The effect of alloying in Pt-Sn/C electrocatalysts in the performance of a direct ethanol fuel cell

Work on Pt-Sn-C catalysts for ethanol oxidation showed that a thermal treatment at moderate temperatures leads to a significant increase in activity. The best activity was observed for Pt3Sn1 thermally treated at 200 degrees C and ascribed to a Pt3Sn1 phase plus a cleaning effect. However, electronic effects may be very important and these were not evaluated in the Pt3Sn1 phase. Therefore, in this work we investigated the effect of the degree of alloy on the electronic structure of Pt3Sn1 electrocatalysts by performing electrochemical in situ X-ray absorption (XAS) experiments in the Pt L-III XANES region. Overall, the results show that although the occupancy of the Pt 5d band depends on the degree of alloy other factors, such as the presence of tin oxides/hydroxides in the materials, have to be considered to understand the performance of the DEFC.

Evaluation of area contaminated by wood treatment activities: genetic markers in the environment and in the child population

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Quality of wood and pulp from a clone of Eucalyptus grandis planted at three locations

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Influence of wood moisture content on modulus of elasticity on tension paralllel to the grain of brasilian species

Periodically, when necessary, standard documents are revised in order to analyze inconsistencies and to include considerations according new realities verified. In this sense, aiming to quantify the wood moisture content influence on modulus of elasticity, it was applied tension tests parallel to the grain for six specimens of different strength classes of wood, considering nominal moisture of 12, 20, 25, and 30% in Brazil. The present paper examine the adequacy of the current Brazilian standard ABNT NBR7190:1997, in review, about the adoption of a first degree equation to describe the influence of wood moisture content for timber structures design. It was obtained a new first degree equation which leads to statically equivalent estimations when compared with results by ABNT NBR7190:1997 equation. However, as recommendations it could be maintain the current expression for the next text of the referred document review, without prejudice to statistical significance of the estimates.

Evaluation of longitudinal modulus of elasticity in wood species for structural application

1024x768 This research aimed to investigate possible differences in values of longitudinal modulus of elasticity for wood species usually employed for structural purposes, as Castanheira (Bertholletia excelsa), Cambará (Erisma uncinatum), Cumaru (Dipteryx odorata), Jatobá (Hymenaea stilbocarpa), Garapa (Apuleia leiocarpa) and Peroba Rosa (Aspidosperma polyneuron), obtained from compression and tension parallel to grain, and static bending tests. Recommendations of the Brazilian standard ABNT NBR 7190:1997, Annex B, were followed. Statistical analysis results for the cited properties, had equivalent averages for the six wood species analyzed. This confirms that any of the three tests can be used to obtain the longitudinal elastic modulus and which could avoid the necessity of evaluating stiffness values for wood by more than one kind of mechanical test. Normal 0 21 false false false PT-BR X-NONE X-NONE /* Style Definitions */ table.MsoNormalTable {mso-style-name:"Tabela normal"; mso-tstyle-rowband-size:0; mso-tstyle-colband-size:0; mso-style-noshow:yes; mso-style-priority:99; mso-style-qformat:yes; mso-style-parent:""; mso-padding-alt:0cm 5.4pt 0cm 5.4pt; mso-para-margin:0cm; mso-para-margin-bottom:.0001pt; mso-pagination:widow-orphan; font-size:11.0pt; font-family:"Calibri","sans-serif"; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-fareast-font-family:"Times New Roman"; mso-fareast-theme-font:minor-fareast; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin; mso-bidi-font-family:"Times New Roman"; mso-bidi-theme-font:minor-bidi;}

Influence of moisture content in some mechanical properties of two brazilian tropical wood species

This study aimed, with the aid of analysis of variance (ANOVA), to investigate and quantify the influence of moisture ranging between 12% and over 30% (fiber saturation) on the mechanical properties: strength and modulus of elasticity in compression and in tension parallel to grain; modulus of rupture and modulus of elasticity in static bending; shear strength parallel to grain considering wood species Ipê (Tabebuia sp) and Angelim Araroba (Vataireopsis araroba). Tests were performed according to the assumptions and calculating methods Brazilian standard ABNT NBR 7190, Anexx B, totalizing 400 tests. Results of ANOVA revealed a significant reduction (16% on average) for mechanical properties wood due to the increase in moisture content from 12% to over 30% (fiber saturation). The same behavior also occurred when assembly containing the two species was considered.

Influence of the number of load cycles to obtain the stiffness properties of angico preto (Anadenanthera macrocarpa) wood specie

The tests used to obtain the stiffness properties of wood are made with two loading cycles, as defined by the Brazilian standard ABNT NBR 7190 (Design of Timber Structures). However, the possibility of reducing the number of cycles allows decrease the operating time of the machine, resulting in reduced spending on electricity used during the tests. This research aimed to investigate, with the aid of the analysis of variance (ANOVA), the influence of the use of three load cycles to obtain the modulus of elasticity in compression parallel to grain (Ec0), in tensile parallel to the grain (Et0), in bending (Em) and in compression perpendicular to the grain (Ec90) of Angico Preto (Anadenanthera macrocarpa) wood specie. For the number of cycles and stiffness were manufactured 12 samples, totaling 144 specimens. The results of the ANOVA revealed statistical equivalence between the stiffness properties for both load cycle numbers evaluated, indicating that it is possible to carry out the tests with a single charge cycle, allowing savings in time and energy in the operation of the equipment.

Poissons ratios for wood species for structural purposes

The broader knowledge about physical and mechanical properties of wood allows reliable timber structures design. Even little addressed in the literature, in several situations Poisson's ratios are required for the evaluation of stresses acting on structural elements. This study aimed to obtain values of Poisson's ratios (ν), plans Longitudinal-Radial (νLR) and Longitudinal-Tangential (νLT), for species Peroba Rosa (Aspidosperma polyneuron) and Jatobá (Hymenaea courbaril L.). For this purpose, forty samples Peroba Rosa and eight samples of Jatobá were prepared for testing in compression parallel to the grain, following the recommendations of ABNT NBR 7190 standard. The results of means confidence intervals, considered at the level of 5% significance, revealed that the Poisson's ratios νLR e νLT to Peroba Rosa are 0.27 and 0.42, respectively, and 0.25 and 0.43 to Jatobá.

Study of combustion of different biomass and its atmospheric emissions

One of the energy alternatives that provide utility, flexibility, cleanliness and economy is biomass, such as forest waste (wood) and agricultural (sugarcane bagasse, rice husks, coffee pods, etc.). However, with its increasing supply and use grows also the concern of industries to invest in monitoring and control of emissions into the atmosphere, because during biomass burning are emitted as exhaust gases, fine particles known as particulates, which greatly contribute to the triggering of serious health problems to humans, in addition to the environmental damage. With that, this work aimed to conduct a monitoring of particulate and gaseous pollutants emissions to the atmosphere from the burning of various types of biomass used by industries. The equipment used for sampling were the optical monitor DataRAM 4 and the Unigas3000 + gas sampler. The results showed that biomass coffee pods presented the greatest concentration of particulates (485119 μg m-3) with particle diameters between 0.0602 μm and 0.3502 μm, i.e. the most ultrafine particles, harmful to human health and the environment. The largest emissions of CO and NOx were observed, respectively, for the coffee pods (3500 ppm) and for the rice husk (48 ppm). As for the superior calorific value (PCS), the best of fuel, with higher PCS, was the Eucalyptus grandis.

Moisture content and its influence on the roughness and noise emission during wood machining

Numerous factors influencing the surface quality of wood after machining, among them we highlight the machining parameters and the properties of the wood. In the analysis of the influence of these factors on machining and in determining the quality measurement systems are used to obtain surface characteristics, these systems are divided into methods of contact and non-contact. The method for mechanical contact performed with the aid of the surface roughness tester is the most valued in the measurement of roughness of wood, however, aiming at a greater agility in these measurements, there is a need to seek alternatives for evaluation of surface quality, and one of these options is to use the forms of indirect measurements of this quality, as for example, the use of noise emission during the machining process. With this, the aim was to analyze the influence of the moisture content of the wood, at different levels, on surface quality of the species Pinus elliottii, determined by the method of mechanical probing move and relate this roughness with the sound emission issued for each class of humidity, during machining. The planning of experiments and statistical analyses were performed with the help of Taguchi method. The specimens were conditioned in greenhouses climatizadoras automatics for obtaining three classes of humidity. Machining tests of wooden pieces were performed on a machining center specific for this type of material. The roughness values were measured by a roughness verifier and the noise emission values were measured by for a measurer sound pressure level. Statistically significant differences were observed, the significance level of 10 %, on roughness and noise emission between the three levels of moisture. It was observed that with the increase in the moisture content occurred an increase of roughness and a reduction in noise emission. Monitoring of surface quality through noise level is an interesting alternative to the method of mechanical contact.