Método multiresiduo para determinar pesticidas en frutas por extracción con fluido supercrítico

A rapid and reliable method for the determination of 25 compounds selected from four classes of pesticides in samples of fresh apples, grapes, pears, and strawberries purchased at a local supermarket, is presented. The study describes two different methods of extraction: solid-liquid extraction with acetone and supercritical fluid extraction. Clean-up was based on aminopropyl cartridge extraction followed by gas chromatography with an electron capture detector for simultaneous determinations. Confirmatory analysis was carried out by gas chromatography with mass spectrometry in the selected-ion monitoring (SIM) mode. Extraction efficiencies were directly compared and the methods were applied to the analysis of real samples. Recoveries for a majority of pesticides from standard samples at enrichment levels of 0.04-0.10 mg/ kg ranged from 77 to 96 % for both methods. The supercritical fluid extraction method showed good limits of detection (less than 0.01 mg/kg, depending on the pesticide and matrix) as well as minimizing environmental concerns, time, and laboratory effort. © 2006 Centro de Información Tecnológica.

Abordagens estatísticas em testes de resistência de união entre dentina bovina, sistema adesivo e resina composta

Pós-graduação em Odontologia Restauradora - ICT

Concepções de tecnologia de graduandos do estado de São Paulo e suas implicações educacionais: breve análise a partir de modelagem de equações estruturais

This paper presents some results from a study of undergraduate students from different regions of the State of São Paulo that sought to better understand the relationships between society and perceptions and attitudes towards technological development. Noting that the media, academia and official documents regulating education understand and present the technology in a distinct and often contradictory ways, this paper seeks to review existing literature on the different ways to conceptualize this term, and thereafter, to develop a Likert' scale for mapping the concepts of students. Using the confirmatory analysis of structural equation modeling, this research concludes that the sample studied shows a classical view, but outdated, what means technology, by linking it to science and technology without distinction or critical viewpoints.

Confirmatory factor analysis of different versions of the Body Shape Questionnaire applied to Brazilian university students

This study aimed at evaluating the validity, reliability, and factorial invariance of the complete (34-item) and shortened (8-item and 16-item) versions of the Body Shape Questionnaire (BSQ) when applied to Brazilian university students. A total of 739 female students with a mean age of 20.44 (standard deviation = 2.45) years participated. Confirmatory factor analysis was conducted to verify the degree to which the one-factor structure satisfies the proposal for the BSQ's expected structure. Two items of the 34-item version were excluded because they had factor weights (lambda)< 40. All models had adequate convergent validity (average variance extracted =.43-.58; composite reliability=.85-.97) and internal consistency (alpha =.85-.97). The 8-item B version was considered the best shortened BSQ version (Akaike information criterion = 84.07, Bayes information criterion = 157.75, Browne-Cudeck criterion= 84.46), with strong invariance for independent samples (Delta chi(2)lambda(7)= 5.06, Delta chi(2)Cov(8)= 5.11, Delta chi(2)Res(16) = 19.30). (C) 2014 Elsevier Ltd. All rights reserved.