123 resultados para Polypropylene glycols


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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Pós-graduação em Zootecnia - FMVZ

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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

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1,3-propanediol is a high-value specialty chemical which has many industrial applications. Its main use is the production of the polymer polypropylene terephthalate, a thermoplastic used in the textile and automobile industries. The interest in 1,3-propanediol production from glycerol bio-conversion has increased after the employment of biodiesel by various countries, being produced by chemical synthesis from petroleum intermediates or biotechnologically by microbial fermentation. Glycerol is an abundant low-cost byproduct from biodiesel refineries, and it is the only substrate that can be naturally or enzymatically converted to 1,3-propanediol by microbial fermentation. In this review, information on 1,3-propanediol's importance, production and purification are presented, along with results from recent research on glycerol microbial conversion to 1,3-propanediol. The bio-production of this intermediate compound from glycerol is very attractive both economically and environmentally, since it allows the replacement of fossil fuels by renewable resources.

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Atualmente alguns híbridos importados têm substituído as tradicionais cultivares de beterraba de mesa, sem no entanto, desenvolver estudos básicos sobre a melhor densidade de plantio para as condições brasileiras. O objetivo deste trabalho foi avaliar o efeito do espaçamento entre linhas e entre plantas na produção de beterraba híbrido Boro. O experimento foi conduzido em campo da UNESP em Botucatu-SP, de 10 de setembro a 8 de dezembro de 2010. Foram estudados dois fatores, espaçamentos entre linhas (EL) de 20 e 25 cm, e 7,5; 10,0 e 12,5 cm entre plantas (EP), no esquema fatorial 2 EL x 3 EP, totalizando seis tratamentos (populações variando de 246.400 a 513.333 plantas ha-1, considerando-se canteiros com 1,0 m de largura e espaço entre canteiros de 0,3 m). O delineamento experimental foi em blocos ao acaso, com cinco repetições e parcelas de 2 m2. As mudas foram produzidas em bandejas de polipropileno com 288 células. A irrigação foi por aspersão e a adubação foi igual para todos os tratamentos, seguindo a recomendação para o estado de São Paulo. A maior massa fresca por raiz (116,1 g) foi obtida no EL de 25,0 cm. Em relação ao comprimento da raiz, observaram-se diferenças significativas apenas para o EP, sendo que o maior espaçamento, 12,5 cm, resultou em maior comprimento (63,1 mm). Foram obtidos maiores valores de diâmetro das raízes quanto maiores os EP (65,6 mm para 12,5 cm) e EL (63,1 mm para 25 cm). A maior produtividade (44,7 t ha-1) foi obtida no menor EP (7,5 cm), enquanto que o EL não afetou a produtividade. Pode-se concluir que o melhor EP foi de 7,5 cm pela maior produtividade. Quanto ao tamanho da raiz, tanto o maior EL (25 cm) como o maior EP (12,5 cm) resultaram em raízes com maiores massa média e diâmetro.

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Pós-graduação em Agronomia (Produção Vegetal) - FCAV

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In this work we report the surface modification of different engineering polymers, such as, polyethylene terephthalate (PET), polyethylene (PE) and polypropylene (PP) by an atmospheric pressure plasma jet (APPJ). It was operated with Ar gas using 10 kV, 37 kHz, sine wave as an excitation source. The aim of this study is to determine the optimal treatment conditions and also to compare the polymer surface modification induced by plasma jet with the one obtained by another atmospheric pressure plasma source the dielectric barrier discharge (DBD). The samples were exposed to the plasma jet effluent using a scanning procedure, which allowed achieving a uniform surface modification. The wettability assessments of all polymers reveal that the treatment leads to reduction of more than 40 degrees in the water contact angle (WCA). Changes in surface composition and chemical bonding were analyzed by x-ray photoelectron spectroscopy (XPS) and Fourier-Transformed Infrared spectroscopy (FTIR) that both detected incorporation of oxygen-related functional groups. Surface morphology of polymer samples was investigated by Atomic Force Microscopy (AFM) and an increase of polymer roughness after the APPJ treatment was found. The plasma-treated polymers exhibited hydrophobic recovery expressed in reduction of the O-content of the surface upon rinsing with water. This process was caused by the dissolution of low molecular weight oxidized materials (LMWOMs) formed on the surface as a result of the plasma exposure. (C) 2014 Elsevier B.V. All rights reserved.

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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This work intends to investigate the biodegradation of the polymers and blend films of polypropylene (PP) and poly(hidroxybutirate-valerate) (PHBV), after UV radiation to facilitate the PP degradation, which is a polymer with long chains difficult to degrade by biological agents present in the environment. This polymer is outstanding by its mechanical properties and versatility of industrial and commercial use and the PHBV by its quick biodegradability in the environment. Blends of these materials could to present a commitment between mechanical properties and biodegradability to execute its function and after the discard to have lesser lifetime in the garbage landfills. Another aspect of this work is the controlling effect of PP on PHBV, influencing its degradation time

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The concern with the environment preservation has done with that researchers as well as industries invest in the search for materials that come from renewable sources. Natural fibers, because they are ecologically correct and have low cost, have been studied as a possible substitute, even if partial, of synthetic fibers in the development of polymeric composites. In this context, the hybrid composites (natural/synthetic) increase considerably the range of application of natural composites. The auto industry, in its constant quest for good mechanical properties materials which are developed with sustainability, has in composites with hybrid reinforcement a very viable alternative. In the present work, the nature Crown pineapple fibers and nature Crown pineapple fibers treated with alkaline solution were studied in order to evaluate the influence of chemical treatment in its properties. For this techniques were used x-ray diffractometry, Thermogravimetry and Infrared Spectroscopy (FTIR). Composites have been developed using polypropylene, reinforced with pineapple fibers and pineapple fibers hybrids/glass fibres, both with levels of 5 and 10%. These composites were analyzed by Thermogravimetry techniques and tested by traction. The realization of this work indicated that although the chemical treatment did not affect the thermal stability of the fibers, caused an increase in crystallinity index fibers and decreased its hydrophilic. The tests performed on composite indicated that the composites process was suitable because it provided good dispersion of the polymer matrix. The addition of natural fibers from the pineapple's Crown, in a proportion of 10%, provided the greatest increase in modulus of elasticity (27%) when compared to the pure polymer