565 resultados para resina fenólica


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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Pós-graduação em Odontologia Restauradora - ICT

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Pós-graduação em Odontologia - ICT

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Pós-graduação em Odontologia Restauradora - ICT

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In the present work it was studied the behavior of four water bath curing cycles of heat activated acrylic resin considered as long duration (I – 65ºC for 30 min;50ºC for 23h and 30min; and 100º C for 1h; II- 50ºC for 24h and the rapid cycle), compared to the known long time curing cycle (9 hours for 72ºC) and short curing cycle (1 h for 65ºC; 30 min to elevate at 100º C and 1:00 to 100º C). Analysis consisted of observations and verification of the residual monomer, weight alterations, dimensional, dimensional lineal, porosity and hardness to determine material performance. The results pointed out that residual monomer presented statistical significant differences in the factor storage and interaction among the factors cycle X storage for weight alteration; statistical significant differences for the factor storage for lineal dimensional alterations, without significant differences for hardness. Porosity was verified in minimum degree in the cycle III and in appreciable amount in the cycle IV

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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The glassy carbon is a material with a huge technological evolution. Due to its lightness, biocompatibility and their thermal and electrical properties this material finds applications in several industrial fields such as electronics, medical, aerospace and chemical. In order to explore the conductive properties of glassy carbon for use as modified electrodes, the present work aims the processing of monolithic and reticulated glassy carbon with colloidal copper for use in electrochemical applications. First, the best parameters for the cure of furfuryl alcohol resin doped were established through viscosimetry measurements and pressurized differential scanning calorimetry. The analysis of the micrographs of the cured resins show that copper concentrations above 3% weight, generate higher porosity in the material. The characterizations of the monolithic and reticulated glassy carbon resulting from carbonization were performed by scanning electron microscopy (SEM), Raman and Electrochemical impedance spectroscopy, and although it was not possible to detect the presence of copper by SEM, the influence of these particles have been observed by Raman and FT-IR spectra and electrochemical behavior of the material. The decrease in conductivity of monolithic and reticulated glassy carbon in the presence of copper may be related to the defects caused by the presence of copper in the structure of the material.