115 resultados para landfill gas emission measurements
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Pós-graduação em Ciência e Tecnologia de Materiais - FC
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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This study focuses on the presence of radon (Rn-222) and volatile organic compounds (VOCs) in soil gases at a gas station located in the city of Rio Claro, Sao Paulo, Brazil, where a fossil fuel leak occurred. The spatial distribution results show a correlation between Rn-222 and VOCs, consistent with the fact that radon gas has a greater chemical affinity with organic phases than with water. This finding demonstrates that the presence of a residual hydrocarbon phase in an aquifer can retain radon, leading to a reduced radon content in the soil gas. The data in this study confirm the results of previous investigations, in which the method used in this study provided a preliminary fingerprint of a contaminated area. Furthermore, the data analysis time is brief, and only simple equipment is required. (C) 2014 Published by Elsevier Ltd.
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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The landfill biogas can be an alternative energetic resource as a fuel to electrical energy generators, although, there are not too many techniques to prospect the gas. Usually, landfills receive home waste, which in most are constituted by organic matter whose degradation by anaerobic activity produces the biogas. Geophysics is an important tool in environmental studies and the electrorresistivity, an important method employed in contaminated areas by slurry or necroslurry, including a monitoring for each contaminator flow. The electrorresistivity has not too much application in finding biogas. For this work, two biogas drains in Rio Claro-SP landfill were selected: one whose waste disposition correspond to the initial activities in the landfill and another drain whose disposition started more recently. The result consists in a higher biogas production if compared to the biogas from the older drain. The present paper consists in a monitoring along one year, with dates collection in each fifteen days. These dates were tabled in Excel 2010 program and graphics of resistivity x depth were generated. Hereafter, most variable resistivity values depth were chosen, to further graphics pluviosity x resistivity generation in Grapher 8 program and the biogas output (m³/h) in monitoring period. The use of pluviosity parameter can be justified by its influence above resistivity. The results show that there is a horizon with possibly biogas accumulation. Lastly, the method was effective, although, for any application of geophysical methods, the knowledge about its limitations is necessary; in this case the influence of pluviosity and also that the measurements were made in one single point, it will not show any side variation
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This work aims to analyze data from a Natural Electric Potential landfill type ditch located in Cordeirópolis (SP). The procedure measures initially involved the assembly and installation of an apparatus cables, sensors and drain geophysical measurements and flow rate of biogas in a ditch later filled by solid waste. Biogas is a product of degradation of organic matter in waste by the action of microorganisms in an anaerobic environment. Its features high methane content in the gas potentially usable as fuel in energy generation systems or steam. The study area is characterized by clayey soil composition change from the diabase sill correlated to the event Serra Geral Formation siltstones overlapping Tatuí with groundwater level site around 50m. The cables were installed vertically in parallel with drain gas manifold, which allowed the collection of data by the technique geophysical logging every 15 days over a period of eight months. For data analysis we used four parameters in the study, the closing time of the ditch, natural electric potential, the flow velocity of biogas and rain. With the tabulated data plots were constructed for each collection day showing values in the range of the cable is in contact with waste (200 cm - 400 cm) and range of the cable in contact with the soil (600 cm - 800 cm). Subsequently graphs were generated with the period of eight months to analyze the data tabulated. A statistical correlation data, which show the influence of rainfall on the production of biogas. The results were satisfactory and demonstrated the feasibility of the research method in studies for the feasibility analysis for the capture of biogas energy
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MgTiO3 (MTO) thin films were prepared by the polymeric precursor method with posterior spin-coating deposition. The films were deposited on Pt(111)/Ti/SiO2/Si(100) substrates and heat treated at 350 °C for 2 h and then heat treated at 400, 450, 500, 550, 600, 650 and 700 °C for 2 h. The degree of structural order−disorder, optical properties, and morphology of the MTO thin films were investigated by X-ray diffraction (XRD), micro-Raman spectroscopy (MR), ultraviolet− visible (UV−vis) absorption spectroscopy, photoluminescence (PL) measurements, and field-emission gun scanning electron microscopy (FEG-SEM) to investigate the morphology. XRD revealed that an increase in the annealing temperature resulted in a structural organization of MTO thin films. First-principles quantum mechanical calculations based on density functional theory (B3LYP level) were employed to study the electronic structure of ordered and disordered asymmetric models. The electronic properties were analyzed, and the relevance of the present theoretical and experimental results was discussed in the light of PL behavior. The presence of localized electronic levels and a charge gradient in the band gap due to a break in the symmetry are responsible for the PL in disordered MTO lattice.
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The present work shows a study about the growing of ZnO nanorods by chemical bath deposition (CBD) and its application as gas sensor. It was prepared ZnO nanorods and Au decorated ZnO nanorods and the samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and gas sensing response measurements. The results obtained by XRD show the growth of ZnO phase. It was possible to observe the formation of uniform dense well-aligned ZnO nanorods. The results obtained also revealed that Ag nanoparticles have decorated the surface of ZnO nanorods successfully. Au nanoparticles with diameter of a few nanometers were distributed over the ZnO surface nanorods. The gas sensing response measurements showed a behavior of n type semiconductor. Furthermore, the Au-functionalized ZnO nanorods gas sensors showed a considerably enhanced response at 250 and 300 °C.
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Pós-graduação em Agronomia (Ciência do Solo) - FCAV
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)