells or by solar collectors. The aim of this article is analysethe yield of the solar heather assembled with hydraulic conductive and plastic bottles using three different materials for hydraulic conductors, in order to compare these efficiences and analyze material which has the best cost-benefit in this type of application. The materials analyzed in this study were copper, aluminum and PVC. For this analysis were assembled three alike solar heaters using each one of these materials, and were done several series of measurements of the temperature water output to each heat with flow between 10 and 30 liters per hour. With these data we can analyze the yield and the performance of copper, aluminum and PVC in this application. So we can conclude that aluminum has a higher efficiency, followed by PVC, and the copper had the lowest efficiency. This behavior kept for all values of flow rates examined

Use of modified atmosphere to extend shelf life of fresh-cut carambola (Averrhoa carambola L. cv. Fwang Tung)

Fresh-cut fruit products, including carambola (Averrhoa carambola L.), have limited marketability due to cut surface browning attributed to phenolic compound oxidation by enzymes, such as polyphenol oxidase (PPO). The objective of this study was to evaluate postharvest changes in carambola slices in three different packages. Carambola fruit (cv. Fwang Tung) were picked from the Estacao Experimental de Citricultura de Bebedouro orchard at the mature-green stage. The fruit were washed, dipped in NaOCl solution (200 mg L-1 for 5 min), stored overnight at 10 degrees C, then manually sliced into pieces of approximately 1 cm. The slices were rinsed with NaOCl solution at 20 mg L-1, drained for 3 min, and packaged in polyethylene terephthalate (PET) trays (Neoform (R) N94); polystyrene trays covered with PVC 0.017 turn (Vitafilm (R), Goodyear); and vacuum seated polyolefin bags (PLO, Cryovac (R) PD900). The packages were stored at 6.8 degrees C and 90% RH for 12 d, with samples taken every 4 d. PET trays and PVC film did not significantly modify the internal atmosphere and the high water permeability of PVC led to more rapid slice desiccation. PPO activity was lower when the slices were packaged in PLO vacuum sealed bags, which reduced degreening and led to better appearance maintenance for up to 12 d. (R) 2006 Elsevier B.V. All rights reserved.

Conservação pós-colheita de abacaxi 'Pérola' colhido no estádio de maturação pintado associando-se refrigeração e atmosfera modificada

Estudou-se a manutenção da qualidade do abacaxi 'Pérola', utilizando-se de refrigeração e atmosfera modificada. Os frutos foram armazenados em ambiente com controle de temperatura a 8ºC e 90%UR, durante 17 dias, quando foram transferidos para condição de ambiente (25ºC, 75-80%UR). Eles foram avaliados na recepção, caracterizando-os, após 5; 9; 13 e 17 dias sob refrigeração, e depois de transferidos para as condições de ambiente, aos 21; 25 e 29 dias. O delineamento experimental utilizado foi o inteiramente casualizado, em esquema fatorial (6 x 8), tendo-se seis tratamentos (testemunha, duas ceras e três filmes plásticos) e oito épocas de avaliação. Os frutos foram avaliados quanto à coloração, ocorrência de podridões e de escurecimento interno, e a polpa avaliada quanto ao pH e aos teores de sólidos solúveis totais (SST), acidez total titulável (ATT), ácido ascórbico e açúcares solúveis, totais e redutores. Durante o armazenamento, observaram-se o amarelecimento dos frutos, o aumento no pH, na relação SST/ATT, e nos teores de açúcares solúveis, totais e redutores, que foram maiores após a transferência dos frutos para o ambiente. Os sintomas de injúria por chilling aumentaram com o tempo de armazenamento. Os tratamentos que modificam a atmosfera (embalagens e ceras) não influenciam significativamente nos principais atributos de qualidade do abacaxi 'Pérola', mas o uso de embalagem com PEBD e PVC atrasou o aparecimento de sintomas de escurecimento interno após a transferência dos frutos para a condição ambiente. Os frutos sem embalagem e os tratados com cera mostraram-se mais sensíveis à injúria por chilling, que se manifestou aos quatro dias após a remoção para o ambiente. A embalagem em PEBD e PVC retardou o aparecimento dos primeiros sintomas, em quatro dias.

Utilização de um eletrodo de grafite-epóxi recoberto com [Zn(FEN)3][tetratris(4-clorofenil) borato]2 sensível a zinco(II) em meio 1,10-fenantrolina como eletrodo indicador em titulações potenciométricas de precipitação

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Influência do tipo de coleta (comum ou seletiva) na reciclagem de filmes de poliolefinas pós-consumo

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Use of modified atmosphere to extend shelf life of fresh-cut carambola (Averrhoa carambola L. cv. Fwang Tung)

Fresh-cut fruit products, including carambola (Averrhoa carambola L.) have limited marketability due to cut surface browning attributed to oxidation of phenolic compounds by enzymes such as polyphenol oxidase (PPO). The objective of this study was to evaluate postharvest changes of carambola slices in three different packagings. Carambola fruit (cv. Fwang Tung) were picked from the orchard of Estação Experimental de Citricultura de Bebedouro at mature-green stage. Fruit were washed, dipped in NaOCl solution (200 mg.L -1 for 5 minutes), and stored overnight at 10°C. Fruit were manually sliced into pieces of approximately 1 cm. Slices were rinsed with NaOCl solution at 20 mg.L-1, drained for 3 minutes, and packaged in polyethylene terephthalate (PET) trays (Neoform N94); polystyrene trays covered with PVC 0.017 mm (Vitafilm - Goodyear); and vacuum sealed polyolefin bags (PLO, Cryovac PD900). The packages were stored at 6.8°C and 90%RH for 12 days and samples taken every 4 days. PET trays and PVC film did not significantly modify internal atmosphere and the high water permeability of PVC led to more rapid slice desiccation. PPO activity was lower when slices were packaged in PLO vacuum sealed bags, which reduced discolouration and led to better appearance maintenance for up to 12 days.

Influência do pneumoperitôneo sobre a pressão pleural, parâmetros cardiovasculares e hemogasométricos em eqüinos

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)