12 resultados para Eutectic

em Repositório Institucional UNESP - Universidade Estadual Paulista "Julio de Mesquita Filho"


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We report herein on a comparison of the performance of two different grinding wheels (conventional and CBN) in the transverse cylindrical grinding of a eutectic alloy. Three cutting conditions were tested: rough, semi-finishing and finishing. The parameters of evaluation were the cutting force, roughness and wheel wear. The optimal cutting force and roughness values were obtained when grinding with the conventional wheel, due to the superior dressing operation performed under every cutting condition tested. Although the CBN wheel presented the best G ratio values, they were lower than expected owing to the inappropriate dressing operation applied. Excessive wheel corner wear was detected in both wheels, caused by the grinding kinematics (transverse grinding) employed. In terms of cutting force and roughness, the conventional wheel proved to be the better choice under the conditions tested. However, in terms of the G ratio, a cost analysis is crucial to determine whether the differences between the wheels justify the use of the CBN wheel, in which case the dressing operation requires improvement.

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Metallographic studies by scanning electron microscopy and energy dispersive spectroscopy carried out for two types of dental amalgam showing a porous multiphase material. Surface analysis shows that the structure of the Dispersalloy amalgam consists of gamma-Ag3Sn, gamma(1)-Ag2Hg3, eta'-Cu6Sn5, epsilon-Cu3Sn and eutectic Ag-Cu phases. while Velvalloy amalgam consists mainly of gamma, gamma(1) and gamma(2)-Sn7-8Hg phases. The latter phase presents an uniform distribution often associated with voids.

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Metallographic studies carried out for Tytin-Plus and Dispersalloy amalgams show a porous multiphase material, whose surface phases are: gamma-(Ag3Sn), gamma(1)-(Ag2Hg3), eta'-(Cu6Sn5) and epsilon-(Cu3Sn). Additionally, Dispersalloy is present in the Ag-Cu eutectic. The application of surface analysis by SEM reveal a heterogeneous distribution of the above mentioned phases. Microstructures consisting of colonies or clusters were not observed. The corrosion testing of these materials was done in 0.9% NaCl aerated solution at 25 degrees C using potentiodynamic polarization curves and ac impedance measurements. The corrosion process in these multiphase systems can be interpreted as the sum of more than one electrodissolution process and the posterior formation of corrosion films. on each electrode, the corrosion film is formed by different mechanisms. (C) 1998 Elsevier B.V. B.V. All rights reserved.

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Continuous strip metal matrix composite (MMC) casting of 0.3 mm diameter hard-drawn stainless steel (316L) wire in a quasi-eutectic SnPb (64Sn36Pb) matrix was performed by a two-roll melt drag processing (TRMDping) method, with the wire being dragged through a semisolid puddle with a fibre contact time of approximately 0.2 s. A slag weir placed at the nozzle contained two wire guide holes: one located near the upper roll, and the other located between the rolls. A successful continuous composite strip casting with good fibre alignment was achieved by inserting and embedding the wire into the matrix using the guide hole between the rolls. Degeneration of eutectic/dendrite structures led to the formation of globular structures. The occurrence and formation mechanisms of cracks, de-lamination and voids in the matrix were discussed. TRMDping is economically viable and has significant benefits over other MMC fabrication methods. © (2013) Trans Tech Publications, Switzerland.

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Alloy Al-7%Si-0,3Mg (AA356), having an excellent combination of properties such as low solidification shrinkage and good fluidity, good weldability, high wear resistance, high strength to weight particularly in the automotive and aerospace engineering. The refinement of the structure aluminum silicon eutectic alloy is a fairly common practice in the casting, through the treatment knows as modification. You can get the modification for the addition of chemicals and rare earths, these have the ability to modify the structure of the eutectic, but only sodium and strontium produce a strong action modifier when used in low concentrations. The modifying effect of silicon grain turns into a fibrous form branched and enveloped by the metal matrix in the form of a composite structure that has the highest limit of tensile strength, ductility and machinability. This work will be obtained AA356 alloy ingots using two different types of molds: metal mold and sand mold. Macrographs will be made in ingots obtained for observation of the macrostructures obtained in both types of ingots. Will be sampled at strategic locations of the ingots to correlate microstructure and cooling rate. The results showed that the material of the ingot has a strong influence on the resulting micro-andmacrostructure

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The AA356 alloy is an alloy widely used in the automotive industry and aerospace due to its excellent mechanical properties. Refining the structure of eutectic silicon aluminum alloys is a fairly common practice in the foundry through treatment known as modification. This can be achieved by modifying agent adding chemicals such as contained in groups I and IIa of the periodic table and rare earths (europium, céreioi, praseodymium, neodymium, etc.). Has the ability to modify the structure of the eutectic, but only sodium and strontium produce an action modifier strong when used in low concentrations. The modifying effect of the shafts turn silicon into a fibrous form and branched surrounded by metallic matrix in the form of a composite structure that has the highest limit of tensile strength, ductility and machinability. In this work will be obtained ingots with and without the modifier type Al-10% Sr, made in sand molds and are generated and analyzed cooling curves and also the study of the macrostructure and microstructure of the solidified material. It was found that by adding the Al-Sr made shorten the solidification time and lower the grain size

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This study aimed to analyze the cooling curves, micro and macrograph alloy Al-1 %Si without the addition of strontium modifier and with the addition of the same. One of the ways of improving mechanical properties of alloy Al -Si is through the modification process. For the experiments two billets of the alloy Al-1%Si cast iron mold in a billet with addition of 0.02% strontium by weight, and the other billet without the addition of modifier were fused. In the solidification process of billet temperature was monitored and recorded every second for later plotting in Origin 8 program and analyzes the cooling curves obtained. The billets were cut and passed by grinding and polishing to perform the macrograph and micrographs. The results concerning the macrograph indicated that billet without the addition of Strontium particle size obtained was more refined than the billet where the strontium modifier was added. Regarding the micrograph, photos stemmed from the optical microscope didn´t show the expected modification effect by the addition of Strontium. This suggests that the low amount of silicon (1 %) present in the alloy used in this study interfered in the change process, because according to the literature review, Strontium 0.022 % by weight is sufficient to fully modify an alloy with 7% Silicon. The results from the cooling curve showed that both the eutectic temperature and the solidification time remained unchanged with the addition of strontium

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Several alloys have been used for prosthodontics restorations in the last years. These alloys have a number of metals that include gold, palladium, silver, nickel, cobalt, chromium and titanium and they are used in oral cavity undergo several corrosion. Corrosion can lead to poor esthetics, compromise of physical properties, or increased biological irritation. The objective of this study was evaluated corrosion resistance of two alloys Ni-Cr and Ni-Cr-Ti in three types of mouthwashes with different active ingredients: 0.5g/l cetylpyridinium chloride + 0.05% sodium fluoride, 0.05% sodium fluoride + 0.03% triclosan (with fluor) and 0.12% chlorohexidine digluconate. The potentiodynamic curves were performed by means of an EG&G PAR 283 potentiostat/galvanostat. The counter electrode was a platinum wire and reference electrode was an Ag/AgCl, KCl saturated. Before each experiment, working electrodes were mechanically polished with 600 and 1200 grade papers, rinsed with distilled water and dried in air. All experiments were carried out at 37.0oC in conventional three-compartment double wall glass cell containing mouthwashes. The microstructures of two alloys were observed in optical microscopy. Analysis of curves showed that Ni-Cr alloy was less reactive in the presence of 0.12% chlorohexidine digluconate while Ni-Cr-Ti alloy was more sensitive for others two types of mouthwashes (0.5g/l cetylpyridinium chloride + 0.05% sodium fluoride  and 0.05% sodium fluoride + 0.03% triclosan). This occurred probably due presence of titanium in this alloy. Microstructural analysis reveals the presence of dendritic and eutectic microstructures for NiCr and Ni-Cr-Ti, respectively.