PREPARATION and CHARACTERIZATION of CELLULOSE/HYDROUS NIOBIUM PHOSPHATE HYBRID

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

SUGARCANE BAGASSE PULPING and BLEACHING: THERMAL and CHEMICAL CHARACTERIZATION

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

CHEMICAL MODIFICATION EFFECT on THE MECHANICAL PROPERTIES of HIPS/COCONUT FIBER COMPOSITES

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

NOVEL CELLULOSE/NbOPO4 center dot nH(2)O HYBRID MATERIAL FROM SUGARCANE BAGASSE

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

SURFACE MODIFICATION of SUGARCANE BAGASSE CELLULOSE and ITS EFFECT on MECHANICAL and WATER ABSORPTION PROPERTIES of SUGARCANE BAGASSE CELLULOSE HDPE COMPOSITES

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Novel cellulose/NbOPO 4.nH 2O hybrid material from sugarcane bagasse

In recent years studies concerning the applications of lignocellulosic/ inorganic couples have resulted in the development of an interesting class of functional materials. In this work a cellulose/NbOPO 4.nH 2O hybrid using cellulose from surgacane bagasse was prepared and characterized in order to test for adsorption applications. The preparation process was conducted by carrying out metallic niobium dilution in hydrofluoric acid in the presence of nitric acid, then adding boric acid to form the complex and, finally, the cellulose sugar cane bagasse was added. Concentrated phosphoric acid was also inserted to precipitate hydrous niobium phosphate particles in the cellulose fiber. This material was characterized by X-ray diffractometry (XRD), thermogravimetry (TG/DTG), and scanning electronic microscopy (SEM) connected to an energy dispersive spectrophotometer (EDS). Results by SEM/EDS show that NbOPO 4.nH 2O was present in structure of the cellulose. During the preparation of the material, using boric acid it was observed that the formation of precipitate occurred in a shorter time than the material prepared without boric acid.

Xylanase and β-Xylosidase from Penicillium janczewskii: Production, Physico-Chemical properties, and application of the crude extract to pulp biobleaching

Extracellular xylanase and β-xylosidase production by a Penicillium janczewskii strain were investigated in liquid cultures with xylan from oat spelts under different physical and chemical conditions. The selected conditions for optimized production of xylanase and β-xylosidase were 7 days, pH 6.5, at 30 °C and 8 days, pH 5.0, at 25 °C, respectively. The xylanase exhibited optimal activity in pH 5.0 at 50 °C and the β- xylosidase in pH 4.0 at 75 °C. The xylanase was more stable at pH 6.0 to 9.5, while the β-xylosidase remained stable at pH ranging from 1.6 to 5.5. The xylanase half-life (T50) at 40, 50, and 60 °C was 183, 15, and 3 min, respectively. β-xylosidase half-life was 144, 8, and 4 min at 50, 65, and 75 °C, respectively. When applied to the biobleaching of Eucalyptus kraft pulp, xylanase dosages of 2 and 4 U/g dried pulp reduced, respectively, kappa number by 3.0 and 3.3 units after 1 h treatment, demonstrating that the use of P. janczewskii xylanases in this process is quite promising. The pulp viscosity was not altered, confirming the absence of cellulolytic enzymes in the fungal extract.

Kraft pulp from juvenile and mature woods of corymbia citriodora

Kraft pulp produced from juvenile and mature wood from thirty-two-year-old Corymbia citriodora trees was evaluated. The stem was subdivided into regions of juvenile and mature wood, and then it was transformed into chips. These materials were then cooked in the Laboratory of Pulp and Paper at São Paulo State University (UNESP, Botucatu, SP, Brazil) and the physico-mechanical properties of the pulps were determined. The results showed that: (1) the pulp yields of mature wood were up to 4.4% greater in comparison to the juvenile wood, (2) the juvenile wood pulp required a shorter refining time than mature wood to reach the same Schopper-Riegler degree, (3) the juvenile wood pulp presented lower specific volume, and (4) the mature wood pulp presented greater air resistance, tensile, tear and burst index values, stress-strain factor, and stretch than the juvenile wood pulp.

Characterization of high density polyethylene (HDPE) reinforced with banana peel fibers

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Damage and Loss Due to Ceratocystis fimbriata in Eucalyptus Wood for Charcoal Production

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Estudo da dose efetiva, razão sinal-ruído e razão contraste-ruído em tomografia computadorizada de múltiplos detetores

Since discovery, computed tomography is a widely used diagnostic modality. However, this modality imparts relatively high doses to the patients and with fast technological advancement, it is necessary optimize the doses used and ensure the quality of the images through a quality assurance program. This work intended to compare Computed Tomography Dose Index (CTDIW) and effective dose with components of image quality: the Contrast-to-Noise Ratio (CNR) and Signal-to-Noise Ratio (SNR), and a quality factor (Q) deduced by the Rose model for two groups of computed tomography units. The first group was composed by equipments with 10 up to 16 slices and the second one presented 40 up to 320 slices detectors, for the protocols of head and abdomen. It was realized a comparison between different selectable parameters in the protocol of a Philips Brilliance 16, too. The results of the first group to CTDIW, effective dose, SNR and CNR showed variations of 28%, 33%, 37% and 32% respectively for head protocol, and 21%, 27%, 43% and 37% respectively for abdomen protocol. The results of the group 2 to CTDIW, effective dose, SNR and CNR showed variations of 15%, 26%, 36% and 34% respectively for the head protocol, and 8%, 13%, 50% and 60% respectively for abdomen protocol. The comparison between both groups demonstrated similar levels of doses impartation to patients though having so many different configurations, if the uncertainties associated with this measurement were considered. The results of the comparison between different parameters in the Philips Brilliance 16 scanner were in agreement with expected

Characterization of corn (Zea mays) leaf powder and Its adsorption properties regarding Cu(II) and Cd(II) from aqueous samples

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Production of particleboards with bamboo (Dendrocalamus giganteus) reinforcement

The focus of this research was to study the utilization of residues from bamboo (Dendrocalamus giganteus) lamination in the manufacturing of panels for structural purposes. Bamboo particleboards were produced under three conditions: pure boards, reinforced with bamboo laminas, and with treated particles. Castor oil-based polyurethane was the resin binder, in view of using lower toxicity materials. The mechanical tests were performed according to Brazilian Standard (NBR) 14810-3 (2006) and European Standard (EN) 310 (2000). The results were superior to those recommended by these and other standards for internal adhesion resistance, modulus of rupture, and elasticity in static bending, as well as to the results of other studies. Starch treatment was an unnecessary stage. According to the conditions of this process, the studied panels showed a good potential for construction use. Moreover, the bamboo particleboards are an economically viable, environmentally friendly, and sustainable alternative for the use of waste generated during the processing of Dendrocalamus giganteus bamboo species, allied with castor oil-based polyurethane resin. The reinforced particleboard and its production process are being licensed as an Innovation Patent in Brazil, (BR 1020130133919-1-2013).

Medium density particleboard reinforced with bamboo laminas

The objective of this work was to evaluate the effect of the addition of bamboo laminas of the species Dendrocalamus giganteus to three-layer medium density particleboard (MDP). These laminas were glued onto both the top and the bottom of each panel. With the manufactured panels laminated with bamboo, mechanical tests based on the Brazilian Standard ABNT NBR 14810 were carried out to determine the modulus of rupture (MOR) in static bending and the tensile strength parallel-to-surface. These mechanical tests were realized in particleboards of eucalyptus and in reinforced particleboard, both produced in the laboratory. The modulus of rupture and tensile strength parallel-to-surface of the laminated MDP had values close to those that have been reported. The reinforcements increased the values of these studied properties. Nevertheless, this fact indicated the possibility to produce a stronger MDP using bamboo lamina as surface layers. These results show the possibility of using coatedbamboo MDP for utilization in large spans, for example, in flooring for mezzanines with finish on both sides, and for robust furniture as bookshelves, beds, tables, etc.

Fragmentation of lignin from organosolv black liquor by white rot fungi

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)