Determination of rice herbicides, their transformation products and clofibric acid using on-line solid-phase extraction followed by liquid chromatography with diode array and atmospheric pressure chemical ionization mass spectrometric detection

A simultaneous method for the trace determination of acidic, neutral herbicides and their transformation products in estuarine waters has been developed through an on-line solid-phase extraction method followed by liquid chromatography with diode array and mass spectrometric detection. An atmospheric pressure chemical ionization (APCI) interface was used in the negative ionization mode after optimization of the main APCI parameters. Limits of detection ranged from 0.1 to 0.02 ng/ml for 50 mi of acidified estuarine waters preconcentrated into polymeric precolumns and using time-scheduled selected ion monitoring mode. Two degradation products of the acidic herbicides (4-chloro-2-methylphenol and 2,4-dichlorophenol) did not show good signal response using APCI-MS at the concentration studied due to the higher fragmentor voltage needed for their determination For molinate and the major degradation product of propanil, 3,4-dichloroaniline, positive ion mode was needed for APCI-MS detection. The proposed method was applied to the determination of herbicides in drainage waters from rice fields of the Delta del Ebro (Spain). During the S-month monitoring of the herbicides, 8-hydroxybentazone and 4-chloro-2-methylphenoxyacetic acid were successively found in those samples. (C) 2000 Elsevier B.V. B.V. All rights reserved.

Levantamento histórico da Classe Tentaculitoidea no Devoniano brasileiro: principais características e padrões de preservação

This work deals with the historical survey of the class for the Devonian layers, general characteristics of the group and taphonomic preservation standards associated with the group. It was analyzed specimens of scientific collections from brazilian museums and universities. The taxonomic group is represented by four genera in the basins of Parana, Parnaiba and Amazon: Tentaculites, Homoctenus, Styliolina and Volynites. The tentaculitids occur from Ordovician to the Devonian, having its peak in the Middle Devonian. The class has three known orders: Tentaculitida, animals of benthic habit, Homoctenida and Dacryoconarida, animals of habit planktonic. It was also noticed the presence of two patterns of taphonomic conservation: isolated and grouped specimens.

Comparación de tres métodos para estimar estabilidad del rendimiento en nueve variedades de algodón

With the purpose of selecting and recommending promissory cultivars of cotton, Gossypium hirsutum (L) with high yield potential and stability, for crop areas in Venezuela, the yield (seed included) of nine cotton varieties was evaluated. The data from the 1995-96 and 1996-97 cycles was used. The experimental design was a randomized completed block design with four repetitions on twelve environments. Parameters of stability offered by the methods of Eberhart and Russell, (1966), Cruz et al. (1989) and the AMMI model were estimated and compared to determine the best method or combination. There was no coincidence between the best yield varieties, Unellez-2 and the commercial variety Delta Pine 16, in relation to stability criteria. According to Eberhart and Russell, these were classified as stable, while according to Cruz et al. they were adaptive to favorable environments and according to AMMI they were unstable with high interaction,.Of the three methods studied, the AMMI model allowed associating the response of high yield varieties to specific environments, gave more information and was easier to interpret.

Hydrochemical and stable isotopes (H, O, S) signatures in deep groundwaters of Parana basin, Brazil

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)